Synthesis, spectroscopy and magnetic properties of transition-metal complexes with aminophosphonate derivatives of pyridine

Żurowska, B.; Boduszek, B.

doi:10.2478/s13536-011-0026-4

Abstract

The compounds of general formula [ML2](ClO4)2 [M = Cu(II), Ni(II), Co(II)]; L = diethyl 3-pyridylmethyl[N-(butyl)amino]phosphonate (3-pmape) or diethyl 4-pyridylmethyl[N-(butyl)amino]phosphonate (4-pmape) were prepared. The new complexes were identified and characterized by elemental analysis, infrared, electronic spectral studies and magnetic measurements. The complexes are sixcoordinate. Metal ions are octahedrally surrounded by two pyridine and two amine nitrogens, and two oxygens of the phosphoryl groups. The results of the magnetic studies suggest polymeric chain structure of the above complexes and indicate weak antiferromagnetic interaction between the magnetic centers. The magnetic behavior of Co(II) complexes is characteristic for cobalt(II) system with an important orbital contribution via spin-orbit coupling.

References

[1] Syamal A., Maurya M.R, Coord. Chem. Rev., 95 (1985), 95.
Search in Google Scholar
[2] Kukhar V.P., Hudson H.R. in: Kukhar V.P. Hudson H.R. (Eds), Aminophosphonic and Aminophosphinic Acids. Chemistry and Biological Activity, (1999) Wiley, London.
Search in Google Scholar
[3] Lippert B., An Inorganic Perspective of Life, NATO ASI Series, Kluwer Academic Publishers, Dordrecht, 459 (1995), 179.
Search in Google Scholar
[4] Żurowska B., Mroziński J., Ciunik Z., Ochocki J., J. Mol. Struct., 834 (2007), 26. http://dx.doi.org/10.1016/j.molstruc.2006.12.02410.1016/j.molstruc.2006.12.024
Search in Google Scholar
[5] Żurowska B., Mroziński J., Ciunik Z., Ochocki J., J. Mol. Struct., 79 (2006), 98. http://dx.doi.org/10.1016/j.molstruc.2006.01.01110.1016/j.molstruc.2006.01.011
Search in Google Scholar
[6] Ochocki J., Kostka K., Żurowska B., Mroziński J., Gałdecka E., Gałdecki Z., Reedijk J., J. Chem. Soc. Dalton Trans., 2955 (1992). 10.1039/dt9920002955
Search in Google Scholar
[7] Żurowska B., Ochocki J., Mroziński J., Ciunik Z., Reedijk J., Inorg. Chim. Acta, 357 (2004), 755. http://dx.doi.org/10.1016/j.ica.2003.06.01710.1016/j.ica.2003.06.017
Search in Google Scholar
[8] Ochocki J., Żurowska B., Mroziński J., Kooijman H., Spek. A.L., Reedijk. J., Eur. J. Inorg. Chem., 169 (1998).
Search in Google Scholar
[9] Żurowska B., Ślepokura K., Lis T., Ochocki J., Inorg. Chim. Acta, 362 (2008), 733. http://dx.doi.org/10.1016/j.ica.2008.04.00810.1016/j.ica.2008.04.008
Search in Google Scholar
[10] Żurowska B., Kalinowska-Lis U., Białońska A., Ochocki J., J. Mol. Struct., 889 (2008), 98. http://dx.doi.org/10.1016/j.molstruc.2008.01.02410.1016/j.molstruc.2008.01.024
Search in Google Scholar
[11] Żurowska B., Kalinowska-Lis U., Brzuszkiewicz A., Ochocki J., Inorg. Chim. Acta, 362 (2009), 1435. http://dx.doi.org/10.1016/j.ica.2008.07.00110.1016/j.ica.2008.07.001
Search in Google Scholar
[12] Kalinowska U., Cheçińska L., Małecka M., Erxleben, A. Lippert, B., Ochocki J., Inorg. Chim. Acta, 358 (2005), 464. http://dx.doi.org/10.1016/j.ica.2005.02.02010.1016/j.ica.2005.02.020
Search in Google Scholar
[13] Aranowska K., Graczyk J., Cheçińska L., Pakulska W., Ochocki J., Pharmazie, 61 (2006), 5.
Search in Google Scholar
[14] Zięba R., Malinowska K., Wiewiórowski M., Graczyk J., Acta Pol. Pharm., 57 (2000), 136.
Search in Google Scholar
[15] Cheçiń Ska L., Małecka M., Ochocki J., Aranowska K., Acta Cryst., E 59 (2003), m350. http://dx.doi.org/10.1107/S160053680301002X10.1107/S160053680301002X
Search in Google Scholar
[16] Brzezińska-Błaszczyk E., Mińcikiewicz M., Ochocki J., Eur. J. Pharmacol, 298 (1996), 155. http://dx.doi.org/10.1016/0014-2999(95)00809-810.1016/0014-2999(95)00809-8
Search in Google Scholar
[17] Kostka B., Ochocki J., Pharmazie, 51 (1996), 990. 10.1111/j.1365-2044.1996.tb14979.x
Search in Google Scholar
[18] Kajman-Bronżewska L., Ochocki J., Pharmazie, 52 (1997), 198.
Search in Google Scholar
[19] Zhao G., Lin H., Yu P.. Su H., Zhu S., Su X., Chen Y., J. Inorg. Biochem., 73 (1999), 145. http://dx.doi.org/10.1016/S0162-0134(99)00009-410.1016/S0162-0134(99)00009-4
Search in Google Scholar
[20] Iakovidou Z., Papageorgiou A., Demertzis M.A., Mioglou E., Mourelatos D., Kotsls A., Nath Yadav P., Kovala-Demertzi D., Anti-Cancer Drugs, 12 (2001), 65. http://dx.doi.org/10.1097/00001813-200101000-0000910.1097/00001813-200101000-00009
Search in Google Scholar
[21] Ćurić M., Tušek-Božic L., Vikić-Topić D., Scarcia V., Furlani A., Balzarini J., De Clercq E., J. Inorg. Biochem., 63 (1996), 125. http://dx.doi.org/10.1016/0162-0134(95)00199-910.1016/0162-0134(95)00199-9
Search in Google Scholar
[22] Tušek-Božić L, Ćurić M, Balzarini J, De Clercq E., Nucleos Nucleot, 14 (1995), 777. http://dx.doi.org/10.1080/1525777950801247010.1080/15257779508012470
Search in Google Scholar
[23] Tušek-Božić L., Matijašić J., Bocelli G,, Sgarbotto P,, Furlani A,, Scaria V., Papaioannou A., Inorg Chim Acta, 185 (1991), 229. http://dx.doi.org/10.1016/S0020-1693(00)85448-110.1016/S0020-1693(00)85448-1
Search in Google Scholar
[24] Tušek-Božić L., Matijašić J., Bocelli G., Calestani G., Furlani A., Scarcia V., Papaioannou A., J. Chem. Soc. Dalton Trans., 195 (1991). 10.1039/DT9910000195
Search in Google Scholar
[25] Kalinowska U., Matławska K., Cheçińska L., Domagała M., Kontek R., Osiecka R., Ochocki J., J. Inorg. Biochem., 99 (2005), 2024. http://dx.doi.org/10.1016/j.jinorgbio.2005.06.03010.1016/j.jinorgbio.2005.06.03016111760
Search in Google Scholar
[26] KÖ Nig E., Magnetic Properties of Coordination and Organometallic Transition Metal Compounds, (1966), Springer, Berlin.
Search in Google Scholar
[27] Carlin R.L., Magnetochemistry, (1986) Springer, Heidelberg. 10.1007/978-3-642-70733-9
Search in Google Scholar
[28] Boduszek B., Phosphorus, Sulfur and Silicon, 113 (1996), 209. http://dx.doi.org/10.1080/1042650960804639010.1080/10426509608046390
Search in Google Scholar
[29] Boduszek B., Tetrahedron, 52 (1996), 12483. http://dx.doi.org/10.1016/0040-4020(96)00727-210.1016/0040-4020(96)00727-2
Search in Google Scholar
[30] Witteveen H.T., Reedijk J., J. Solid State Chem., 10 (1974), 151. http://dx.doi.org/10.1016/0022-4596(74)90022-X10.1016/0022-4596(74)90022-X
Search in Google Scholar
[31] Clark R.J.H., Wiliams C.S.W., Inorg. Chem., 4 (1965), 350. http://dx.doi.org/10.1021/ic50025a02010.1021/ic50025a020
Search in Google Scholar
[32] Ray M.S., Ghosh A., Bhattacharya R., Mukhopadhyay G.M., Drew M.G.B., Ribas J., Eur. J. Inorg. Chem., 3110 (2004). 10.1002/ejic.200300969
Search in Google Scholar
[33] Żurowska B., Erxleben A., Glinka Ł., Łeçzycka M., Zyner E., Ochocki J., Inorg. Chim. Acta, 362 (2009) 739. http://dx.doi.org/10.1016/j.ica.2008.04.01410.1016/j.ica.2008.04.014
Search in Google Scholar
[34] Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley and Sons, (1978), New York.
Search in Google Scholar
[35] Hathaway B.J., Underhill A.E., J. Chem. Soc., 3091 (1961). 10.1039/jr9610003091
Search in Google Scholar
[36] Ferraro J.R., Low Frequency Vibrations of Inorganic and Coordination Compounds, Plenum, (1971) New York. 10.1007/978-1-4684-1809-5_9
Search in Google Scholar
[37] Lever A.B.P., Inorganic Electronic Spectroscopy, Elsevier, (1986), Amsterdam.
Search in Google Scholar
[38] Reedijk J., van Leeuwen P.W.N.M., Groeneveld W.L., Recl. Trav. Chim. Pays-Bas, 87 (1968), 129. http://dx.doi.org/10.1002/recl.1968087020310.1002/recl.19680870203
Search in Google Scholar
[39] Reedijk J., Driessen W.L,, Groeneveld W,L., Recl, Trav. Chim. Pays-Bas, 88 (1969), 1095. http://dx.doi.org/10.1002/recl.1969088091210.1002/recl.19690880912
Search in Google Scholar
[40] Figgis F.N., Levis J., Progress Inorg. Chem., 6 (1964), 37. http://dx.doi.org/10.1002/9780470166079.ch210.1002/9780470166079.ch2
Search in Google Scholar
[41] Ginsberg A.P., Martin R.L., Brookes W., Sherwood R.R.C., Inorg. Chem., 11 (1972), 2884. http://dx.doi.org/10.1021/ic50118a00610.1021/ic50118a006
Search in Google Scholar
[42] Boca R., Coord. Chem. Rev., 248 (2004), 757. http://dx.doi.org/10.1016/j.ccr.2004.03.00110.1016/j.ccr.2004.03.001
Search in Google Scholar
[43] Smart J.S., Effective Field Theories of Magnetism, (1966) Saunders W.B. Comp., Philadelphia and London. 10.1063/1.3048415
Search in Google Scholar
[44] Hall J.W.A., Ph.D. Dissertation, (1977), University of North Carolina.
Search in Google Scholar
[45] Bonner J.C., Fisher M.E., Phys. Rev. Sect. A., 135 (1964), 640. 10.1103/PhysRev.135.A640
Search in Google Scholar
[46] O’brien S. Gaura R.M., Landee C.P., Willett R.D., Solid. State Commun., 39 (1981).
Search in Google Scholar
[47] Mabbs F.E., Machin D.J., Magnetism and Transition Metal Complexes, Chapman and Hall, (1973), London.
Search in Google Scholar
[48] Kahn O., Molecular Magnetism, VCH Publishers, (1993), New York.
Search in Google Scholar
[49] O’connor C.J., Prog. Inorg. Chem., 29 (1982), 203. http://dx.doi.org/10.1002/9780470166307.ch410.1002/9780470166307.ch4
Search in Google Scholar
[50] Rizzi A.C., Brondino C.D., Calvo R., Baggio R., Garland M.T., Rapp R.E., Inorg. Chem., 42 (2003), 4409. http://dx.doi.org/10.1021/ic026111b10.1021/ic026111b12844314
Search in Google Scholar
[51] Kahn O., Larionova J., Yakhim J.V., Chem. Eur. J., 5 (1999), 3443. http://dx.doi.org/10.1002/(SICI)1521-3765(19991203)5:12<;3443::AID-CHEM3443>3.0.CO;2-#
Search in Google Scholar
[52] Żurowska B., Mrozinski J., Ciunik Z., Ochocki J., J. Mol. Struct., 79 (2006), 98. http://dx.doi.org/10.1016/j.molstruc.2006.01.01110.1016/j.molstruc.2006.01.011
Search in Google Scholar

Synthesis, spectroscopy and magnetic properties of transition-metal complexes with aminophosphonate derivatives of pyridine

Abstract

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