Table 1.
Monitoring stations analyzed in the Warsaw agglomeration
| Name of station | Location | Location | Type | Pollution | Sampling frequency | ||
|---|---|---|---|---|---|---|---|
| Latitude | Longitude | ||||||
| MzWarAlNiepo | Warsaw, Niepodległości 227/233 | 52.22 | 21.00 | communication | PM2.5 | PM10 | 1h |
| MzPiasPulask | Piastów, Pułaskiego 6/8 | 52.19 | 20.84 | suburban background | PM2.5 | - | 1h |
| MzLegZegrzyn | Legionowo, Zegrzyńska 38 | 52.41 | 20.96 | suburban background | PM2.5 | - | 1h |
| MzWarWokalna | Warsaw, Wokalna 1 | 52.16 | 21.03 | urban background | - | PM10 | 1h |

Figure 1.
Distribution of measurement stations of the State Environmental Monitoring (PMŚ) department in Warsaw and its surroundings

Figure 2.
PM10 concentration levels from 2016 to 2021 at the MzWarAlNiepo station

Figure 3.
PM10 concentration level in 2016–2021 at MzWarWokalna station

Figure 4.
PM2.5 concentration levels from 2016 to 2021 at MzWarAlNiepo station

Figure 5.
PM2.5 concentration levels from 2016 to 2021 at MzPiasPulask station

Figure 6.
PM2.5 concentration level in 2016–2021 at MzLegZegrzyn station

Figure 7.
Exceedances of the permissible annual average concentration of PM10 dust from 2016 to 2021 in μg/m3

Figure 8.
Exceedances of the permissible annual average concentration of PM2.5 dust in 2016–2021 in μg/m3

Figure 9.
Number of days with exceedances of the 24-hour average value of PM10 dust in μg/m3
Table 2.
PM10 Monthly Median and IQR at the stations MzWarAlNiepo and MzWarWokalna
| Month | MzWarAlNiepo | MzWarWokalna | ||
|---|---|---|---|---|
| Median [µg/m3] | IQR [µg/m3] | Median [µg/m3] | IQR [µg/m3] | |
| I | 48.61 | 8.37 | 38.16 | 14.75 |
| II | 48.57 | 14.98 | 34.42 | 16.13 |
| III | 54.55 | 12.17 | 31.59 | 9.8 |
| IV | 46.23 | 4.92 | 27.76 | 5.35 |
| V | 35.05 | 4.06 | 22.57 | 7.31 |
| VI | 35.09 | 5.62 | 21.33 | 0.76 |
| VII | 31.42 | 2.83 | 19.21 | 2.66 |
| VIII | 31.3 | 1.82 | 19.84 | 6.14 |
| IX | 36.14 | 4.28 | 22.88 | 6.7 |
| X | 37.27 | 1.77 | 28.71 | 3.87 |
| XI | 39.05 | 10.24 | 32.01 | 10.84 |
| XII | 36.94 | 5.25 | 28.9 | 6.2 |
Table 3.
PM2.5 Monthly Median and IQR at the stations MzPiasPulask, MzWarAlNiepo, and MzLegZegrzyn
| Month | MzPiasPulask | MzWarAlNiepo | MzLegZegrzyn | |||
|---|---|---|---|---|---|---|
| Median [µg/m3] | IQR [µg/m3] | Median [µg/m3] | IQR [µg/m3] | Median [µg/m3] | IQR [µg/m3] | |
| I | 40.93 | 12.82 | 37.79 | 9.1 | 41.78 | 12.79 |
| II | 33.79 | 12.53 | 33.56 | 11.1 | 34.54 | 7.2 |
| III | 28.43 | 6.93 | 29.86 | 6.59 | 30.7 | 6.14 |
| IV | 19.4 | 4.46 | 21.47 | 4.56 | 19.86 | 5.58 |
| V | 12.96 | 2.56 | 15.91 | 5.38 | 12.72 | 2.9 |
| VI | 11.84 | 1.42 | 14.83 | 0.89 | 11.08 | 2.88 |
| VII | 10.91 | 3.03 | 14.2 | 2.01 | 10.36 | 2.48 |
| VIII | 11.49 | 2.96 | 14.57 | 2.97 | 11.31 | 1.88 |
| IX | 14.57 | 3.23 | 17.97 | 3.68 | 14.59 | 2.84 |
| X | 21.47 | 3.42 | 24.54 | 3.61 | 22.65 | 4.77 |
| XI | 28.7 | 8.18 | 30.33 | 10.03 | 29.03 | 5.34 |
| XII | 27.88 | 4.4 | 29.32 | 4.66 | 29.27 | 5.14 |
Table 4.
PM10 monthly mean concentrations for the period 2016–2021 at stations MzWarAlNiepo and MzWarWokalna
| Station | Year | I | II | III | IV | V | VI | VII | VIII | IX | X | XI | XII |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| MzWarAlNiepo | 2016 | 53.65 | 38.18 | 48.54 | 46.63 | 37.80 | 34.90 | 28.89 | 31.30 | 54.95 | 33.41 | 45.39 | 45.38 |
| 2017 | 68.63 | 55.54 | 62.93 | 37.02 | 37.04 | 31.37 | 30.95 | 32.11 | 27.44 | 37.90 | 44.47 | 39.44 | |
| 2018 | 44.52 | 58.63 | 62.46 | 53.07 | 37.29 | 38.21 | 32.44 | 34.25 | 35.66 | 42.75 | 44.56 | 37.09 | |
| 2019 | 42.83 | 53.34 | 49.03 | 47.38 | 34.49 | 32.93 | 30.28 | 30.88 | 30.60 | 35.85 | 29.19 | 30.57 | |
| 2020 | 38.52 | 28.32 | 48.40 | 49.80 | 32.72 | 27.74 | 27.82 | 29.82 | 35.07 | 36.40 | 37.40 | 32.60 | |
| 2021 | 43.50 | 57.42 | 55.93 | 43.49 | 30.98 | 45.40 | 38.11 | 29.47 | 33.13 | 37.33 | 33.27 | 36.59 | |
| average | 48.61 | 48.57 | 54.55 | 46.23 | 35.05 | 35.09 | 31.42 | 31.30 | 36.14 | 37.27 | 39.05 | 36.94 | |
| stdev | 10.03 | 11.32 | 6.31 | 5.06 | 2.54 | 5.61 | 3.33 | 1.58 | 8.86 | 2.83 | 6.24 | 4.78 | |
| stdev/average | 0.21 | 0.23 | 0.12 | 0.11 | 0.07 | 0.16 | 0.11 | 0.05 | 0.25 | 0.08 | 0.16 | 0.13 | |
| MzWarWokalna | 2016 | 46.12 | 29.20 | 32.95 | 29.05 | 23.96 | 20.00 | 17.23 | 18.41 | 26.38 | 22.29 | 31.96 | 34.23 |
| 2017 | 56.38 | 45.69 | 36.25 | 25.30 | 27.40 | 20.79 | 20.67 | 24.00 | 22.81 | 30.10 | 37.25 | 33.17 | |
| 2018 | 38.00 | 46.30 | 45.04 | 35.72 | 29.43 | 27.43 | 25.20 | 24.96 | 30.99 | 42.94 | 47.62 | 31.43 | |
| 2019 | 28.03 | 27.59 | 22.13 | 31.27 | 17.73 | 19.05 | 14.12 | 16.81 | 15.11 | 25.26 | 22.33 | 21.21 | |
| 2020 | 28.46 | 18.32 | 28.49 | 25.57 | 23.74 | 20.69 | 19.17 | 21.41 | 24.10 | 26.30 | 29.21 | 26.95 | |
| 2021 | 31.96 | 39.43 | 24.67 | 19.67 | 13.15 | 20.01 | 18.87 | 13.43 | 17.88 | 25.35 | 23.71 | 26.39 | |
| average | 38.16 | 34.42 | 31.59 | 27.76 | 22.57 | 21.33 | 19.21 | 19.84 | 22.88 | 28.71 | 32.01 | 28.90 | |
| stdev | 10.25 | 10.22 | 7.65 | 5.06 | 5.56 | 2.79 | 3.37 | 4.05 | 5.24 | 6.77 | 8.58 | 4.51 | |
| stdev/average | 0.27 | 0.30 | 0.24 | 0.18 | 0.25 | 0.13 | 0.18 | 0.20 | 0.23 | 0.24 | 0.27 | 0.16 |
Table 5.
PM2.5 monthly mean concentrations for the period 2016–2021 at stations MzPiasPulask, MzWarAlNiepo and MzLegZegrzyn
| Station | Year | I | II | III | IV | V | VI | VII | VIII | IX | X | XI | XII |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| MzPiasPulask | 2016 | 48.19 | 27.60 | 30.86 | 21.97 | 14.75 | 14.77 | 13.54 | 15.56 | 19.95 | 22.13 | 31.80 | 35.27 |
| 2017 | 64.64 | 46.92 | 31.27 | 18.89 | 14.84 | 10.73 | 10.89 | 11.46 | 12.67 | 19.15 | 28.93 | 30.31 | |
| 2018 | 32.02 | 41.94 | 37.75 | 21.82 | 14.09 | 12.20 | 12.25 | 13.01 | 16.53 | 28.66 | 42.69 | 28.56 | |
| 2019 | 37.81 | 31.53 | 21.54 | 21.01 | 14.01 | 10.78 | 8.51 | 10.32 | 14.16 | 22.17 | 23.75 | 25.68 | |
| 2020 | 27.84 | 16.10 | 23.89 | 16.14 | 11.37 | 10.49 | 8.45 | 9.45 | 12.80 | 18.61 | 22.62 | 22.09 | |
| 2021 | 35.04 | 38.64 | 25.28 | 16.58 | 8.73 | 12.05 | 11.80 | 9.11 | 11.29 | 18.10 | 22.41 | 25.40 | |
| average | 40.93 | 33.79 | 28.43 | 19.40 | 12.96 | 11.84 | 10.91 | 11.49 | 14.57 | 21.47 | 28.70 | 27.88 | |
| stdev | 12.31 | 10.16 | 5.46 | 2.38 | 2.22 | 1.47 | 1.89 | 2.24 | 2.90 | 3.59 | 7.15 | 4.19 | |
| stdev/average | 0.30 | 0.30 | 0.19 | 0.12 | 0.17 | 0.12 | 0.17 | 0.19 | 0.20 | 0.17 | 0.25 | 0.15 | |
| MzWarAlNiepo | 2016 | 43.67 | 26.87 | 30.22 | 23.49 | 18.22 | 14.50 | 13.51 | 14.88 | 22.51 | 25.75 | 36.53 | 36.94 |
| 2017 | 54.31 | 44.08 | 33.42 | 21.11 | 18.60 | 14.51 | 15.96 | 17.02 | 18.16 | 26.52 | 35.86 | 32.10 | |
| 2018 | 33.26 | 41.08 | 39.94 | 23.75 | 14.25 | 14.05 | 13.98 | 14.31 | 17.01 | 25.86 | 34.40 | 29.08 | |
| 2019 | 36.02 | 35.61 | 26.49 | 25.93 | 19.60 | 17.24 | 15.25 | 16.68 | 20.02 | 28.46 | 26.91 | 26.80 | |
| 2020 | 27.00 | 16.31 | 23.21 | 16.10 | 12.75 | 13.43 | 10.71 | 11.61 | 15.50 | 21.74 | 24.98 | 24.35 | |
| 2021 | 32.45 | 37.39 | 25.88 | 18.46 | 12.03 | 15.23 | 15.76 | 12.91 | 14.65 | 18.93 | 23.30 | 26.65 | |
| average | 37.79 | 33.56 | 29.86 | 21.47 | 15.91 | 14.83 | 14.20 | 14.57 | 17.97 | 24.54 | 30.33 | 29.32 | |
| stdev | 8.91 | 9.39 | 5.56 | 3.34 | 3.00 | 1.21 | 1.79 | 1.92 | 2.68 | 3.21 | 5.41 | 4.16 | |
| stdev/average | 0.24 | 0.28 | 0.19 | 0.16 | 0.19 | 0.08 | 0.13 | 0.13 | 0.15 | 0.13 | 0.18 | 0.14 | |
| MzLegZegrzyn | 2016 | 54.74 | 29.26 | 38.69 | 23.74 | 17.07 | 12.77 | 11.08 | 12.66 | 19.81 | 22.54 | 36.59 | 39.51 |
| 2017 | 61.87 | 40.20 | 29.50 | 16.94 | 12.75 | 10.24 | 10.94 | 12.91 | 13.62 | 16.19 | 23.70 | 24.41 | |
| 2018 | 33.22 | 47.98 | 38.78 | 19.18 | 12.12 | 11.00 | 11.80 | 14.04 | 15.53 | 29.81 | 36.53 | 29.16 | |
| 2019 | 35.83 | 30.73 | 21.54 | 23.47 | 14.33 | 10.70 | 8.02 | 9.90 | 14.11 | 27.12 | 27.98 | 27.96 | |
| 2020 | 28.51 | 18.43 | 29.43 | 18.70 | 10.79 | 10.35 | 7.83 | 9.41 | 12.68 | 22.09 | 24.57 | 24.09 | |
| 2021 | 36.52 | 40.68 | 26.28 | 17.10 | 9.29 | 11.41 | 12.52 | 8.93 | 11.78 | 18.18 | 24.83 | 30.48 | |
| average | 41.78 | 34.54 | 30.70 | 19.86 | 12.72 | 11.08 | 10.36 | 11.31 | 14.59 | 22.65 | 29.03 | 29.27 | |
| stdev | 12.14 | 9.59 | 6.27 | 2.77 | 2.50 | 0.85 | 1.80 | 1.96 | 2.61 | 4.71 | 5.49 | 5.14 | |
| stdev/average | 0.29 | 0.28 | 0.20 | 0.14 | 0.20 | 0.08 | 0.17 | 0.17 | 0.18 | 0.21 | 0.19 | 0.18 |

Figure 10.
Statistical analysis with PM10 correlation

Figure 11.
Statistical analysis with PM2.5 correlation
Table 6.
Statistical analysis of stations measuring PM10 dust concentrations
| Year | Correlation | SD MzWarAlNiepo | SD MzWarWokalna | ||
|---|---|---|---|---|---|
| SD | mean | SD | mean | ||
| 2016 | 0.556 | 26.10 | 41.64 | 16.23 | 27.51 |
| 2017 | 0.774 | 29.91 | 42.05 | 21.76 | 31.68 |
| 2018 | 0.654 | 25.54 | 42.88 | 20.79 | 35.52 |
| 2019 | 0.631 | 20.26 | 37.30 | 13.40 | 21.88 |
| 2020 | 0.573 | 21.45 | 35.37 | 16.41 | 24.56 |
| 2021 | 0.589 | 27.72 | 40.3 | 16.82 | 22.91 |
Table 7.
Statistical analysis of stations measuring PM2.5 concentrations
| Year | correlation MzWarAlNiepo-MzLegZegrzyn | correlation MzWarAlNiepo-MzPiasPulask | MzLegZegrzyn-MzPiasPulask correlation | MzWarAlNiepo | MzLegZegrzyn | MzPiasPulask | |||
|---|---|---|---|---|---|---|---|---|---|
| SD | Mean | SD | Mean | SD | Mean | ||||
| 2016 | 0.778 | 0.700 | 0.747 | 27.61 | 25.55 | 19.06 | 26.38 | 16.57 | 24.69 |
| 2017 | 0.776 | 0.724 | 0.865 | 28.22 | 27.57 | 26.61 | 23.06 | 20.03 | 25.07 |
| 2018 | 0.746 | 0.722 | 0.753 | 25.93 | 24.86 | 21.46 | 24.77 | 17.37 | 25.01 |
| 2019 | 0.796 | 0.783 | 0.800 | 18.77 | 24.65 | 15.77 | 21.07 | 13.25 | 19.67 |
| 2020 | 0.813 | 0.775 | 0.760 | 16.59 | 18.08 | 13.42 | 17.92 | 11.29 | 16.6 |
| 2021 | 0.845 | 0.784 | 0.873 | 20.94 | 21.05 | 17.28 | 20.66 | 15.02 | 19.46 |