Figure 1

Figure 2

Figure 3

Raw coke wastewater [Miodoński et al_ 2010]_
| Parameter | Concentration mg/dm3 |
|---|---|
| Ammonium nitrogen | 600 |
| Total nitrogen | 900 |
| Chemical oxygen demand | 4500 |
| Phenols | 2000 |
| Thiocyanates | 30 |
| Free cyanides | 5 |
| Hydrogen sulphide | 50 |
Quality parameters of the wastewater discharged_
| Type of substance | Dz.U. 2006 nr 136 poz. 964 mg/dm3 mgO2/dm3 | Dz.U. 2014 poz. 1800 mg/dm3 mgO2/dm3 | Requirements of BAT 56 Decyzja …2012. |
|---|---|---|---|
| Ammonium nitrogen | 100–200 | 10 | - |
| Nitrite nitrogen | 10 | 1 | - |
| Total nitrogen | - | 30 | <15–50 |
| Chlorides | 1000 | 1000 | - |
| COD | * | 250 The values of the indicators shall be determined on the basis of the permissible load of the treatment plant. | <220 The values of the indicators shall be determined on the basis of the permissible load of the treatment plant. |
| BOD5 | * | 25 The values of the indicators shall be determined on the basis of the permissible load of the treatment plant. | <20 The values of the indicators shall be determined on the basis of the permissible load of the treatment plant. |
| Free cyanides | 0.5 | 0.1 | <0.1 |
| Combined cyanides | 5 | 5 | - |
| Thiocyanides | - | - | <4.0 |
| Free sulphides | - | 0.2 | <0.1 |
| Thiocyanates | 30 | 10 | - |
| Volatile phenols | 15 | 0.1 | <0.5 |
| PAHs | 15 | 15 | <0.05 |