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Chemical and radiochemical characterization of phosphogypsum from Poland Cover

Chemical and radiochemical characterization of phosphogypsum from Poland

Open Access
|Jun 2024

Figures & Tables

Fig. 1.

(a) Phosphogypsum waste stack of the former Wizów Chemical Plant in Poland. (b) Phosphogypsum sampling points. (c) Raw sample of phosphogypsum. (d) Dried phosphogypsum.
(a) Phosphogypsum waste stack of the former Wizów Chemical Plant in Poland. (b) Phosphogypsum sampling points. (c) Raw sample of phosphogypsum. (d) Dried phosphogypsum.

Fig. 2.

Illustration of phosphogypsum sample laboratory preparation steps for analysis.
Illustration of phosphogypsum sample laboratory preparation steps for analysis.

Fig. 3.

Activity concentrations of 226Ra, 232Th, 238U, and 40K in Wizów’s phosphogypsum sample.
Activity concentrations of 226Ra, 232Th, 238U, and 40K in Wizów’s phosphogypsum sample.

The content of selected metals in Wizów’s phosphogypsum

ElementsConcentration (mg/kg)ElementsConcentration (mg/kg)
Antimony0.12–0.15Manganese22.96–25.18
Arsenic4.76–5.23Molybdenum2.14–2.36
Barium476.3–522.5Neodymium685.9–752.5
Beryllium0.27–0.31Nickel12.54–13.75
Cadmium0.06–0.08Praseodymium200.5–220.0
Cerium2036–2234Samarium97.4–106.8
Cobalt3.35–3.69Selenium6.46–7.10
Copper19.77–21.69Silver0.61–0.67
Dysprosium41.92–45.97Terbium10.23–11.23
Erbium15.45–16.95Thallium0.01–0.02
Europium26.98–29.58Thorium9.92–10.88
Gadolinium117.2–128.6Thulium1.21–1.32
Holmium6.26–6.87Uranium0.67–0.72
Iron1024–1124Vanadium12.27–13.46
Lanthanum1408–1545Ytterbium5.46–5.99
Lead3.36–3.72Zinc14.57–15.99
Lutetium0.54–0.61

The content of radionuclides in phosphogypsum sample related to sea sand as natural background

IsotopeEnergy (keV)Combined activity ± uncertainty (Bq/kg)A/Abackground
214Pb53.2, 241.9, 258.8, 351.92.13 ± 0.0042.7
214Bi79.7, 609.3, 768.4, 934.11.33 ± 0.0012.5
208Tl84.91.25 ± 0.0021.9
212Pb87.3, 115.2, 238.61.16 ± 0.0042.1
235U89.95, 93.9, 109.2, 185.70.192 ± 0.0111.48
228Ac99.5, 129.1, 129.1, 153.9, 199, 209.25.76 ± 0.0681.8
40K1460.80.132 ± 0.0013.0

Comparison of the radioactivity of phosphogypsum collected from the former Wizów Chemical Plant, Poland, to phosphogypsum from other countries

Country/RadioisotopeActivity concentration (Bq/kg)
226Ra232Th238U40KReference
Spain670222039[13]
Egypt459401402[14]
USA (Florida)1140213014[15]
Tunisia18826003[16]
Serbia600347[16]
Croatia811813[16]
Czech Republic1153195[16]
Morocco1602019010[17]
Togo100131503[16]
Greece5732.229562.4[18]
Worldwide range162–51262.1–35.215–6015–1410[17, 18]
Poland, Wizów77.4425.964.730.13Current study
DOI: https://doi.org/10.2478/nuka-2024-0016 | Journal eISSN: 1508-5791 | Journal ISSN: 0029-5922
Language: English
Page range: 113 - 117
Submitted on: Nov 15, 2023
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Accepted on: Mar 7, 2024
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Published on: Jun 25, 2024
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2024 Linda Maina, Katarzyna Kiegiel, Ewelina Chajduk, Grażyna Zakrzewska-Kołtuniewicz, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.