Fig. 1.

Fig. 2.

Fig. 3.

The content of selected metals in Wizów’s phosphogypsum
| Elements | Concentration (mg/kg) | Elements | Concentration (mg/kg) |
|---|---|---|---|
| Antimony | 0.12–0.15 | Manganese | 22.96–25.18 |
| Arsenic | 4.76–5.23 | Molybdenum | 2.14–2.36 |
| Barium | 476.3–522.5 | Neodymium | 685.9–752.5 |
| Beryllium | 0.27–0.31 | Nickel | 12.54–13.75 |
| Cadmium | 0.06–0.08 | Praseodymium | 200.5–220.0 |
| Cerium | 2036–2234 | Samarium | 97.4–106.8 |
| Cobalt | 3.35–3.69 | Selenium | 6.46–7.10 |
| Copper | 19.77–21.69 | Silver | 0.61–0.67 |
| Dysprosium | 41.92–45.97 | Terbium | 10.23–11.23 |
| Erbium | 15.45–16.95 | Thallium | 0.01–0.02 |
| Europium | 26.98–29.58 | Thorium | 9.92–10.88 |
| Gadolinium | 117.2–128.6 | Thulium | 1.21–1.32 |
| Holmium | 6.26–6.87 | Uranium | 0.67–0.72 |
| Iron | 1024–1124 | Vanadium | 12.27–13.46 |
| Lanthanum | 1408–1545 | Ytterbium | 5.46–5.99 |
| Lead | 3.36–3.72 | Zinc | 14.57–15.99 |
| Lutetium | 0.54–0.61 |
The content of radionuclides in phosphogypsum sample related to sea sand as natural background
| Isotope | Energy (keV) | Combined activity ± uncertainty (Bq/kg) | A/Abackground |
|---|---|---|---|
| 214Pb | 53.2, 241.9, 258.8, 351.9 | 2.13 ± 0.004 | 2.7 |
| 214Bi | 79.7, 609.3, 768.4, 934.1 | 1.33 ± 0.001 | 2.5 |
| 208Tl | 84.9 | 1.25 ± 0.002 | 1.9 |
| 212Pb | 87.3, 115.2, 238.6 | 1.16 ± 0.004 | 2.1 |
| 235U | 89.95, 93.9, 109.2, 185.7 | 0.192 ± 0.011 | 1.48 |
| 228Ac | 99.5, 129.1, 129.1, 153.9, 199, 209.2 | 5.76 ± 0.068 | 1.8 |
| 40K | 1460.8 | 0.132 ± 0.001 | 3.0 |
Comparison of the radioactivity of phosphogypsum collected from the former Wizów Chemical Plant, Poland, to phosphogypsum from other countries
| Country/Radioisotope | Activity concentration (Bq/kg) | ||||
|---|---|---|---|---|---|
| 226Ra | 232Th | 238U | 40K | Reference | |
| Spain | 670 | 2 | 220 | 39 | [13] |
| Egypt | 459 | 40 | 140 | 2 | [14] |
| USA (Florida) | 1140 | 2 | 130 | 14 | [15] |
| Tunisia | 188 | 2 | 600 | 3 | [16] |
| Serbia | 600 | 3 | – | 47 | [16] |
| Croatia | 811 | 8 | – | 13 | [16] |
| Czech Republic | 115 | 31 | – | 95 | [16] |
| Morocco | 160 | 20 | 190 | 10 | [17] |
| Togo | 100 | 13 | 150 | 3 | [16] |
| Greece | 573 | 2.2 | 29 | 562.4 | [18] |
| Worldwide range | 162–5126 | 2.1–35.2 | 15–60 | 15–1410 | [17, 18] |
| Poland, Wizów | 77.44 | 25.96 | 4.73 | 0.13 | Current study |