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Recent upgrading of the nanosecond pulse radiolysis setup and construction of laser flash photolysis setup at the Institute of Nuclear Chemistry and Technology in Warsaw, Poland Cover

Recent upgrading of the nanosecond pulse radiolysis setup and construction of laser flash photolysis setup at the Institute of Nuclear Chemistry and Technology in Warsaw, Poland

By: Tomasz Szreder  
Open Access
|Oct 2022

Figures & Tables

Fig. 1

Simplified diagram illustrating the operation principle of laser flash photolysis and pulse radiolysis with fast spectrophotometric detection.

Fig. 2

Pulse time duration recorded as the first derivative of a signal recorded at 700 nm for pulse-irradiated Ar-saturated water (solid black line); the Faraday cup signal (dashed red line), and the Cherenkov radiation recorded for pulse-irradiated Ar-saturated water at 390 nm (dotted green line).

Fig. 3

Simplified scheme of the optical pathway of the PR system in the irradiation chamber (PR IC). S – sample; F150, F75 – lenses.

Fig. 4

Optical characteristics of the cutoff filters BK-7 (solid line) and RG-5 (dash line) used in the automatic filter wheel in front of the MSH-301 monochromator. The dotted lines represent the first derivative of the transmittance T.

Fig. 5

Layout of the PR facility at the INCT.

Fig. 6

Simplified scheme of the network/communication core at the INCT PR system.

Fig. 7

Optical pathway of the monitoring light of the LFP system. S – sample; F150 – lenses.

Fig. 8

Simplified block diagram of the TSFF system communication.

Fig. 9

Graphical user interface of the Digitizer application.

Fig. 10

Algorithm of SGN(t) trace preprocessing. DetOffset is the detector offset value; ExtU(0) denotes the absolute value of the light level measured by the external device (so-called back-off system).

Fig. 11

Algorithm diagram of LIGHT(t) trace processing.

Fig. 12

Algorithm diagram for calculation of optical absorption of the investigated system based on traces recorded by the oscilloscope. U(0) is the light level calculated based on the selected range of SGN(t) prepulse trace.

Fig. 13

Examples of advanced (left) and simplified (right) user interfaces of the DeviceCtrl application.

Fig. 14

Advanced (left) and simplified (right) graphical user interface of Mnhr application.

Fig. 15

User interface of the Sqnc application.

Fig. 16

TSFF package batch script execution interface.

Fig. 17

The advanced data processing application (TSUC).

List of available detectors at the INCT PR system

Model (Manufacturer)Spectral range (nm)Rise time/time resolution (ns)Comment
R955 (Hamamatsu)160–900(1)Subnanoseconds(4)PMT detector
iSTAR A-DH720-18F-03 (Andor)180–850(2)<5ICCD detector
PDA10A (Thorlabs)200–1100(3)2.3Silicon-amplified photodiode
APD430A2/M (Thorlabs)200–1000(3)<0.88UV-enhanced, silicon avalanche photodiode
PDA10CF (Thorlabs)800–17002.3InGaAs-amplified photodiode

Description of available gratings of the MSH-301 monochromator/spectrograph

IDSpectral range (nm)Blaze (nm)Lines (g/mm)Resolution per slit size (nm/mm)Comment
1260–90050030030Intended for use with the ICCD detector; cutoff filters are required depending on the measurement range
2250–525350120015Dedicated for the PMT detector; recommended for wavelengths <525 nm; a BK-7 cutoff filter is required for wavelengths >415 nm
3520–1200750120015Dedicated for the PMT detector; recommended for wavelengths >525 nm; RG-5 filter is required for wavelengths >685 nm

Description of SpectraPro 275 monochromator gratings

IDRange of application (nm)Blaze (nm)Lines (g/mm)Resolution per slit size (nm/mm)Comment
1200–310250180030
2310–570500120010BK-7 cutoff filter (or its equivalent) should be used at wavelengths >415 nm
3550–1200100060020RG-5 filter (or its equivalent) should be used at wavelengths >685 nm

Description of types of data time traces collected by Digitizer application

Type of traceIncident beamMonitoring light shutterDescription
SGN(t)ONONThis trace carries the main information about the chemical/physical changes of the irradiated sample.
LIGHT(t)OFFONTrace carries information about the shape of the monitoring light. It is optionally used to correct the resulting output for time-dependent monitoring of light fluctuations.
PULSE(t)ONOFFResponse of the detection system on the incident beam pulse. Important for elimination of emission of sample from absorption output data.
NOISE(t)OFFOFFResponse of detection system on electromagnetic noise generated due to triggering of high-energy incident pulse. In general, it is used for diagnostic purpose or automatic measurement of optical detector offset current. In some cases, it can be used to eliminate electromagnetic, reproducible noise from the detector output (if it is not possible to eliminate noise by hardware handling).
DOI: https://doi.org/10.2478/nuka-2022-0005 | Journal eISSN: 1508-5791 | Journal ISSN: 0029-5922
Language: English
Page range: 49 - 64
Submitted on: Jul 28, 2022
|
Accepted on: Aug 16, 2022
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Published on: Oct 8, 2022
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2022 Tomasz Szreder, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.