Have a personal or library account? Click to login
Influence of alpha and gamma radiolysis on Pu retention in the solvent TBP/kerosene Cover

Influence of alpha and gamma radiolysis on Pu retention in the solvent TBP/kerosene

Open Access
|Dec 2014

References

  1. 1. Mincher, B. J., Modolo, G., & Mezyk, S. P. (2009). The effects of radiation chemistry on solvent extraction: 1. Conditions in acidic solution and a review of TBP radiolysis. Solvent Extr. Ion Exch., 27(1), 1-25. DOI: 10.1080/07366290802544767.10.1080/07366290802544767
  2. 2. Tahraoui, A., & Morris, J. H. (1995). Decomposition of solvent extraction media during nuclear reprocessing: Literature review. Sep. Sci. Technol., 30(13), 2603-2630. DOI: 10.1080/01496399508013706.10.1080/01496399508013706
  3. 3. Schulz, W. W., & Navratil, J. D. (1987). Science and technology of tributyl phosphate. Boca Raton, FL, USA: CRC Press, Inc.
  4. 4. Burr, J. G. (1958). The radiolysis of tributyl phosphate. Radiat. Res., 8(3), 214-221. DOI: 10.2307/3570477. 10.2307/3570477
  5. 5. Burger, L. L., & McClanahan, E. D. (1958). Gamma radiolysis. Tributyl phosphate and its diluent systems. Ind. Eng. Chem., 50(2), 153-156. DOI: 10.1021/ ie50578a025.
  6. 6. Wagner, R. M., Kinderman, E. M., & Towle, L. H. (1959). Radiation stability of organophosphorus compounds. Ind. Eng. Chem., 51(1), 45-46. DOI: 10.1021/ie50589a033.10.1021/ie50589a033
  7. 7. Wilkinson, R. W., & Williams, T. F. (1961). The radiolysis of tri-n-alkyl phosphates. J. Chem. Soc., 4098-4107. DOI: 10.1039/JR9610004098.10.1039/jr9610004098
  8. 8. Hardy, C. J., & Scargill, D. (1961). Studies on monoand di-n-butylphosphoric acids-III. The extraction of zirconium from nitrate solution by di-n-butylphosphoric acid. J. Inorg. Nucl. Chem., 17(3/4), 337-349. DOI: 10.1016/0022-1902(61)80160-7.10.1016/0022-1902(61)80160-7
  9. 9. Haase, K. D., Schulte-Frohlinde, D., Kouřīm, P., & Vacek, K. (1973). Low-temperature radiolysis of organic phosphates studied by electron spin resonance. Int. J. Radiat. Phys. Chem., 5(4), 351-360. DOI: 10.1016/0020-7055(73)90060-0.10.1016/0020-7055(73)90060-0
  10. 10. Jin, H., Wu, J., Zhang, X., Fang, X., Yao, S., Zuo, Z., & Lin, N. (1999). The examination of TBP excited state by pulse radiolysis. Radiat. Phys. Chem., 54(3), 245-251. DOI: 10.1016/S0969-806X(98)00198-4.10.1016/S0969-806X(98)00198-4
  11. 11. Canva, J. (1965). Effects of protection and of sensibilization in the radiolytic decomposition of phosphate tributyl. Radiochim. Acta, 4(2), 88-91. DOI: 10.1524/ract.1965.4.2.88.10.1524/ract.1965.4.2.88
  12. 12. Barelko, E. P., Solyanina, I. P., & Tsvetkova, Z. I. (1966). Radiation-chemical stability of TBP in solutions of hydrocarbons. Atom. Energy, 21(4), 946-950. DOI: 10.1007/BF01885923.10.1007/BF01885923
  13. 13. Bellido, A. V., & Rubenich, M. N. (1984). Infl uence of the diluents on the radiolytic degradation of TBP in TBP, 30%(v/v)-diluent-HNO3 systems. Radiochim. Acta, 36(1/2), 61-64. DOI: 10.1524/ ract.1984.36.12.61.10.1524/ract.1984.36.12.61
  14. 14. Blanco, R. E., Blake, C. A. Jr., Davis, W. Jr., & Rainey, R. H. (1963). Survey of recent developments in solvent extraction with tributyl phosphate. Oak Ridge: Oak Ridge National Laboratory. (ORNL-TM-527).10.2172/4755206
  15. 15. Egorov, G. F., Tkhorzhnitskii, G. P., Zilberman, B. Ya., Shmidt, O. V., & Goletskii, N. D. (2005). Radiation chemical behavior of tributyl phosphate, dibutylphosphoric acid, and its zirconium salt in organic solutions and two-phase systems. Radiochemistry, 47(4), 392-397. DOI: 10.1007/s11137-005-0108-4.10.1007/s11137-005-0108-4
  16. 16. Stieglitz, L., & Becker, R. (1985). Chemische und radiolytische Solventzersetzung im PUREX-prozeß. Kerntechnik, 46, 76-80.
  17. 17. Brodda, B. G., & Heinen, D. (1977). Solvent performance in THTR nuclear fuel reprocessing. Part II. On the formation of dibutyl phosphoric acid by radiolytic and hydrolytic degradation of the TBP-n-paraffi n extractant. Nucl. Technol., 34(3), 428-437.
  18. 18. Peterman, D. R., Mincher, B. J., Riddle, C. L., & Tillotson, R. D. (2010). Summary report on gamma radiolysis of TBP/n-dodecane in the presence of nitric acid using the radiolysis/hydrolysis test loop. Idaho Falls: Idaho National Laboratory. (INL/EXT-10-19866).10.2172/993164
  19. 19. Aneheim, E., Ekberg, C., Fermvik, A., Foreman, M. R. St. J., Grüner, B., Hájková, Z., & Kvičalová, M. (2011). A TBP/BTBP-based GANEX separation process - Part 2: Ageing, hydrolytic, and radiolytic stability. Solvent Extr. Ion Exch., 29(2), 157-175. DOI: 10.1080/07366299.2011.539462.10.1080/07366299.2011.539462
  20. 20. Becker, R., Stieglitz, L., & Bautz, H. (1983). Untersuchung der strahlenchemischen TBP-Zersetzung unter den Bedingungen des PUREX-Prozesses. Karlsruhe: Kernforschungszentrum. (KfK-3639).
  21. 21. Tallent, O. K., Mailen, J. C., & Pannell, K. D. (1980). Purex diluent degradation. Oak Ridge: Oak Ridge National Laboratory. (ORNL/TM-8814).
  22. 22. Baroncelli, F., & Grossi, G. (1965). The complexing power of hydroxamic acids and its effect on the behaviour of organic extractants in the reprocessing of irradiated fuels. I. The complexes between benzohydroxamic acid and zirconium, iron(III) and uranium(VI). J. Inorg. Nucl. Chem., 27(5), 1085-1092. DOI: 10.1016/0022-1902(65)80420-1.10.1016/0022-1902(65)80420-1
  23. 23. Becker, R., Baumgartner, F., & Stieglitz, L. (1977). Identifi cation of complexing radiolytic products of the purex systems (20% TBP-dodecane-HNO3). Karlsruhe: Kernforschungszentrum. (KfK-2304).
  24. 24. Becker, R., & Stieglitz, L. (1973). Untersuchung der Zersetzungsprodukte im System 20% vol. Tributylphosphat- Dodekan-Salpetersäure. Karlsruhe: Kernforschungszentrum. (KfK-1373).
  25. 25. Barney, S. G., & Bouse, D. G. (1977). Alpha radiolysis of tributyl phosphate-effect of diluents. Richland, WA: Atlantic Richfi eld Hanford Company. (ARH-ST-153).10.2172/7300558
  26. 26. Lloyd, M. H., & Fellows, R. L. (1985). Alpha radiolysis and other factors affecting hydrolysis of tributyl phosphate. Oak Ridge: Oak Ridge National Laboratory. (ORNL/TM-9565).10.2172/5534740
  27. 27. Cong, H. F., Li, H. B., Su, Z., Yuan, J. Q., Liu, Z. Y., Song, F. L., Wang, X. R., & Lin, C. S. (2013). α-Radiolysis behavior of 30% TBP-kerosene-HNO3 extraction system I. Analysis of DBP and MBP in radiolysis products. J. Nucl. Radiochem., 35(4), 222-227. DOI: 10.7538/hhx.2013.35.04.0222.
  28. 28. Su, Z., Li, H. B., Cong, H. F., Song, F. L., Yuan, J. Q., Liu, Z. Y., Wang, X. R., & He, H. (2013). α-Radiolysis behavior of 30% TBP-kerosene-HNO3 extraction system II. Formation of carbonyl compounds of solvent radiolysis. J. Nucl. Radiochem., 35(5), 270-274. DOI: 10.7538/hhx.2013.35.05.0270.
  29. 29. Fermvik, A. (2011). Comparison of the effect of alpha and gamma radiolysis on the extraction of americium by C5-BTBP in cyclohexanone. J. Radioanal. Nucl. Chem., 289(3), 811-817. DOI: 10.1007/s10967-011-1163-2.10.1007/s10967-011-1163-2
  30. 30. Mincher, B. J., Mezyk, S. P., Groenewold, G., & Elias, G. (2011). A comparison of the alpha and gamma radiolysis of CMPO. Idaho Falls: Idaho National Laboratory. (INL/EXT-11-22543).10.2172/1027928
  31. 31. Mezyk, S. P., Mincher, B. J., Ekberg, C., & Skarnemark, G. (2013). Alpha and gamma radiolysis of nuclear solvent extraction ligands used for An(III) and Ln(III) separations. J. Radioanal. Nucl. Chem., 296(2), 711-715. DOI: 10. 1007/s10967-012-2036-z.10.1007/s10967-012-2036-z
  32. 32. Sharpe, P. H. G., Miller, A., & Bjergbakke, E. (1990). Dose rate effects in the dichromate dosimeter. Int. J. Radiat. Appl. Instrum., Part C Radiat. Phys. Chem., 35(4/6), 757-761. DOI: 10.1016/1359-0197(90)90311-5.10.1016/1359-0197(90)90311-5
  33. 33. Gao, Y., Zheng, W. F., Cao, X. M., & Chen, S. L. (2014). Gamma and alpha radiolysis of TBP solvent. Nucl. Sci. Tech., 25, S10310. DOI: 10.13538/j.1001-8042/nst.25.S10310.
DOI: https://doi.org/10.2478/nuka-2014-0024 | Journal eISSN: 1508-5791 | Journal ISSN: 0029-5922
Language: English
Page range: 123 - 128
Submitted on: May 24, 2014
Accepted on: Oct 23, 2014
Published on: Dec 30, 2014
Published by: Institute of Nuclear Chemistry and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2014 Yang Gao, Weifang Zheng, Xiaoming Cao, Shaolei Chen, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.