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Synergistic emulsification of polyetheramine/nanofluid system as a novel viscosity reducer of acidic crude oil Cover

Synergistic emulsification of polyetheramine/nanofluid system as a novel viscosity reducer of acidic crude oil

By: Yang Cao,  Yanlin Guo,  Tao Wu and  Dejun Sun  
Open Access
|Mar 2024

Figures & Tables

Fig. 1.

Effect of AEG concentration on viscosity (A) and stability (B) of acidic crude oil, and the appearance of 1# crude oil emulsion prepared with AEG concentrations of 0.1% and 1.0% after standing for 5 min (C)
Effect of AEG concentration on viscosity (A) and stability (B) of acidic crude oil, and the appearance of 1# crude oil emulsion prepared with AEG concentrations of 0.1% and 1.0% after standing for 5 min (C)

Fig. 2.

Effect of S1O2 concentration on stability of acidic crude oil 1# (A); the appearance of 2# ordinary crude oil emulsion after standing for 30 min (B) Notes: In panel (B), the 2# ordinary crude oil emulsion showed good stability and no obvious creaming phenomenon after standing for 30 min
Effect of S1O2 concentration on stability of acidic crude oil 1# (A); the appearance of 2# ordinary crude oil emulsion after standing for 30 min (B) Notes: In panel (B), the 2# ordinary crude oil emulsion showed good stability and no obvious creaming phenomenon after standing for 30 min

Fig. 3.

Effect of D230 concentration on viscosity (A) and stability (B) of acidic crude oil emulsion, and appearance of viscosity reducing agent emulsion crude oil emulsion prepared by polyetheramine with different concentration (C)
Effect of D230 concentration on viscosity (A) and stability (B) of acidic crude oil emulsion, and appearance of viscosity reducing agent emulsion crude oil emulsion prepared by polyetheramine with different concentration (C)

Fig. 4.

Interfacial tension (IFT) between different components and acidic crude oil emulsions
Interfacial tension (IFT) between different components and acidic crude oil emulsions

Fig. 5.

Effect of of SiO2 nanoparticles hydrophobicity and size on emulsion stability of acidic crude oil Notes: (A) Hydrophobic SiO2 nanoparticles R805 and R974, exhibited ineffective to emulsify acidic crude oil; (B) Microscopic images of hydrophobic SiO2 nanoparticle R805 and R974 failed to emulsify crude oil; (C) Microscopic images of hydrophilic SiO2 nanoparticle A200 and MZ32090 emulsified crude oil; (D) dehydration rate of hydrophilic SiO2 nanoparticles A200 and MZ32090 emulsified crude oil. A lower dehydration rate indidated a higher stability
Effect of of SiO2 nanoparticles hydrophobicity and size on emulsion stability of acidic crude oil Notes: (A) Hydrophobic SiO2 nanoparticles R805 and R974, exhibited ineffective to emulsify acidic crude oil; (B) Microscopic images of hydrophobic SiO2 nanoparticle R805 and R974 failed to emulsify crude oil; (C) Microscopic images of hydrophilic SiO2 nanoparticle A200 and MZ32090 emulsified crude oil; (D) dehydration rate of hydrophilic SiO2 nanoparticles A200 and MZ32090 emulsified crude oil. A lower dehydration rate indidated a higher stability

Fig. 6.

Influence of different alkali type on stability of acidic crude oil emulsion
Influence of different alkali type on stability of acidic crude oil emulsion

Fig. 7.

Effect of salinity on emulsion stability of acidic crude oil
Effect of salinity on emulsion stability of acidic crude oil

Fig. 8.

Measurement of contact angles of quartz with different wettability
Measurement of contact angles of quartz with different wettability

Fig. 9.

Core imbibition simulation experiment artificial immersed at 50◦C for 15 days
Core imbibition simulation experiment artificial immersed at 50◦C for 15 days

Imbibition recovery rate of artificial core

Viscosity reducer immersionFormation water immersion
Saturation (%)78.574.0
Recovery rate (%)49.429.6

Basic properties of crude oil used in this study

SamplesViscosity (mPa·s)Acid value (mg KOH/g)Saturate, aromatic, resin, and asphaltene (SARA) composition (%)Moisture content (%)
25◦C50◦C SaturateAromaticResinAsphaltene
1#5221268622.2734.0735.2027.633.1010
2#2149424580.4339.0832.4723.315.1421

Influence of SiO2 nanoparticles on viscosity of acidic crude oil emulsion

Nanoparticles typeDiameter (nm)Surface wettability (water contact angle)Viscosity (mPa·s)
A2001218.2◦135.9
MZ320903030.5◦134.7
R97412117.2◦
R80512131.3◦

Effect of salinity on viscosity of acidic crude oil emulsion

Total salinity (mg/L)Deionized waterNaClCaCl2Simulated formation water
NA50001000020000300005000050005722
Viscosity (mPa·s)123281221153223114128

Effect of alkali type on viscosity of acidic crude oil emulsion

Types of alkalipH of viscosity reducerViscosity emulsion (mPa·s)
D40010.82109.6
D23010.89129.6
NaOH12.62133.7
DOI: https://doi.org/10.2478/msp-2023-0049 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331
Language: English
Page range: 107 - 119
Submitted on: Aug 25, 2023
Accepted on: Feb 27, 2024
Published on: Mar 27, 2024
Published by: Wroclaw University of Science and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2024 Yang Cao, Yanlin Guo, Tao Wu, Dejun Sun, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.