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Study on the effect of nanosilica suspension on the properties of cement-based grouts Cover

Study on the effect of nanosilica suspension on the properties of cement-based grouts

By: Shuiping Li,  Wei Chao,  Wei Li,  Jian Cheng and  Bin Yuan  
Open Access
|May 2023

Figures & Tables

Fig. 1

Picture of suspension for different days. a3—unmodified nanosilica particle solution; b3—nanosilica suspension (γ-(2,3-epoxypropoxy)propytrimethosysilane was used as a silane coupler); c3—nanosilica suspension (methacryloxy propyl trimethoxyl silane was used as a silane coupler)
Picture of suspension for different days. a3—unmodified nanosilica particle solution; b3—nanosilica suspension (γ-(2,3-epoxypropoxy)propytrimethosysilane was used as a silane coupler); c3—nanosilica suspension (methacryloxy propyl trimethoxyl silane was used as a silane coupler)

Fig. 2

The influence of unmodified nanosilica particles on compressive strength of hardened grouts
The influence of unmodified nanosilica particles on compressive strength of hardened grouts

Fig. 3

The influence of nanosilica particles content on the compressive strength of hardened grouts
The influence of nanosilica particles content on the compressive strength of hardened grouts

Fig. 4

The influences of silane ratio in suspension on compressive strength of hardened grouts
The influences of silane ratio in suspension on compressive strength of hardened grouts

Fig. 5

The influences of PCE ratio in suspension on compressive strength of hardened grouts
The influences of PCE ratio in suspension on compressive strength of hardened grouts

Fig. 6

(A) The TG and differential thermal analysis (DTA) curves of specimens with 0 wt% nanosilica particles for 1 day of curing. (B) The TG and DTA curves of specimens with 0.5 wt% nanosilica particles for 1 day of curing. TG, thermogravimetric
(A) The TG and differential thermal analysis (DTA) curves of specimens with 0 wt% nanosilica particles for 1 day of curing. (B) The TG and DTA curves of specimens with 0.5 wt% nanosilica particles for 1 day of curing. TG, thermogravimetric

Fig. 7

(A) The TG and DTA curves of specimens with 0 wt% nanosilica particles for 28 days of curing. (B) The TG and DTA curves of specimens with 0.5 wt% nanosilica particles for 28 days of curing. TG, thermogravimetric
(A) The TG and DTA curves of specimens with 0 wt% nanosilica particles for 28 days of curing. (B) The TG and DTA curves of specimens with 0.5 wt% nanosilica particles for 28 days of curing. TG, thermogravimetric

Fig. 8

(A) The SEM micrographs of cement grouts with 0 wt% nanoparticles for 1 day of curing. (B) The SEM micrographs of cement grouts with 0.5 wt% unmodified nanoparticles for 1 day of curing. (C) The SEM micrographs of cement grouts with 0.5 wt% nanoparticles for 1 day of curing. (D) The SEM micrographs of cement grouts with 0 wt% nanoparticles for 28 days of curing. (E) The SEM micrographs of cement grouts with 0.5 wt% unmodified nanoparticles for 28 days of curing. (F) The SEM micrographs of cement grouts with 0.5 wt% nanoparticles for 28 days of curing
(A) The SEM micrographs of cement grouts with 0 wt% nanoparticles for 1 day of curing. (B) The SEM micrographs of cement grouts with 0.5 wt% unmodified nanoparticles for 1 day of curing. (C) The SEM micrographs of cement grouts with 0.5 wt% nanoparticles for 1 day of curing. (D) The SEM micrographs of cement grouts with 0 wt% nanoparticles for 28 days of curing. (E) The SEM micrographs of cement grouts with 0.5 wt% unmodified nanoparticles for 28 days of curing. (F) The SEM micrographs of cement grouts with 0.5 wt% nanoparticles for 28 days of curing

Chemical composition of Portland cement, fly ash, and slag powder (wt%)

ConstituentCaOSiO2Al2O3Fe2O3MgONa2OSO3Loss
Cement63.7120.355.03.31.370.392.482.6
Fly ash2.461.928.82.50.80.30.61.7
Slag powder38.130.013.60.67.60.30.34.6

Performance indices of Portland cement

IndicesDensity (g/cm3)Consistence (%)Stability> 80 μmSpecific surface area (m2/kg)Setting time (min)Compressive strength (MPa)

1 day3 days28 days
Cement3.0821.35Qualified1.834016019522.137.462.6

The influences of unmodified nanosilica, nanosilica suspension, silane coupler, and PCE content on the setting times of grouting pastes

CompositionContent (wt%)Setting time (min)

InitialFinal
Reference0660 ± 15750 ± 20
Unmodified nanosilica (nanosilica/binder)0.2580 ± 20660 ± 25
0.5500 ± 15570 ± 20
0.8460 ± 10540 ± 20
1410 ± 20470 ± 15
1.5340 ± 15420 ± 20
2270 ± 10350 ± 15
Nanosilica suspension (nanosilica/binder)0.2640 ± 30710 ± 25
0.5590 ± 25660 ± 20
0.8560 ± 25630 ± 15
1650 ± 30720 ± 20
1.5940 ± 401,010 ± 35
21,590 ± 501,660 ± 40
Silane coupler (silane/nanosilica)0500 ± 20580 ± 20
4540 ± 15620 ± 15
10590 ± 20670 ± 25
20910 ± 30990 ± 30
301,810 ± 451,880 ± 35
PCE (PCE/nanosilica)0540 ± 10620 ± 15
4560 ± 15640 ± 20
10580 ± 20650 ± 15
20600 ± 15670 ± 10
30620 ± 10700 ± 20

The effects of unmodified nanosilica, nanosilica suspension, silane coupler, and PCE content on the fluidity of grouting pastes

CompositionContent (wt%)Fluidity (mm)

Initial30 min
Reference0350 ± 4325 ± 3
Unmodified nanosilica (nanosilica/binder)0.2355 ± 3325 ± 5
0.5335 ± 6200 ± 2
0.8280 ± 2180 ± 3
1.0250 ± 3150 ± 4
1.5200 ± 2130 ± 4
2.0150 ± 3120 ± 2
Nanosilica suspension (nanosilica/binder)0.2350 ± 6345 ± 3
0.5345 ± 5335 ± 4
0.8335 ± 5320 ± 5
1.0330 ± 4300 ± 3
1.5310 ± 3200 ± 2
2.0295 ± 3165 ± 2
Silane coupler (silane/nanosilica)0320 ± 4230 ± 3
4330 ± 4320 ± 2
10350 ± 3345 ± 5
20355 ± 4355 ± 4
30355 ± 5355 ± 3
PCE (PCE/nanosilica)0340 ± 3315 ± 4
4350 ± 5325 ± 3
10355 ± 3330 ± 2
20350 ± 4330 ± 4
30345 ± 2330 ± 3
DOI: https://doi.org/10.2478/msp-2022-0054 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331
Language: English
Page range: 171 - 182
Submitted on: Jan 28, 2023
Accepted on: Mar 23, 2023
Published on: May 6, 2023
Published by: Wroclaw University of Science and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2023 Shuiping Li, Wei Chao, Wei Li, Jian Cheng, Bin Yuan, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.