Effect of fuel type on the combustion reaction behavior, phase structure and morphology of Ni0.5Co0.5Fe2O4 nanoparticles

Arman Sedghi; Elham Akbari Salehkooh; Monireh Chadorbafzade

doi:10.2478/msp-2020-0024

Abstract

Nickel-cobalt ferrite spinels are ferrimagnetic ceramic materials that possess a great potential for application in highdensity magnetic media, recording, color imaging, ferrofluids, and high-frequency devices. A change of their structure from micro- to nano- improves their properties drastically, therefore many methods have been investigated to fabricate nanopowder of these spinels. Gel combustion method is one of them. In this research, Ni_{0 5}Co_{0 5}Fe₂O₄ nanoparticles were fabricated via gel combustion method using metallic nitrates as an oxidant and citric acid, glycine and urea as fuels and the effects of fuel type on the reaction behavior, structure and morphology of Ni_{0 5}Co_{0 5}Fe₂O₄ nanoparticles were investigated. The reaction behavior was studied by thermal analysis method (TGA-DTA), crystallite size of powders was characterized by X-ray diffraction (XRD) and their morphology was studied by FE-SEM. The results revealed that the reaction was initiated in urea, glycine and citric at 219 °C, 197 °C, 212 °C, respectively. Samples fabricated from glycine and citric acid had a pure spinel structure but the others fabricated with urea fuel had iron oxide impurity. The crystallite size of nickel cobalt ferrite nanoparticles was in the range of 58 nm to 64 nm and the nanoparticles were agglomerated.

References

[1] Bhattacharyya S., Salvetat J., Fleurier R., Husmann A., Cacciaguerraa T., Saboungia M., J. Chem. Commun., (2005), 4818.10.1039/b509026a16193125
Search in Google Scholar Back to article
[2] Shobana M.K., Sankar S., J. Magnetism and Magnetic Materials., 321 (2009), 3132.10.1016/j.jmmm.2009.05.018
Search in Google Scholar Back to article
[3] Yonglian QI., Yingsheng Y., Zhao X., Xilan L., Peng W., Fazhi Z., Sailong X., J. Particuology., 8 (2010), 207.10.1016/j.partic.2010.03.008
Search in Google Scholar Back to article
[4] Mathe V.L., Sheikh A.D., J. Physica., 405 (2010), 3594.10.1016/j.physb.2010.05.047
Search in Google Scholar Back to article
[5] Zhang C.S., J. Magnetism and Magnetic Materials., 324 (2012), 1469.10.1016/j.jmmm.2011.09.036
Search in Google Scholar Back to article
[6] Deraz N.M., J. Analytical and Applied Pyrolysis., 88 (2010), 103.10.1016/j.jaap.2010.03.002
Search in Google Scholar Back to article
[7] El-Okr M.M., Salem M.A., Salim M.S., El-Okr R.M., Ashoushet M., Talaat H.M., J. Magnetism and Magnetic Materials., 323 (2011), 920.10.1016/j.jmmm.2010.11.069
Search in Google Scholar Back to article
[8] Ahlawat A., Reddy V.R., Gupta A., J. Magnetism and Magnetic Materials., 323 (2011), 2049.10.1016/j.jmmm.2011.03.017
Search in Google Scholar Back to article
[9] Zhenxing Y., Wenyu G., Ji Z., Zhilun G., Logtu L., J. Magnetism and Magnetic Materials., 270 (2004), 216.
Search in Google Scholar Back to article
[10] Deganello F., Mard G., Deganello G., J. the European Ceramic Society., 29 (2009), 439.10.1016/j.jeurceramsoc.2008.06.012
Search in Google Scholar Back to article
[11] Pui A., Gherca D., Carja G., J. Nanomaterials and Biostructures., Vol. 6, No 4, (2011), 1783.
Search in Google Scholar Back to article
[12] Shelar M.B., Jadhav P.A., Chougule S.S., Mallapur M.M., Chougule B.K., J. Alloys and Compounds., 476 (2009), 760.10.1016/j.jallcom.2008.09.107
Search in Google Scholar Back to article
[13] Waje S., Hashim M., Ismail I., J. Magnetism and Magnetic Materials., 323 (2011), 1433.
Search in Google Scholar Back to article
[14] Singhal S., Singh J., Barthwai S.K., Chandra K., J. Solid State Chemistry., 178 (2005), 3183.10.1016/j.jssc.2005.07.020
Search in Google Scholar Back to article
[15] Lezhong L., Long P., Yuanxun L. Xinghua Z., J. Magnetism and Magnetic Materials., 324 (2012), 60.
Search in Google Scholar Back to article
[16] Wu K.H., Ting T.H., Li M.C., Ho W.D., J. Magnetism and Magnetic Materials., 298 (2006), 25.10.1016/j.jmmm.2005.03.008
Search in Google Scholar Back to article
[17] Costa A., Silva V., Xin C., Vieira D., Cornejo D., Kiminami R., J. Alloys and Compounds., 495 (2010), 503.10.1016/j.jallcom.2009.10.065
Search in Google Scholar Back to article
[18] Prabhakaran T., Hemalatha J., J. Alloys and Compounds., 509 (2011), 7071.10.1016/j.jallcom.2011.03.176
Search in Google Scholar Back to article
[19] Gonsalves L., Mojumdar S., Verenkar V., J. Thermal Analysis and Calorimetry., (2010), 789.10.1007/s10973-010-0719-7
Search in Google Scholar Back to article
[20] Bahadur D., Rajakumar S., Kumar A., J. Chemical Science., Vol. 118, No. 1, (2006), 15.10.1007/BF02708761
Search in Google Scholar Back to article
[21] Ramalho M.A.F., Gama L., Antonio S.G., Paiva Santos C.O., Miola E.J., Kiminami R.H.G.A., J. Material Science., (2007), 3603.10.1007/s10853-006-0383-2
Search in Google Scholar Back to article
[22] Baykal A., Kasapoglu N., Koseoglu Y., Basaran A., Kavas H., Toprak M., J. Chemistry., 6(1) (2008), 125.
Search in Google Scholar Back to article
[23] Costa A.C.F.M., Morelli M.R., Kiminami R.H.G.A., J. Materials Synthesis and Processing., (2001), 347.10.1023/A:1016356623401
Search in Google Scholar Back to article
[24] Costa A.C.F.M., Lula R.T., Kiminami R.H.G.A., Gama L.F.V., de Jesus A.A., Andrade H.M.C., J. Material Science., (2006), 4871.10.1007/s10853-006-0048-1
Search in Google Scholar Back to article
[25] Waje S., Hashim M., Yusoff W., Daud W., Abbas Z., J. nanoparticle., 25 (2011), 1225.10.1142/S0217979211058626
Search in Google Scholar Back to article
[26] Salunkhe A.B., Khot V.M., Phadatare M.R., Pawar S.H., J. Alloys and Compounds., 514 (2012), 91.10.1016/j.jallcom.2011.10.094
Search in Google Scholar Back to article
[27] Jakubovics J.P., Magnetism and Magnetic Materials, Brookfield, London, 1987.
Search in Google Scholar Back to article
[28] Toksha B.G., Shirsath S., Patange S., Jadhav K., J Solid State Communications., 147 (2008), 479.10.1016/j.ssc.2008.06.040
Search in Google Scholar Back to article

Effect of fuel type on the combustion reaction behavior, phase structure and morphology of Ni0.5Co0.5Fe2O4 nanoparticles

Abstract

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