Methods of increasing the fire resistance of paper products

M. Nováková; M. Ďurovič

doi:10.2478/kom-2020-0015

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Methods of increasing the fire resistance of paper products

Koroze a ochrana materiálu

Volume 64 (2020): Issue 3 (October 2020)

By: M. Nováková and M. Ďurovič

Open Access

|Dec 2020

Abstract

The search deals with the possibilities of increasing the fire resistance of paper, cardboard or paperboard. The article includes the principles of fire retardancy as well as requirements for a suitable preparation and lists substances and mixtures which, according to the literature, are/were used in the manufacturing process or after-treatment of paper products. The article is also continuously supplemented by examples from the patent literature.

References

1. Joseph, P.; Tretsiakova-McNally, S.: Chemical modification of natural and synthetic textile fibres to improve flame retardancy. In Handbook of Fire Resistant Textiles, 1st ed.; Kilinc, F. S., Ed.; Woodhead Publishing: Cambridge, 2013; pp 37–67.10.1533/9780857098931.1.37
Search in Google Scholar Back to article
2. Nováková, M.: Retardéry hoření pro archivní lepenky. diplomová práce, VŠCHT Praha, 2016.
Search in Google Scholar Back to article
3. Rowell, R. M.; LeVan-Green, S. L.: Thermal Properties. In Handbook of Wood Chemistry and Wood Composites, 1st ed.; Rowell, R. M., Ed.; Taylor & Francis: Boca Raton, 2005; pp 121–138.10.1201/9780203492437
Search in Google Scholar Back to article
4. Yang, C. Q.: Flame resistant cotton. In Handbook of Fire Resistant Textiles, 1st ed.; Kilinc, F. S., Ed.; Woodhead Publishing: Cambridge, 2013; pp 177–220.10.1533/9780857098931.2.177
Search in Google Scholar Back to article
5. Yang, H.; Yan, R.; CHen, H.; Lee, D. H.; Zheng, Ch.: Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel2007, 86 (12-13), 1781–1788.10.1016/j.fuel.2006.12.013
Search in Google Scholar Back to article
6. Shafizadeh, F.; A. G. W. Bradbury: Thermal degradation of cellulose in air and nitrogen at low temperatures. Journal of Polymer Science1979, 23 (5), 1431–1442.10.1002/app.1979.070230513
Search in Google Scholar Back to article
7. Pielichowski, K.; Njuguna, J.: Thermal Degradation of Polymeric Materials, 1st ed.; Rapra Technology Limited: Shawbury, 2005.10.1016/B978-0-12-823023-7.00014-9
Search in Google Scholar Back to article
8. Alongi, J.; Malucelli, G.: Cotton flame retardancy: state of the art and future perspectives. RSC Advances2015, 5 (31), 24239–24263.10.1039/C5RA01176K
Search in Google Scholar Back to article
9. Shafizadeh, F.: The Chemistry of Pyrolysis and Combustion. In The Chemistry of Solid Wood; Rowell, R., Ed.; American Chemical Society: Washington, DC, 1984; Vol. 207, pp 489–529.10.1021/ba-1984-0207.ch013
Search in Google Scholar Back to article
10. Krčma, L.: Degradace textilních vláken a ochrana proti ní, 1st ed.; SNTL: Praha, 1976.
Search in Google Scholar Back to article
11. Netopilová, M.: Materiály: Stavební materiály, 1st ed.; Sdružení požárního a bezpečnostního inženýrství v Ostravě: Ostrava, 2004.
Search in Google Scholar Back to article
12. Bajpai, P.: Pulp and Paper Industry – Chemicals, 1st ed.; Elsevier, 2015.10.1016/B978-0-12-803408-8.00001-9
Search in Google Scholar Back to article
13. Shen, K. K.; Kochesfahani, S. H.; Jouffret, F.: Boron-Based Flame Retardants and Flame Retardancy. In Fire Retardancy of Polymeric Materials, 2nd ed.; Wilkie, Ch. A., Morgan, A. B., Eds.; CRC Press: Boca Raton: 2009; pp 207–237.10.1201/9781420084009-c9
Search in Google Scholar Back to article
14. Alongi, J.; Malucelli, G.: Thermal Degradation of Cellulose and Cellulosic Substrates. In Reactions and Mechanisms in Thermal Analysis of Advanced Materials; Tiwari, A., Raj, B., Eds.; John Wiley & Sons: USA, 2015; pp 301–332.10.1002/9781119117711.ch14
Search in Google Scholar Back to article
15. Shen, K. K.: Review of Recent Advances on the Use of Boron-based Flame Retardants. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 367–388.10.1016/B978-0-444-53808-6.00011-1
Search in Google Scholar Back to article
16. Kupilík, V.: Stavební konstrukce z požárního hlediska; Grada Publishing a.s.: Praha, 2006.
Search in Google Scholar Back to article
17. Rodová, N.; Fišer, S.; Skalický, Č.; Suchitra, Z.; Šimůnková, J.; Kacafírek, S.; Nevečeřal, K.; Kopp, J.: Samozhášivý papír. Popis vynálezu k autorskému osvědčení 252437, Aug 22, 1988.
Search in Google Scholar Back to article
18. Dong, L. Y.; Zhu, Y. J.: A New Kind of Fireproof, Flexible, Inorganic, Nanocomposite Paper and Its Application to the Protection Layer in Flame-Retardant Fiber-Optic Cables. Chemistry – A European Journal2017, 23 (19), 4597–4604.10.1002/chem.20160455227943477
Search in Google Scholar Back to article
19. Kozlowski, R. M.; Muzyczek, M.; Walentovka, J.: Flame Retardancy and protection against Biodeterioration of Natural Fibers: State-of-Art and Future Prospects. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 801–836.10.1016/B978-0-444-53808-6.00023-8
Search in Google Scholar Back to article
20. Joseph, P.; Ebdom, J.: Phosphorus-Based Flame Retardants. In Fire Retardancy of Polymeric Materials, 2nd ed.; Wilkie, Ch. A., Morgan, A. B., Eds.; CRC Press: Boca Raton: 2009; pp 107–127.10.1201/9781420084009-c5
Search in Google Scholar Back to article
21. Sutker, B. J.: Flame Retardants. In Ullmann‘s Encyclopedia of Industrial Chemistry; Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, 2012; Vol. 15, pp 53–71.
Search in Google Scholar Back to article
22. Tesoro, G. C.: Chemical Modification of Polymers with Flame-Retardant Compounds. Journal of Polymer Science: Macromolecular Reviews1978, 13 (1), 283–353.10.1002/pol.1978.230130106
Search in Google Scholar Back to article
23. ČSN EN ISO 13943. Požární bezpečnost – Slovník. Praha: Úřad pro technickou normalizaci, metrologii a státní zkušebnictví, 2011. 84 p.
Search in Google Scholar Back to article
24. Morgan, A. B.; Wilkie, Ch. A.: An Introduction to Polymeric Flame Retardancy, Its Role in Material Science, and the Current State of the Field. In Fire Retardancy of Polymeric Materials, 2nd ed.; Wilkie, Ch. A., Morgan, A. B., Eds.; CRC Press: Boca Raton: 2009; pp 1–42.10.1201/9781420084009-c1
Search in Google Scholar Back to article
25. ASTM D777-97. Standard Test Methods for Flammability of Treated Paper and Paperboard. West Conshohocken: ASTM International, 2002.
Search in Google Scholar Back to article
26. Kandola, B. K.; Horrocks, A. R.; Price, D.: Flame-Retardant Treatments of Cellulose and Their Influence on the Mechanism of Cellulose Pyrolysis. Journal of Macro-molecular Science, Part C1996, 36 (4), 721–79.10.1080/15321799608014859
Search in Google Scholar Back to article
27. Rouette, H. K.: Encyclopedia of Textile Finishing: A-F; Springer: Berlin, 2001.10.1007/978-3-642-85271-8
Search in Google Scholar Back to article
28. Levan, S. L.: Chemistry of Fire Retardancy. In The Chemistry of Solid Wood; Rowell, R., Ed.; American Chemical Society: Washington D. C., 1984; Vol. 207, pp 531–574.10.1021/ba-1984-0207.ch014
Search in Google Scholar Back to article
29. Morgan, A. B.: The Future of Flame Retardant Polymers – Unmet Needs and Likely New Approaches. Polymer Reviews2018, 59 (1), 25–54.10.1080/15583724.2018.1454948
Search in Google Scholar Back to article
30. Shen, K. K.: Boron compounds as fire retardants. In Flame Retardants 101: Basic Dynamics: Past efforts create future opportunities, Baltimore Marriott Inner Harbor Hotel, Maryland, 24.–27. 3. 1996; CRC Press: Lancaster, 1998; pp 137–143.
Search in Google Scholar Back to article
31. Ash, M.; Ash, I.: Handbook of Food Packaging Chemicals and Materials, 2nd ed.; Synapse Information Resources, Inc.: Endicott, 2008.
Search in Google Scholar Back to article
32. Ash, M.; Ash, I.: Handbook of Paper and Pulp Chemicals, 2nd ed.; Synapse Information Resources, Inc.: Endicott, 2013.
Search in Google Scholar Back to article
33. Ash, M.; Ash, I.: Specialty Chemicals – Source Book, 4th ed.; Synapse Information Resources, Inc.: Endicott, 2009.
Search in Google Scholar Back to article
34. Shen, K. K.: Boron-based Flame Retardants in Non-Halogen-based Polymers. In Non-Halogenated Flame Retardant Handbook, 1st ed.; Morgan, A. B., Wilkie, Ch. A., Eds.; Wiley-Scrivener: US, 2014; pp 201–241.10.1002/9781118939239.ch6
Search in Google Scholar Back to article
35. Humphrey, S. B.: Fire retardant paper and paper board. US patent US3770577A, Sept 23, 1969.
Search in Google Scholar Back to article
36. U.S. BORAX PRODUCTS. 20 MULE TEAM BORAX. https://www.borax.com/products (accessed May 26, 2020).
Search in Google Scholar Back to article
37. Huber, C.; Jahromy, S. S.; Birkelbach, F.; et al.: The multistep decomposition of boric acid. Energy Science & Engineering2020, 8 (5), 1650–1666.10.1002/ese3.622
Search in Google Scholar Back to article
38. Borates for fire retardancy in cellulosic materials. Technical Bulletin, 2019. 20 Mule Team® Borax. https://www.borax.com/BoraxCorp/media/Borax-Main/Resources/Technical-Bulletin/borates-fire-retardancy-cellulosic-materials.pdf?ext=.pdf. (accessed May 25, 2020).
Search in Google Scholar Back to article
39. Seznam látek vzbuzujících mimořádné obavy podléhajících povolení – Disodium octaborate. ECHA. https://echa.europa.eu/cs/candidate-list-table/-/dislist/details/0b0236e18260bc78 (accessed May 03, 2020).
Search in Google Scholar Back to article
40. Seznam látek vzbuzujících mimořádné obavy podléhajících povolení – Tetraboron disodium heptaoxide, hydrate. ECHA. https://echa.europa.eu/cs/candidate-list-table/-/dislist/details/0b0236e1807d9fd3 (accessed May 03, 2020).
Search in Google Scholar Back to article
41. Šimůnková, E.; Kučerová, I.: Dřevo, 2nd ed.; Společnost pro technologie ochrany památek: Praha, 2008.
Search in Google Scholar Back to article
42. Vail, J. G.: Soluble Silicates - Their Properties and Uses: Chemistry; American Chemical Society Monograph Series, 1–2; Reinhold Publishing Corporation: New York, 1952.
Search in Google Scholar Back to article
43. Official Gazette of the United States Patent Office, volume 17; Government Printing Office: Washington, 1880.
Search in Google Scholar Back to article
44. Lowden, L. A.; Hull, T. R.: Flammability behaviour of wood and a review of the methods for its reduction. Fire Science Reviews2013, 2 (4), 1–19.10.1186/2193-0414-2-4
Search in Google Scholar Back to article
45. Slimak, K. M.; Slimak, R. A.: Process of using sodium silicate to create fire retardant products. patent US 6,827,984 B2, Dec 07, 2004.
Search in Google Scholar Back to article
46. Svatoň, J.: Ochrana dřeva, 1st ed.; Mendelova zemědělská a lesnická univerzita v Brně: Brno, 2000.
Search in Google Scholar Back to article
47. Pélégris, Ch.; Rivenet, M.; Traisnel, M.: Intumescent Silicates: Synthesis, Characterization and Fire Protective Effect. In Fire Retardancy of Polymers: New Applications of Mineral Fillers, 1st ed.; Le Bras, M., Bourbigot, S., Duquesne, S., Jama, Ch., Wilkie, Ch., Eds.; Royal Society of Chemistry: Cambridge, 2005; Chapter 5, pp 68–78.10.1039/9781847552396-00068
Search in Google Scholar Back to article
48. Awad, W. H.: Recent Developments in Silicon-Based Fame Retardants. In Fire Retardancy of Polymeric Materials, 2nd ed.; Wilkie, Ch. A., Morgan, A. B., Eds.; CRC Press: Boca Raton: 2009; pp 187–206.10.1201/9781420084009-c8
Search in Google Scholar Back to article
49. Han, Z.; Fina, A.; Camino, G.: Organosilicon compounds as Polymer Fire Retardants. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 389–418.10.1016/B978-0-444-53808-6.00012-3
Search in Google Scholar Back to article
50. Morgan, A. B.; Gilman, J. W.: An overview of flame retardancy of polymeric materials: application, technology, and future directions. Fire and Materials2013, 37 (4), 259–279.10.1002/fam.2128
Search in Google Scholar Back to article
51. Hörold, S.: Phosphorus-based and Intumescent Flame Retardants. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 221–254.10.1016/B978-0-444-53808-6.00006-8
Search in Google Scholar Back to article
52. Hull, T. R.; Law, R. J.; Bergman, Å.: Environmental Drivers for Replacement of Halogenated Flame Retardants. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 119–179.10.1016/B978-0-444-53808-6.00004-4
Search in Google Scholar Back to article
53. Jadhav, S. D.: A review of non-halogenated flame retardant. The Pharma Innovation Journal2018, 7 (5), 380–386.
Search in Google Scholar Back to article
54. Kiliaris, P.; Papaspyrides, C. D. Polymers on Fire. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 1–43.10.1016/B978-0-444-53808-6.00001-9
Search in Google Scholar Back to article
55. Clermont, L. P.: Fire retardants for wood and paper. Patent Document 934105, Sept 25, 1973.
Search in Google Scholar Back to article
56. Ash, M.; Ash, I.: Handbook of Green Chemicals, 2nd ed.; Synapse Information Resources, Inc.: Endicott, 2008.
Search in Google Scholar Back to article
57. FR-11. ICL Industrial Products. http://www.icl-ip.com/product/fr-11/ (accessed May 06, 2020).
Search in Google Scholar Back to article
58. Bocchini, S.; Camino, G.: Halogen-Containing Flame Retardants. In Fire Retardancy of Polymeric Materials, 2nd ed.; Wilkie, Ch. A., Morgan, A. B., Eds.; CRC Press: Boca Raton: 2009; pp 75–105.10.1201/9781420084009-c4
Search in Google Scholar Back to article
59. Doversperse water dispersed chlorinated alkanes. Dover Chemical Corporation. https://www.doverchem.com/doversperse-water-dispersed-chlorinated-alkanes (accessed May 06, 2020).
Search in Google Scholar Back to article
60. The 12 initial POPs under the Stockholm Convention. Stockholm Convention. http://chm.pops.int/TheConvention/ThePOPs/The12InitialPOPs/tabid/296/Default.aspx (accessed May 27, 2020).
Search in Google Scholar Back to article
61. Sauerwein R.: Mineral Filler Flame Retardants. In Non-Halogen-based Polymers. In Non-Halogenated Flame Retardant Handbook, 1st ed.; Morgan, A. B., Wilkie, Ch. A., Eds.; Wiley-Scrivener: US, 2014; pp 75–141.10.1002/9781118939239.ch3
Search in Google Scholar Back to article
62. Rothon, R.; Hornsby, P.: Fire Retardant Fillers for Polymers. In Polymer Green Flame Retardants, 1st ed.; Papaspyrides, C. D., Kiliaris, P., Eds.; Elsevier: Amsterdam, 2014; pp 289–321.10.1016/B978-0-444-53808-6.00009-3
Search in Google Scholar Back to article
63. Hornsby, P.: Fire-Retardant Fillers. In Fire Retardancy of Polymeric Materials, 2nd ed.; Wilkie, Ch. A., Morgan, A. B., Eds.; CRC Press: Boca Raton: 2009; pp 163–185.10.1201/9781420084009-c7
Search in Google Scholar Back to article
64. Product Finder. Huber Engineered Materials. https://www.hubermaterials.com/products/product-finder.aspx?navigationid=8 (accessed May 26, 2020).10.1016/S0262-1762(20)30144-9
Search in Google Scholar Back to article

Articles in this issue

DOI: https://doi.org/10.2478/kom-2020-0015 | Journal eISSN: 1804-1213 | Journal ISSN: 0452-599X

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Language: English

Page range: 100 - 107

Published on: Dec 3, 2020

Published by: Association of Czech and Slovak Corrosion Engineers

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Related subjects:

Industrial chemistry,

Chemical engineering,

Materials sciences,

Ceramics and glass

© 2020 M. Nováková, M. Ďurovič, published by Association of Czech and Slovak Corrosion Engineers
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Volume 64 (2020): Issue 3 (October 2020)