Corrosion inhibition of mild steel using novel pyridine derivative in 1 M hydrochloric acid

A.A. Al-Amiery; L.M. Shaker

doi:10.2478/kom-2020-0009

.blurhash-client-img { display: none !important; }

Corrosion inhibition of mild steel using novel pyridine derivative in 1 M hydrochloric acid

Koroze a ochrana materiálu

Volume 64 (2020): Issue 2 (June 2020)

By: A.A. Al-Amiery and L.M. Shaker

Open Access

|Aug 2020

Abstract

A novel pyridine derivative was synthesized, and its corrosion inhibition effects on mild steel in a 1M hydrochloric acid environment were investigated by gravimetric techniques, The results demonstrated that the inhibitive performance increased with the increasing of inhibitor concentration. At 303, the inhibition efficiency of pyridine derivative 4-hydroxy-3-(pyridin-2-ylaminomethyl)toluene accomplished 96.2% at the inhibitor concentration of 0.005 M. The mechanism of inhibition implicated the forming of a protective layer from inhibitor molecules on the surface of mild steel by a Langmuir adsorption isotherm. The presence of nitrogen and oxygen atoms in the structure of 4-hydroxy-3-(pyridin-2-ylaminomethyl)toluene confirmed by CHN-analysis revealed the adsorption of inhibitor molecules on the surface of mild steel surface.

References

1. T.A. Salman, D.S. Zinad, S.H. Jaber, M. Al-Ghezi, A. Mahal, M.S. Takriff and A. Al-Amiery, Effect of 1,3,4 Thiadiazole Scafold on the Corrosion Inhibition of Mild Steel in Acidic Medium: An Experimental and Computational Study, J. BioTribo-Corrosion,2019, 5, 1.10.1007/s40735-019-0243-7
Search in Google Scholar Back to article
2. H.J. Habeeb, H.M. Luaibi, R.M. Dakhil, A.A.H. Kadhum, A. Al-Amiery and T.S. Gaaz, Development of new corrosion inhibitor tested on mild steel supported by electrochemical study, Results Phys.2018, 8, 1260.10.1016/j.rinp.2018.02.015
Search in Google Scholar Back to article
3. A. Al-Amiery, A. Kadhim, A. Mohamad, A. Musa, and C. Li, Electrochemical study on newly synthesized chlorocurcumin as an inhibitor for mild steel corrosion in hydrochloric acid, Materials, 2013, 6, 5466.10.3390/ma6125466
Search in Google Scholar Back to article
4. S. Junaedi, A. Kadhim, A. Al-Amiery, A. Mohamad and M. Takriff, Synthesis and characterization of novel corrosion inhibitor derived from oleic acid: 2-Amino5-Oleyl1,3,4-Thiadiazol (AOT), Int. J. Electrochem Sci.2012, 7, 3543.10.1016/S1452-3981(23)13976-9
Search in Google Scholar Back to article
5. A. Kadhim, A. Al-Okbi, D.M. Jamil, A. Qussay, A. Al-Amiery, T.S. Gaaz, A.A.H. Kadhum, A.B. Mohamad and M.H. Nassir, Experimental and theoretical studies of benzoxazines corrosion inhibitors, Results Phys.2017, 7, 4013.10.1016/j.rinp.2017.10.027
Search in Google Scholar Back to article
6. K.F., Al-Azawi, I.M. Mohammed, S.B. Al-Baghdadi, T.A. Salman, H.A. Issa, A. Al-Amiery, T.S. Gaaz, and A.A.H. Kadhum, Experimental and quantum chemical simulations on the corrosion inhibition of mild steel by 3-((5-(3,5-dinitrophenyl)-1,3,4-thiadiazol-2-yl)imino) indolin-2-one, Results Phys.2018, 9, 278.10.1016/j.rinp.2018.02.055
Search in Google Scholar Back to article
7. S.B. Al-Baghdadi, F.G. Hashim, A.Q. Salam, T.K. Abed, T.S. Gaaz, A. Al-Amiery, A.A.H. Kadhum, K.S. Reda and W.K. Ahmed, Synthesis and corrosion inhibition application of NATN on mild steel surface in acidic media complemented with DFT studies, Results Phys. 2018, 8, 1178.10.1016/j.rinp.2018.02.007
Search in Google Scholar Back to article
8. A.H.M.J. Al-Obaidy, A. Kadhum, S.B. Al-Baghdadi, A. Al-Amiery, A.A.H. Kadhum, A.B. Mohamad and E. Yousif, Eco-friendly corrosion inhibitor: experimental studies on the corrosion inhibition performance of creatinine for mild steel in HCl complemented with quantum chemical calculations, Int. J. Electrochem Sci. 2015, 10, 3961.10.1016/S1452-3981(23)06594-X
Search in Google Scholar Back to article
9. A. Al-Amiery, A.A.H. Kadhum, A.B. Mohamad and S. Junaedi, A Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl, Materials, 2013, 6, 1420.10.3390/ma6041420
Search in Google Scholar Back to article
10. M.H.O. Ahmed, A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum, A.B. Mohamad and T.S. Gaaz, Synthesis and characterization of a novel organic corrosion inhibitor for mild steel in 1 M hydrochloric acid, Results Phys. 2018, 8, 728.10.1016/j.rinp.2017.12.039
Search in Google Scholar Back to article
11. T. A. Salman, A. Al-Amiery, L. M. Shaker, A. Kadhum and M. S. Takriff, A study on the inhibition of mild steel corrosion in hydrochloric acid environment by 4-methyl-2-(pyridin-3-yl)thiazole-5-carbohydrazide. Int. J. Corros. Scale Inhib. 2019, 8, 1035.10.17675/2305-6894-2019-8-4-14
Search in Google Scholar Back to article
12. T. A. Salman, Q.A. Jawad, M. A. Hussain, A. Al-Amiery, L. M. Shaker, A. Kadhum and M. S. Takriff, Novel eco-friendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects. Int. J. Corros. Scale Inhib. 2019, 8, 1123.10.17675/2305-6894-2019-8-4-19
Search in Google Scholar Back to article
13. S.S. Al-Taweel, K.W.S. Al-Janabi, H.M. Luaibi, A. Al-Amiery and T.S. Gaaz, Evaluation and characterization of the symbiotic effect of benzylidene derivative with titanium dioxide nanoparticles on the inhibition of the chemical corrosion of mild steel. Int. J. Corros. Scale Inhib.2019, 8, 1149.10.17675/2305-6894-2019-8-4-21
Search in Google Scholar Back to article
14. D.S. Zinad, Q.A. Jawad, M.A.M. Hussain, A. Mahal, L. M. Shaker and A. Al-Amiery, Adsorption, temperature and corrosion inhibition studies of a coumarin derivatives corrosion inhibitor for mild steel in acidic medium: gravi-metric and theoretical investigations, Int. J. Corros. Scale Inhib.2020, 9, 134.10.17675/2305-6894-2020-9-1-8
Search in Google Scholar Back to article
15. S. Tu, X. H. Jiang, L. M. Zhou, M. Duan, H. Wang, X. M. Jiang, Synthesis of N-alkyl-4-(4-hydroxybut-2-ynyl) pyridinium bromides and their corrosion inhibition activities on X70 steel in 5 M HCl. Corros. Sci.2012, 65, 13–25.10.1016/j.corsci.2012.07.022
Search in Google Scholar Back to article
16. M. A. Hegazy, A. M. Hasan, M. M. Emara, M. F. Bakr, A. H. Youssef, Evaluating four synthesized Schiff bases as corrosion inhibitors on the carbon steel in 1 M hydrochloric acid. Corros. Sci.2012, 65, 67–76.10.1016/j.corsci.2012.08.005
Search in Google Scholar Back to article
17. L. R. Chauhan, G. Gunasekaran, Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corros. Sci. 2007, 49, 1143–1161.10.1016/j.corsci.2006.08.012
Search in Google Scholar Back to article
18. A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum and A.B. Mohamad, New Coumarin Derivative as an Eco-Friendly Inhibitor of Corrosion of Mild Steel in Acid Medium, Molecules2015,20, 366.10.3390/molecules20010366627275525551187
Search in Google Scholar Back to article
19. A.Y.I. Rubaye, A.A. Abdulwahid, S.B. Al-Baghdadi, A. Al-Amiery, A.A.H. Kadhum and A.B. Mohamad, Cheery sticks plant extract as a green corrosion inhibitor complemented with LC-EIS/MS spectroscopy, Int. J. Electrochem Sci.2015,10, 8200.10.1016/S1452-3981(23)11087-X
Search in Google Scholar Back to article
20. A. Kadhum, A. Mohamad, A.A.H. Kadhum, A.B. Mohamad, L.A. Hammed, A. Al-Amiery, N.H. San and A.Y. Musa, Inhibition of Mild Steel Corrosion in Hydrochloric Acid Solution by New Coumarin, Materials2014, 7, 4335.10.3390/ma7064335545592928788680
Search in Google Scholar Back to article
21. A. Mohamad, A. Kadhum, A. Al-Amiery, L. Ying and A. Musa, Synergistic of a coumarin derivative with potassium iodide on the corrosion inhibition of aluminum alloy in 1.0 M H₂SO₄, Met. Mater. Int.2014, 20, 459.10.1007/s12540-014-3008-3
Search in Google Scholar Back to article
22. D.S. Zinad, M. Hanoon, R.D. Salim, S.I. Ibrahim, A. Al-Amiery, M.S. Takriff and A.A.H. Kadhum, A new synthesized coumarin-derived Schiff base as a corrosion inhibitor of mild steel surface in HCl medium: gravimetric and DFT studies. Int. J. Corros. Scale Inhib. 2020, 9, 228.10.17675/2305-6894-2020-9-1-14
Search in Google Scholar Back to article
23. Q. A. Jawad, D. S. Zinad, R. D. Salim, A. Al-Amiery, T. S. Gaaz, M. S. Takriff and, A. Kadhum, Synthesis, Characterization, and Corrosion Inhibition Potential of Novel Thiosemicarbazone on Mild Steel in Sulfuric Acid Environment, Coatings 2019, 9, 729.10.3390/coatings9110729
Search in Google Scholar Back to article
24. A. Al-Amiery, Antimicrobial and antioxidant activities of new metal complexes derived from (E)-3-((5-phenyl-1,3,4-oxadiazol-2-ylimino) methyl)naphthalen-2-ol, Med. Chem. Res.2012, 21, 3204.10.1007/s00044-011-9880-1
Search in Google Scholar Back to article
25. D.M. Jamil, A.K. Al-Okbi, S.B. Al-Baghdadi, A. Al-Amiery, A. Kadhim and T.S. Gaaz, Experimental and theoretical studies of Schiff bases as corrosion inhibitors, Chem. Cent. J.2018, 12, 1.10.1186/s13065-018-0376-7
Search in Google Scholar Back to article
26. E. Yousif, Y. Win, A. Al-Hamadani, A. Al-Amiery, A. Kadhum and A. Mohamad, Furosemi as an environmental-friendly inhibitor of corrosion of zinc metal in acid medium experimental and theoretical studies, Int. J. Electrochem Sci.2015, 10, 1708.10.1016/S1452-3981(23)05105-2
Search in Google Scholar Back to article
27. J.A.A. Yamin, E. Ali Eh Sheet and A. Al-Amiery, Statistical analysis and optimization of the corrosion inhibition efficiency of a locally made corrosion inhibitor under different operating variables using RSM, Int. J. Corros. Scale Inhib. 2020, 9, 502.
Search in Google Scholar Back to article
28. R.D. Salim, Q.A. Jawad, K.S. Ridah, L.M. Shaker, A. Al-Amiery, A.A.H. Kadhum and M.S. Takriff, Corrosion inhibition of thiadiazole derivative for mild steel in hydrochloric acid solution, Int. J. Corros. Scale Inhib.2020, 9, 550.
Search in Google Scholar Back to article
29. A. Al-Amiery, L.M. Shaker, A.A.H. Kadhum, M.S. Takriff, Corrosion Inhibition of Mild Steel in Strong Acid Environment by 4-((5,5-dimethyl-3-oxocyclohex-1-en-1-yl)amino)benzenesulfonamide, Tribology in industry2020, 42, 89.10.24874/ti.2020.42.01.09
Search in Google Scholar Back to article

Articles in this issue

DOI: https://doi.org/10.2478/kom-2020-0009 | Journal eISSN: 1804-1213 | Journal ISSN: 0452-599X

Journal RSS Feed

Language: English

Page range: 59 - 64

Published on: Aug 24, 2020

Published by: Association of Czech and Slovak Corrosion Engineers

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Related subjects:

Industrial chemistry,

Chemical engineering,

Materials sciences,

Ceramics and glass

© 2020 A.A. Al-Amiery, L.M. Shaker, published by Association of Czech and Slovak Corrosion Engineers
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Volume 64 (2020): Issue 2 (June 2020)