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Testing the Applicability of Quartz and Feldspar for Luminescence Dating of Pleistocene Alluvial Sediments in the Tatra Mountain Foothills, Slovakia Cover

Testing the Applicability of Quartz and Feldspar for Luminescence Dating of Pleistocene Alluvial Sediments in the Tatra Mountain Foothills, Slovakia

Open Access
|Nov 2023

Figures & Tables

Fig 1.

Map of the High Tatras where both study areas are indicated: hashed black lines indicate the area of the Velická dolina valley that covers all the six sample sites, and the yellow square indicates the Great Yellow Wall (Fig. S1). Likewise, the location of the Bee Pit is a yellow square.

Fig 2.

Overview of the Bee Pit outcrop with the sampling locations in the different units. The log in Fig. 3 is from the southern side of the exposure (left in photo). The two boulders in unit 4 are marked with the red dashed line.

Fig 3.

Log combining the lower and upper exposures at the Bee Pit, including all units and uncorrected pIRIR225 luminescence ages from the site. The zero level in the log is approximately at 914 m a.s.l. Sample numbers and ages in bold are considered most reliable (for explanation, see text). Lithofacies codes are according to Krüger and Kjaer (1999).

Fig 4.

Overview of the luminescence sampling locations in the Velická dolina valley with location of luminescence samples (yellow stars). (A) Photo of Site 2 taken from Site 1 at the Great Yellow Wall. (B) Dry riverbed north of Site 3. (C) Site 4, east from the modern river. (D) Site 5, west from the modern river. (E) Site 6, the modern riverbed can be seen in the background. (F) Overview of Site 8, showing the natural outcrop from which the moraine sample was taken.

Fig 5.

Log from Sites 1 (left) and 2 (right), showing the units of the uppermost, southern side (YS) and the sampled northern part of the Great Yellow Wall (YN). It includes the uncorrected pIRIR225 luminescence ages, where the bold ages are the most reliable. The zero level of the log is at approximately 1110 m a.s.l., and the legend can be found in Fig. 3. Sample numbers and ages in bold are considered most reliable (for explanation, see text).

Fig 6.

(A) Weathered boulders with a sand matrix at Site 2, Great Yellow Wall. Sample 20026 was taken from within one of the weathered boulders and used as a sample with field-saturated luminescence signal since light exposure is not expected to have occurred at any point in time for these grains. (B) Sample 20026 taken from the weathered boulders.

Fig 7.

Small (2-mm) aliquot with feldspar grains used for dose estimation of sample 19102. The average number of grains for the small aliquots is approximately 70.

Fig 8.

Representative sensitivity-corrected dose–response curves and dose estimates for sample 19088 for (A) IR50. and (B) pIRIR225. De was determined to be 325 Gy and 800 Gy, respectively. (C) Example of a g-value measurement of the IR50 signal on a single aliquot of sample 19088. The steep trend line suggests a significant fading of the IR50 signal.

Fig 9.

Variation in equivalent dose and dose recovery ratio with temperature and signal integration intervals for sample 19082. (A) Preheat plateau (PHP) test where doses were calculated with early background subtraction (peak first 0.32 s, background next 0.32 s). All aliquots for 200° were rejected, (B) dose recovery ratios with corresponding calculation. (C) PHP test with late background subtraction for dose determination (peak first 0.8 s, background last 64 s). (D) Dose recovery ratios with corresponding calculation. The hatched line in B and D shows a dose recovery ratio of 1.0 (i.e. unity).

Fig 10.

(A) Decay curve comparison between normalised OSL signals from quartz sample 19083 and Risø calibration quartz (Hansen et al., 2015) for the initial part of the stimulation. The decay curve of sample 19083 indicates a slow signal decay, which is not dominated by a fast component. (B) A similar comparison between non-normalised OSL signals shows the very dim signal of the quartz from the Biely Váh valley.

Fig 11.

LM-OSL curves for one aliquot each of samples: (A) 19082 (B) 19095 (C) 19104 and (D) Risø calibration quartz batch 123. It is notable that the presence of the fast component varies greatly between samples, but it is not dominant in any of the Tatra samples.

Fig 12.

Comparison of the thermal stability between the natural quartz extracts (samples 19082, 19095 and 19104) and the Risø 180–250 μm calibration quartz (batch 123).

Fig 13.

(A) Dose–response curve and fading plot (inset) for the IR50 signal of sample 20026. Note that the signal does not display full saturation and fades significantly (mean g-value 5.4 ± 0.4%/decade for all aliquots). (B) Dose–response curve and fading plot (inset) for the pIRIR225 signal of sample 20026. The natural signal of this aliquot is close to saturation since the De > 2D0 (De = 765 ± 95 Gy; D0 = 289 ± 4 Gy) but not at saturation, and it still shows some fading in the laboratory (sample average g-value 0.66 ± 0.25%/decade).

Fig 14.

Examples of growth curves for IR50 and pIRIR225 measurements for samples 19091 (A,B) and 19096 (C,D). For the aliquot of sample 19091, the De is closer to saturation for the pIRIR225 signal. Sample 19096 is not close to saturation for IR50 and pIRIR225 (i.e. De < 2*D0).

Fig 15.

Bleaching rate of sample 19087 showing the signal or dose (Gy) plotted against exposure time in a logarithmic scale for both IR50 and pIRIR225.

Fig 16.

Comparison between quartz and feldspar ages. (A) Approximate quartz ages, based on 3 aliquots per sample, are all much lower than the fading corrected IR50 ages. (B) Feldspar-corrected IR50 ages are mostly of the same order as the uncorrected pIRIR225 ages, with some exceptions.

Fig 17.

Relation of uncorrected ages of the pIRIR225 (ka) on the x-axis vs. elevation of the samples in the outcrops on the y-axis. Preferred ages per site or unit are black. Note that the Velická dolina valley and the Biely Váh valley are two different areas in the southern foothills of the Tatra Mountains and are not subsequent geological strata as the figure might imply.

Fig S1.

Lower part of the Velická dolina valley with the orange dots to mark the sample sites.

Fig S4.

Probability plots with a z-distribution (mean of 0 and the standard deviation of 1) showing the dose distributions of samples with the most aliquots: samples 19091 (n=30), 19096 (n=29) and 19102 (n=33).

Dose recovery ratios and residual doses for IR and pIRIR measured on all samples from the Bee pit and the Velická dolina valley_

Sample no.IR50pIRIR225


Dose recovery ratioErrorResidualErrorDose recovery ratioErrorResidualError
190820.890.032.730.20.920.0316.090.12
190830.840.032.560.10.890.03150.1
190860.860.033.290.10.870.0317.30.1
190870.840.032.640.10.90.0317.50.1
190910.840.032.730.10.920.0315.60.5
190920.880.03--0.910.03--
190940.920.032.890.30.940.0315.51.6
19096--2.860.2--15.31.5

Results of the SOL2 bleaching experiment for sample 19087_

Bleaching time (min)IR50 De (Gy)IR50 Ln/TnpIRIR225 De (Gy)pIRIR225 Ln/Tn
0 (Natural)232.8 ± 2.86.49 ± 0.08587.8 ± 19.48.88 ± 0.39
145.4 ± 8.71.55 ± 0.27311.7 ± 31.77.38 ± 0.52
56.8 ± 0.30.24 ± 0.0192.7 ± 4.43.04 ± 0.12
203.3 ± 0.20.12 ± 0.0129.5 ± 0.71.06 ± 0.02
602.2 ± 0.10.08 ± 0.0016.3 ± 0.70.60 ± 0.03
201600.5 ± 0.00.02 ± 0.004.8 ± 0.30.17 ± 0.01

Results of the IR50 and pIRIR225 measurements: g-values, feldspar dose estimates, the number aliquots with De < 2D0 compared to the total number of accepted aliquots and the uncorrected and corrected ages_

Sample No.Unit / Site No.g-value (%/decade)De (Gy)Accepted (De<2D0) / Total aliquotsUncorrected age (ka)Corrected age (ka)





IR50pIRIR225IR50pIRIR225IR50pIRIR225IR50pIRIR225IR50pIRIR225
19082Unit 36.71 ± 0.12.23 ± 0.3414 ± 15868 ± 8612(12)/1212(1)/12125 ± 7.8261 ± 29278 ± 18326 ± 38
19083Unit 1B4.82 ± 0.71.56 ± 0.1351 ± 14844 ± 11612(12)/1212(1)/12109 ± 7.2263 ± 39185 ± 28308 ± 51
19084Unit 39.83 ± 0.22.84 ± 0.2348 ± 14741 ± 8012(12)/1212(2)/12129 ± 8.7275 ± 33624 ± 82368 ± 46
19085Unit 36.52 ± 0.11.66 ± 0.6317 ± 11760 ± 7612(12)/1212(1)/12106 ± 6.8254 ± 29230 ± 16300 ± 39
19086Unit 31.66 ± 0.20.09 ± 0.1387 ± 16812 ± 10512(12)/1212(0)/12100 ± 7.3210 ± 30117 ± 8.7212 ± 29
19087Unit 125.06 ± 0.31.48 ± 0.1351 ± 13788 ± 7312(12)/1212(2)/12120 ± 7.6269 ± 29208 ± 16311 ± 31
19088Unit 125.85 ± 0.20.81 ± 0.6326 ± 11776 ± 7412(12)/1212(1)/1281 ± 4.9193 ± 21156 ± 12208 ± 27
19089Unit 125.05 ± 0.021.99 ± 0.02372 ± 14850 ± 9112(12)/1212(2)/12109 ± 6.6249 ± 29188 ± 11304 ± 36
19090Unit 95.71 ± 0.42.16 ± 0.1354 ± 13763 ± 7312(12)/1212(1)/12115 ± 7.8248 ± 28219 ± 22308 ± 31
19091Unit 98.69 ± 1.10.37 ± 0.4360 ± 13710 ± 5830(30)/3030(8)/3097.3 ± 5.7192 ± 18318 ± 185199 ± 19
19092Unit 55.26 ± 0.30.70 ± 0.4465 ± 20949 ± 12312(12)/1212(2)/12132 ± 8.6269 ± 38236 ± 19287 ± 39
19093Site 18.01 ± 0.61.05 ± 0.3338 ± 15636 ± 6412(12)/1212(5)/1279.5 ± 5.5150 ± 17219 ± 50165 ± 19
19094Site 19.43 ± 0.53.04 ± 0.1304 ± 14611 ± 4912(11)/1512(7)/1369.9 ± 5.2139 ± 14266 ± 105188 ± 21
19095Site 14.83 ± 0.32.06 ± 0.2325 ± 13709 ± 8512(12)/1212(5)/1386.1 ± 5.9188 ± 25145 ± 12231 ± 29
19096Site 27.20 ± 0.61.52 ± 0.2346 ± 14770 ± 7229(29)/3029(9)/3090.9 ± 6.1202 ± 22204.5 ± 34234 ± 24
19097Site 27.25 ± 1.1−0.41 ± 0.1330 ± 12798 ± 8812(12)/1512(3)/1896.7 ± 6.9234 ± 30234 ± 83*
19098Site 38.61 ± 0.83.31 ± 0.2134 ± 4.2361 ± 2212(12)/1212(10)/1238.5 ± 2.9103 ± 9.5116 ± 35145 ± 14
19100Site 44.56 ± 0.61.43 ± 0.2306 ± 15839 ± 12212(12)/1212(2)/1281.7 ± 6.1224 ± 35130 ± 14257 ± 41
19101Site 511.49 ± 0.31.65 ± 0.2131 ± 4.1506 ± 3712(12)/1412(7)/1237.7 ± 2.8146 ± 14307 ± 118172 ± 17
19102Site 57.49 ± 0.92.60 ± 0.296.0 ± 3.1387 ± 3233(33)/3333(22)/3529.1 ± 2.0117 ± 1269 ± 15152 ± 15
19105Site 610.77 ± 1.02.98 ± 0.331.5 ± 1.5109 ± 7.012(12)/1512(9)/1817.7 ± 1.661.6 ± 6.379 ± 3782 ± 10
19106Site 66.74 ± 0.041.64 ± 0.156.2 ± 1.9183 ± 5.812(12)/1512(9)/1820.1 ± 1.665.4 ± 5.242 ± 3.577 ± 5.7
20026Site 25.42 ± 0.410.66 ± 0.25453 ± 10737 ± 475(5)/55(5)/5n/an/an/an/a
20028Site 84.89 ± 0.830.88 ± 0.4118.4 ± 3.955.6 ± 5.612(12)/1212(12)/125.0 ± 1.115.0 ± 1.77.6 ± 2.016.1 ± 1.9

The water content values used for the age calculation, per sample_ For three samples the uncorrected pIRIR age (ka) is shown calculated with all three water contents_

Sample No.Field Water Content (%)Saturated Water Content (%)Expected Water Content (%)
19082113127
19083152524
1908472219
19085132523
19086212726
19087243529
19088233026
19089152720
19090153529
19091173127
19092323836
19093162521
1909492213
19095182821
19096283531
19097283531
1909852323
1909952323
1910082923
19101173130
19102213029
19105194949
19106194949
2002801815

OSL parameters calculated from the quartz extracts using linear modulation compared to other values from literature_

SampleOSL componentDetraping probability (b)Photoionisation cross-section (ϭ)Relative Cross-section
19082Fast22.4 ± 4.91.4 × 10−161
Slow11.8 ± 0.21.2 × 10−170.09
Slow20.17 ± 0.0031.1 × 10−180.01
Slow30.018 ± 0.0041.1 × 10−190.001
Slow40.0004 ± 0.00032.5 × 10−200.0002

19095Fast9.6 ± 3.26.1 × 10−171
Medium0.94 ± 0.16.0 × 10−180.1
Slow20.12 ± 0.0087.8 × 10−190.01
Slow30.017 ± 0.00081.2 × 10−190.002
Slow40.004 ± 0.000092.9 × 10−200.0006

19104Fast1.6 ± 0.36.2 × 10−181
Slow10.08 ± 0.045.0 × 10−190.05
Slow30.005 ± 0.00033.1 × 10−200.003

Calib. quartzFast2.7 ± 0.091.6 × 10−171
Slow40.0007 ± 0.000034.5 × 10−210.0003

Jain et al. (2003)Fast2.5 ± 0.22.3 × 10−171
Medium0.62 ± 0.055.6 × 10−180.2
Slow10.15 ± 0.031.3 × 10−180.06
Slow20.023 ± 0.0052.1 × 10−190.01
Slow30.0022 ± 0.00022.1 × 10−200.001
Slow40.00030 ± 0.000012.8 × 10−210.0001

Durcan and Duller (2011)Fastn.a.2.6 × 10−171
Mediumn.a.4.3 × 10−180.16
Slow1n.a.1.1 × 10−180.04
Slow2n.a.3.0 × 10−190.01
Slow3n.a.3.4 × 10−200.001
Slow4n.a.9.1 × 10−210.0003

OSL doses, dose rates and ages for the quartz samples_

Sample No.Number of aliquotsType of OSL measurementMean Dose ± error (Gy)Total Dose rate ± error (Gy ka−1)Age (ka)
1908218Differential OSL268 ± 582.6 ± 0.1104 ± 23
12Pulsed OSL102 ± 640 ± 3
190833Standard SAR143 ± 272.7 ± 0.153 ± 10
190846Standard SAR160 ± 412.1 ± 0.177 ± 20
190853Standard SAR103 ± 212.4 ± 0.142 ± 9
190903Standard SAR96 ± 112.6 ± 0.138 ± 5
190913Standard SAR186 ± 553.2 ± 0.158 ± 17
190923Standard SAR114 ± 403.3 ± 0.235 ± 12
1910212Pulsed OSL30 ± 62.3 ± 0.213 ± 3

Concentration of radioactive elements in the sampled sediments (from gamma spectrometry) and the dose rate from cosmic radiation to each sample (as calculated in DRAC v1_2 (Durcan et al_, 2015))_

Sample No.U (ppm) ± errorTh (ppm) ± errorK (%) ± errorCosmic dose rate (Gy. ka−1)Total Dose Rate (Gy. ka−1)wce(%)
190821.49 ± 0.585.87 ± 0.152.52 ± 0.040.14 ± 0.013.33 ± 0.1727
190830.96 ± 0.456.55 ± 0.132.42 ± 0.050.10 ± 0.013.21 ± 0.1624
190840.48 ± 0.174.98 ± 0.081.91 ± 0.030.07 ± 0.012.70 ± 0.1519
190850.92 ± 0.545.11 ± 0.142.23 ± 0.040.10 ± 0.012.99 ± 0.1623
190862.43 ± 1.248.48 ± 0.332.86 ± 0.100.09 ± 0.013.87 ± 0.2326
190871.22 ± 0.426.96 ± 0.121.99 ± 0.040.16 ± 0.022.93 ± 0.1529
190884.23 ± 0.849.35 ± 0.232.46 ± 0.050.17 ± 0.024.03 ± 0.2026
190891.04 ± 0.215.60 ± 0.082.52 ± 0.030.17 ± 0.023.41 ± 0.1620
190900.74 ± 0.715.97 ± 0.182.32 ± 0.050.21 ± 0.023.07 ± 0.1729
190912.08 ± 0.398.79 ± 0.112.59 ± 0.030.21 ± 0.023.70 ± 0.1727
190922.20 ± 0.797.27 ± 0.212.74 ± 0.050.20 ± 0.023.53 ± 0.1836
190933.28 ± 0.3412.0 ± 0.172.56 ± 0.040.20 ± 0.024.24 ± 0.2321
190942.85 ± 0.6412.3 ± 0.192.48 ± 0.050.19 ± 0.024.39 ± 0.2613
190952.38 ± 0.4510.6 ± 0.132.29 ± 0.030.19 ± 0.023.78 ± 0.2121
190963.60 ± 0.4411.6 ± 0.122.47 ± 0.040.06 ± 0.013.80 ± 0.2031
190971.61 ± 0.8613.5 ± 0.242.21 ± 0.050.11 ± 0.013.41 ± 0.2131
190981.15 ± 0.496.80 ± 0.142.18 ± 0.050.27 ± 0.033.48 ± 0.2323
191002.94 ± 0.5812.1 ± 0.172.09 ± 0.050.17 ± 0.023.75 ± 0.2123
191012.39 ± 0.6011.8 ± 0.172.32 ± 0.050.18 ± 0.023.48 ± 0.2330
191021.39 ± 0.728.57 ± 0.192.31 ± 0.050.17 ± 0.023.29 ± 0.2029
191041.50 ± 0.256.53 ± 0.071.81 ± 0.030.29 ± 0.032.43 ± 0.20-
191051.06 ± 0.306.68 ± 0.151.89 ± 0.040 (surface)1.78 ± 0.14-
191061.06 ± 0.306.68 ± 0.151.89 ± 0.040.31 ± 0.032.80 ± 0.2049
200281.18 ± 0.2710.16 ± 0.152.44 ± 0.040.15 ± 0.023.72 ± 0.1715

Sample information acquired from the investigated study areas_ Lithofacies codes are based on Krüger and Kjaer (1999)_

Sample No.SiteUTM 33N eastingUTM 33N northingLocation / Sample typeDepth in m (overburden sediment)Stratigraphic unitLithofaciesFraction (μm)
19082Bee Pit428295439202Lower section7.1B3SiSm(ng)180–250
19083Bee Pit4282895439024Lower section11.4B1BSSim180–250
19084Bee Pit4282925439015Lower section13.8B3SiSm(ng)180–250
19085Bee Pit4282895439024Lower section11.4B3SiSm(ng)180–250
19086Bee Pit4282835439047Lower section10.8B3SiSm(ng)180–250
19087Bee Pit4282285438971Upper section5.4B12SiSm(ng)180–250
19088Bee Pit4282285438971Upper section5.4B12SiSm(ng)180–250
19089Bee Pit4282285438971Upper section5.4B12Sm(ng)180–250
19090Bee Pit4282825439016Lower section2.2B9SiSm180–250
19091Bee Pit4282825439016Lower section2.2B9SiSm180–250
19092Bee Pit4282865439018Lower section3.6B5Sm(ng)180–250
19093GYW, site 14394895441932GYW South (YS)1.8YS3GSm180–250
19094GYW, site 14394895441932GYW South (YS)1.7YS3Sm180–250
19095GYW, site 14394895441932GYW South (YS)2.2YS3GSm180–250
19096GYW, site 24395145442023GYW North (YN)15YN1Sm180–250
19097GYW, site 24395145442023GYW North (YN)15YN1Sm180–250
19098Site 34397375441549Flood deposit0.24-Gm250–355
19099*Site 44396775441615East of Velická potok2-Gm*
19100Site 44396775441615East of Velická potok2.5-Sm180–250
19101Site 54396055441701West of Velická potok2.6-Sh90–180
19102Site 54396055441701West of Velická potok2.5-Sh180–250
19105Site 64397755441345Modern Analogue (MA)0-Sm180–250
19106Site 64397755441345Modern Analogue (MA)0.03-Sm250–355
19103*Site 74406145436964Distant MA0-Sm*
19104*Site 74406145436964Distant MA0.12-Sm90–180
20026GYW, site 24395145442023Saturated sample15YN1Boulder180–250
20028Site 84398195442867Moraine5-DmC180–250

Water content test, where ages for samples 19084, 19086 and 19094 were calculated for 0% and 50% water content_

Sample No.Water Content (0%)Water Content (50%)Expected Water Content

Age (ka)Age (ka)Age (ka)
19084236 ± 28328 ± 40275 ± 33
19086169 ± 24245 ± 35210 ± 30
19094123 ± 13178 ± 17139 ± 14
Language: English
Page range: 50 - 80
Submitted on: Dec 22, 2022
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Accepted on: Jul 3, 2023
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Published on: Nov 22, 2023
Published by: Sciendo
In partnership with: Paradigm Publishing Services
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© 2023 Ingrid Bejarano-Arias, Roos M. J. Van Wees, Helena Alexanderson, Juraj Janočko, Zoran M. Perić, published by Sciendo
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.