Spatiotemporal Variations and Emission Characteristics of CO2 Fluxes in Deep Large Reservoirs
Abstract
Climate change driven by greenhouse gas emissions is a global priority. Deep large reservoirs represent significant potential emission sources, yet their greenhouse gas source-sink dynamics and driving mechanisms remain inadequately understood. This study targeted three representative deep reservoirs of the upper Yellow River (Longyangxia (LYX), Lijiaxia (LJX), and Liujiaxia (LJXX)). Comparative analysis of water column conditions during the stratification period (summer) and mixing period (winter) was conducted. We quantified the spatial distribution of dissolved partial pressure of CO2 (pCO2) and the water-air interface exchange flux (FCO₂), elucidating their spatiotemporal patterns and carbon source-sink attributes. Key findings include: (1) Concentration and Flux Characteristics: Mean pCO2 was 765.00 μatm in summer and 739.00 μatm in winter. Corresponding mean FCO₂ was 12.273 mmol/(m2·d) and 9.111 mmol/(m2·d). (2) Regulatory Mechanisms: Thermal stratification, climatic fluctuations, and reservoir-specific properties influenced pCO2 by modulating carbon cycling pathways and carbonate equilibria. (3) Source-Sink Nature: All three reservoirs exhibited significant spatial gradients and seasonal variations in pCO2 and FCO₂, collectively functioning as sources of the CO2. This study provides critical theoretical support for quantifying the carbon footprint of hydropower projects.
© 2026 Lei Ren, Sheng Xu, Peng Zheng, Xiaoxiong Zhang, Jialong Liu, published by Society of Ecological Chemistry and Engineering
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