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Synthesis and Characterisation of Biobased Grease Derived from Chemically Modified Waste Cooking Oil Cover

Synthesis and Characterisation of Biobased Grease Derived from Chemically Modified Waste Cooking Oil

Open Access
|Feb 2025

Abstract

As the global population rises, the dependency on edible oils also rises. The used oil possesses environmental concerns due to improper waste oil disposal. This study emphasises the feasibility of repurposing waste cooking oil (WCO) for eco-friendly lubricating grease production, emphasising enhanced stability and performance through chemical modifications. Chemical modifications, primarily transesterification, enhance the oxidative stability and chemical properties of WCO. Gas chromatography and mass spectroscopy analyse the fatty acid profile, and the hot oil oxidation test (HOOT) assesses the oxidative characteristics of WCO. The formulated grease using WCO undergoes tribological testing and penetration value testing. Results indicate post-transesterification improvements in chemical and oxidative stability, with lowered acid and peroxide values. Modified waste cooking oil (MWCO) exhibits enhanced thermal stability with higher flash and fire points. Viscosity results suggest the potential of MWCO as a lubricant with superior oxidative stability. Tribological properties reveal an improved characteristic value for MWCO, establishing its potential as an eco-friendly grease. Cone penetration tests categorise the formulated grease as NLGI grade 2, indicating a softer consistency with potential advantages for specific applications. The findings offer insights into the sustainable development of the lubricant industry, presenting MWCO as a promising alternative to conventional lubricants.

DOI: https://doi.org/10.2478/eces-2024-0036 | Journal eISSN: 2084-4549 | Journal ISSN: 1898-6196
Language: English
Page range: 551 - 568
Published on: Feb 19, 2025
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2025 Sabarinath Sankarannair, Pranav Prasannakumar, Vinod Vt Padil, Sabarinadh Baburaj Gayathri, Appu Babu, Aswin Gopal, Akash Rajasekharan, published by Society of Ecological Chemistry and Engineering
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.