Factors Affecting the Compressive Strength of Eco-Friendly Limestone Calcined Clay Cement (LC3): A Review
References
- EZ-ZAKI, H. – MARANGU, J.M. – BELLOTTO, M. – DALCONI, M.C. – ARTIOLI, G. – VALENTINI, L.: A fresh view on limestone calcined clay cement (LC3) pastes. Materials, vol. 14, no. 11, Jun. 2021, doi: 10.3390/ma14113037.
- AKGÜN, Y.: Behavior of concrete containing alternative pozzolan calcined marl blended cement. Periodica Polytechnica Civil Engineering, vol. 64, no. 4, 2020, pp. 1087–1099, doi: 10.3311/PPci.15122.
- NASIRI, S. – MADANDOUST, R. – RANJBAR, M.M.: Investigating the Calcination Temperature and Grinding Time of Calcined Clay on the Mechanical Properties and Durability of LC3 Concrete. Infrastructures, vol. 8, no. 10, Oct. 2023, doi: 0.3390/infrastructures8100139.
- CANCIO DIAZ, Y. – SÁNCHEZ BERRIEL, S. – SÁNCHEZ MACHADO, I.R. – MARTIRENA HERNÁNDEZ, J.F. – HABERT, G.: Eco-efficiency assessment of conventional OPC/PPC replacement by LC3 in Cuban residential buildings. IOP Conference Series: Earth and Environmental Science, vol. 323, no. 1, 2019, doi: 10.1088/1755-1315/323/1/012129.
- KRISHNAN, S. – EMMANUEL, A.C. – SHAH, V. – PARASHAR, A. – MISHRA,G. – MAITY, S. – BISHNOI, S.: Industrial production of limestone calcined clay cement: experience and insights. Green Materials, vol. 7, no. 1, 2018, pp. 15–27, doi:
https://doi.org/10.1680/jgrma.18.00003">https://doi.org/10.1680/jgrma.18.00003 . - MONTEIRO, P.J.M. – MILLER, S.A. – HORVATH, A.: Towards sustainable concrete. Nature Materials, vol. 16, no. 7, 2017, pp. 698–699, doi: 10.1038/nmat4930.
- SCRIVENER, K. – DEKEUKELAERE, A. – AVET, F – GRIMMEISSEN, L.: Financial Attractiveness of LC3. LC3-Project / École Polytechnique Fédérale de Lausanne, 2019,p. 44.
- GUTTERIDGE, W.A. – DALZIEL, J.A.: The effect of a secondary component on the hydration of Portland cement, Part I, Fine hydraulic binders. Cem. Concr. Res, vol. 20, 1990, pp. 853–861.
- SCRIVENER, K. – AVET, F. – MARAGHECHI, H. – ZUNINO, F. – STON, J. – HANPONGPUN, W – FAVIER,A: Impacting factors and properties of limestone calcined clay cements (LC3). Green Materials, vol. 7, no. 1, 2018, pp. 3–14, doi: 10.1680/jgrma.18.00029.
- NEIßER-DEITERS, A. – SCHERB, S. – BEUNTNER, N. – THIENEL, K.C: Influence of the calcination temperature on the properties of a mica mineral as a suitability study for the use as SCM. Applied Clay Science, vol. 179, 2019, p. 105168, doi:
https://doi.org/10.1016/j.clay.2019.105168">https://doi.org/10.1016/j.clay.2019.105168 . - JOMAA’H, M.M.: Using of Local Limestone as Aggregate in Concrete Mixture. Tikrit Journal of Engineering Sciences, vol. 19, no. 1, 2012, pp. 35–43, doi: 10.25130/tjes.19.1.04.
- GANI, S.A. – PUTRI, E.E. – ADJI, B.M. – HAKAM, A. – MAKINDA,J.: Investigation on the Performance of Limestone as Filler on Various Pavement Mixtures. Civil and Environmental Engineering, vol. 19, no. 2, 2023, pp. 618–629, doi: 10.2478/cee-2023-0056.
- ANTONI, M. – ROSSEN, J. – MARTIRENA, F. – SCRIVENER, K.: Cement substitution by a combination of metakaolin and limestone. Cement and Concrete Research, vol. 42, no. 12, 2012, pp. 1579–1589, doi:
https://doi.org/10.1016/j.cemconres.2012.09.006">https://doi.org/10.1016/j.cemconres.2012.09.006 . - SCRIVENER, K. – FAVIER, A.: Calcined clays for sustainable concrete. Springer, 2015.
- GETTU, R. – PATEL, A. – RATHI, V. – PRAKASAN, S. – BASAVARAJ, A.S. – PALANIAPPAN, S. – MAITY,S: Influence of supplementary cementitious materials on the sustainability parameters of cements and concretes in the Indian context. Materials and Structures, vol. 52, 2019, pp. 1–11.
- JASKULSKI, R. – JÓŹWIAK-NIEDŹWIEDZKA, D. – YAKYMECHKO, Y.: Calcined clay as supplementary cementitious material. Materials, MDPI, vol. 13, no. 21. 2020, pp. 1–36, doi: 10.3390/ma13214734.
- AKINDAHUNSI, A.A. – AVET, F. – SCRIVENER,K.: The Influence of some calcined clays from Nigeria as clinker substitute in cementitious systems. Case Studies in Construction Materials, vol. 13, Dec. 2020, doi: 10.1016/j.cscm.2020.e00443.
- BERNAL, S.A. – JUENGER, M.C.G. – Ke, X. – MATTHES, W. – LOTHENBACH, B. – De BELIE, N. – PROVIS,J.L.: Characterization of supplementary cementitious materials by thermal analysis. Materials and Structures/Materiaux et Constructions, vol. 50, no. 1, Feb. 2017, doi: 10.1617/s11527-016-0909-2.
- KRISHNAN, S. – EMMANUEL, A.C. – BISHNOI,S.: Effective clinker replacement using SCM in low clinker cements. Calcined Clays for Sustainable Concrete: Proceedings of the 1st International Conference on Calcined Clays for Sustainable Concrete, 2015, pp. 517–521.
- AVET, F. – SNELLINGS, R. – ALUJAS DIAZ, A. – BEN HAHA, M. – SCRIVENER, K.: Development of a new rapid, relevant and reliable (R3) test method to evaluate the pozzolanic reactivity of calcined kaolinitic clays. Cement and Concrete Research, vol. 85, 2016, pp. 1–11, doi:
https://doi.org/10.1016/j.cemconres.2016.02.015">https://doi.org/10.1016/j.cemconres.2016.02.015 . - RAM, K. – FLEGAR, M. – SERDAR, M. – SCRIVENER, K.: Influence of Low- to Medium-Kaolinite Clay on the Durability of Limestone Calcined Clay Cement (LC3) Concrete. Materials, vol. 16, no. 1, Jan. 2023, doi: 10.3390/ma16010374.
- SUN, J. – ZUNINO, F. – SCRIVENER, K.: Hydration and phase assemblage of limestone calcined clay cements (LC3) with clinker content below 50 %. Cement and Concrete Research, vol. 177, Mar. 2024, doi: 10.1016/j.cemconres.2023.107417.
- MARAGHECHI, H. – AVET,F. – WONG, H. – KAMYAB, H. – SCRIVENER, K.: Performance of Limestone Calcined Clay Cement (LC3) with various kaolinite contents with respect to chloride transport. Materials and Structures/Materiaux et Constructions, vol. 51, no. 5, Oct. 2018, doi: 10.1617/s11527-018-1255-3.
- ZUNINO, F. – SCRIVENER, K.: Assessing the effect of calcite impurities in clay on optimal dehydroxylation parameters for enhanced reactivity. Calcined Clays for Sustainable Concrete: Proceedings of the 2nd International Conference on Calcined Clays for Sustainable Concrete, 2018, pp. 507–513,
https://doi.org/10.1007/978-94-024-1207-9_81">https://doi.org/10.1007/978-94-024-1207-9_81 . - BABAFEMI, A.J. – KNOBEL, H. – KOLAWOLE, J.T. – OYEBANJO, O.M. – BUKALO, N.N. – PAUL, S.C. – MIAH,M.J.: Performance of Selected South African Kaolinitic Clays for Limestone Calcined Clay Cement. Applied Sciences (Switzerland), vol. 12, no. 21, Nov. 2022, doi: 10.3390/app122110751.
- ABDULQADER, M. – KHALID, H.R. – IBRAHIM, M. – ADEKUNLE,S.K. – AL-OSTA, M.A. – AHMAD, S. – SAJID, M.: Physicochemical properties of limestone calcined clay cement (LC3) concrete made using Saudi clays. Journal of Materials Research and Technology, vol. 25, 2023, pp. 2769–2783, doi: 10.1016/j.jmrt.2023.06.114.
- BONTLE, M. – NADIYE-TABBIRUKA, M: Chemical and thermal characterization of a clayey material found near Gaborone Dam. J. Appl. Sci. Environ. Manage, vol. 11, no. 4, 2007, pp. 77–80.
- BROWN, I.W.M. – MACKENZIE, K.J.D. – BOWDEN, M.E. – MEINHOLD, R.H.: Outstanding problems in the kaolinite-mullite reaction sequence investigated by 29Si and 27Al solid-state nuclear magnetic resonance: 11, high-temperature transformations of metakaolinite. Journal of the American Ceramic Society, vol. 68, no. 6, 1985, pp. 298–301.
- WHITE, C.E. – PROVIS, J.L. – PROFFEN, T. – RILEY, D.P. – VAN DEVENTER, J.S.J.: Density functional modeling of the local structure of kaolinite subjected to thermal dehydroxylation. Journal of Physical Chemistry A, vol. 114, no. 14, 2010, pp. 4988–4996, doi: 10.1021/jp911108d.
- HANEIN, T. – THIENEL, K.C. – ZUNINO, F. – MARSH, A.T.M. – MAIER, M. – WANG, B. – CANUT, M. – JUENGER, M.C.G. – BEN HAHA, M. – AVET, F. – PARASHAR, A. – AL-JABERI, L.A. – ALMENARES-REYES, R.S. – ALUJAS-DIAZ, A. – SCRIVENER, K.L. – BERNAL, S.A.,… MARTIRENA-HERNÁNDEZ, F.: Clay calcination technology: state-of-the-art review by the RILEM TC 282-CCL,” Materials and Structures/Materiaux et Constructions. Springer Science and Business Media B.V., vol. 55, no. 1, 2022, doi: 10.1617/s11527-021-01807-6.
- MAITY, S. – JOSEPH, S. – KRISHNAN, S.: Pilot scale manufacture of limestone calcined clay cement : The Indian experience Special iSSue-Future cements. 2014.
- SHVARZMAN, A. – KOVLER, K. – GRADER, G.S. – SHTER,G.E.: The effect of dehydroxylation/amorphization degree on pozzolanic activity of kaolinite. Cement and concrete research, vol. 33, no. 3, 2003, pp. 405–416.
- SÁNCHEZ BERRIEL, S. – FAVIER, A.,ROSA DOMÍNGUEZ,E.,SÁNCHEZ MACHADO,I.R.,HEIERLI,U.,SCRIVENER,K. – MARTIRENA HERNÁNDEZ, F. – HABERT, G.: Assessing the environmental and economic potential of Limestone Calcined Clay Cement in Cuba. Journal of Cleaner Production, vol. 124, 2016, pp. 361–369, doi: 10.1016/j.jclepro.2016.02.125.
- KAFODYA, I. – BASUROY, D. – MARANGU, J.M. – KULULANGA, G. – MADDALENA, R. – NOVELLI, V.I.: Mechanical Performance and Physico-Chemical Properties of Limestone Calcined Clay Cement (LC3) in Malawi. Buildings, vol. 13, no. 3, Mar. 2023, doi: 10.3390/buildings13030740.
- MUHAMMAD, A. – THIENEL, K.C. – SCHERB,S.: Calcined Clays from Nigeria—Properties and Performance of Supplementary Cementitious Materials Suitable for Producing Level 1 Concrete. Materials, vol. 16, no. 7, Apr. 2023, doi: 10.3390/ma16072684.
- SHEIKH, M.D. – JAMIL, T. – AYUB, T. – KHAN, A.U.R. – BILAL, S.M. – HU, C.: Comparative Study on LC3-50 with OPC Concrete Using Raw Materials from Pakistan. Advances in Materials Science and Engineering, vol. 2023, 2023, doi: 10.1155/2023/5503670.
- ALMENARES, R.S. – VIZCAÍNO, L.M. – DAMAS, S. – MATHIEU, A. – ALUJAS, A. – MARTIRENA, F: Industrial calcination of kaolinitic clays to make reactive pozzolans. Case Studies in Construction Materials, vol. 6, 2017, pp. 225–232, doi: 10.1016/j.cscm.2017.03.005.
- ANTONI, A. – KUNCORO, A. – FERNALDY, I. – DAVIAN, M. – SUSANTO, T.E. – HARDJITO, D.: Potential of Local Clay for the Development of Limestone Calcined Clay Cement in East Java. E3S Web of Conferences, Nov. 2023, vol. 445. doi: 10.1051/e3sconf/202344501035.
- WANG, S. – GAINEY, L. – MACKINNON, I.D.R. – ALLEN, C. – Gu, Y. – Xi, Y.: Thermal behaviors of clay minerals as key components and additives for fired brick properties: A review. Journal of Building Engineering, vol. 66. Elsevier Ltd, May 01, 2023. doi: 10.1016/j.jobe.2022.105802.
- ALGHAMDI, H. – SHOUKRY, H. – ABADEL, A.A. – KHAWAJI, M.: Performance assessment of limestone calcined clay cement (LC3)-Based lightweight green mortars incorporating recycled waste aggregate. Journal of Materials Research and Technology, vol. 23, 2023, pp. 2065–2074, doi: 10.1016/j.jmrt.2023.01.133.
- ZUNINO, F. – SCRIVENER, K.: The reaction between metakaolin and limestone and its effect in porosity refinement and mechanical properties. Cement and Concrete Research, vol. 140, Feb. 2021, doi: 10.1016/j.cemconres.2020.106307.
- AVET, F. – SCRIVENER, K.: Investigation of the calcined kaolinite content on the hydration of Limestone Calcined Clay Cement (LC3). Cement and Concrete Research, vol. 107, 2018, pp. 124–135,
https://doi.org/10.1016/j.cemconres.2018.02.016">https://doi.org/10.1016/j.cemconres.2018.02.016 . - TIRONI, A. – TREZZA, M.A. – SCIAN, A.N. – IRASSAR, E.F.: Assessment of pozzolanic activity of different calcined clays. Cement and concrete composites, vol. 37, 2013, pp. 319–327.
- SHARMA, M. – BISHNOI, S. – MARTIRENA, F. – SCRIVENER, K.: Limestone calcined clay cement and concrete: A state-of-the-art review. Cement and Concrete Research, vol. 149, 2021.
- CHOWANIEC, O. – Limestone addition in cement. Lausanne, EPFL, 2012.
- VAASUDEVAA, B. V. – DHANDAPANI, Y. – SANTHANAM, M.: Performance evaluation of limestone-calcined clay (LC2) combination as a cement substitute in concrete systems subjected to short-term heat curing. Construction and Building Materials, vol. 302, Oct. 2021, doi: 10.1016/j.conbuildmat.2021.124121.
- AVET, F. – SCRIVENER, K.: Hydration study of limestone calcined clay cement (LC 3) using various grades of calcined kaolinitic clays. Calcined Clays for Sustainable Concrete: Proceedings of the 2nd International Conference on Calcined Clays for Sustainable Concrete, 2018, pp. 35– 40,
https://doi.org/10.1007/978-94-024-1207-9_6">https://doi.org/10.1007/978-94-024-1207-9_6 . - REDDY, S.S. – REDDY, M.A.K.: LIME CALCINED CLAY CEMENT (LC3): A Review.
I OP Conference Series: Earth and Environmental Science, vol. 796, no. 1., 2021, doi: 10.1088/1755-1315/796/1/012037. - DONG, Y. – HU, C. – WANG, B. – HANIF, A.: Mechanical properties and microstructure of high strength LC3 pastes with varying limestone/calcined clay ratios and different curing conditions. 7 th International Conference on the Durability of Concrete Structures, May 2022.
- SCRIVENER, K.L. – JOHN, V.M. – GARTNER, E.M.: Eco-efficient cements: Potential economically viable solutions for a low-CO2 cement-based materials industry. Cement and Concrete Research, vol. 114, no. August, 2018, pp. 2–26, doi: 10.1016/j.cemconres.2018.03.015.
- MARANGU, J.M.: Physico-chemical properties of Kenyan made calcined Clay -Limestone cement (LC3). Case Studies in Construction Materials, vol. 12, Jun. 2020, doi: 10.1016/j.cscm.2020.e00333.
- DHANDAPANI, Y. – SAKTHIVEL, T. – SANTHANAM, M. – GETTU, R. – PILLAI,R.G.: Mechanical properties and durability performance of concretes with Limestone Calcined Clay Cement (LC3). Cement and Concrete Research, vol. 107, 2018, pp. 136–151, doi: 10.1016/j.cemconres.2018.02.005.
- ZUNINO, F. – SCRIVENER, K.: Microstructural developments of limestone calcined clay cement (LC3) pastes after long-term (3 years) hydration. Cement and Concrete Research, vol. 153, Mar. 2022, doi: 10.1016/j.cemconres.2021.106693.
- FERREIRO, S. – CANUT, M.M.C. – LUND, J. – HERFORT,D.: Influence of fineness of raw clay and calcination temperature on the performance of calcined clay-limestone blended cements. Applied Clay Science, vol. 169, 2019, pp. 81–90.
- VIZCAÍNO ANDRÉS, L.M. – ANTONI, M.G. – DIAZ, A.A. – MARTIRENA HERNÁNDEZ, J.F. – SCRIVENER, K.L.: Effect of fineness in clinker-calcined clays-limestone cements. Advances in Cement Research, vol. 27, no. 9, 2015, pp. 546–556, doi: 10.1680/adcr.14.00095.
- CHEN, Y. – Li, Z. – FIGUEIREDO, S.C. – ÇOPUROĞLU, O. – VEER, F. – SCHLANGEN, E.: Limestone and Calcined Clay-Based Sustainable Cementitious Materials for 3D Concrete Printing: A Fundamental Study of Extrudability and Early-Age Strength Development. Applied Sciences (Switzerland), vol. 9, no. 9, 2019, doi: 10.3390/app9091809.
- YU, J. – WU, H.L. – MISHRA, D.K. – LI, G. – LEUNG, C.K.: Compressive strength and environmental impact of sustainable blended cement with high-dosage Limestone and Calcined Clay (LC2). Journal of Cleaner Production, vol. 278, Jan. 2021, doi: 10.1016/j.jclepro.2020.123616.
- FERREIRO, S. – HERFORT, D. – DAMTOFT,J.S.: Effect of raw clay type, fineness, water-to-cement ratio and fly ash addition on workability and strength performance of calcined clay– limestone Portland cements. Cement and Concrete Research, vol. 101, 2017, pp. 1–12, doi:
https://doi.org/10.1016/j.cemconres.2017.08.003">https://doi.org/10.1016/j.cemconres.2017.08.003 . - MARK, O. – EDE, A. – ARUM, C. – JOLAYEMI, K.: Empirical Modeling of High-Performance Self-Compacting Concrete with Induction-Furnace Slag. Civil and Environmental Engineering, vol. 20, no. 1, 2024, pp. 440–460, doi: 10.2478/cee-2024-0034.
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