Catalytic Activity of Burkina Phosphates for Chalcone Synthesis in Green Solvent

Zoungrana, Jean-Baptiste; Sorgho, Brahima; Bakouan, Corneille; Ouedraogo, Régie Dimanche; Gonon, Maurice François; Guel, Boubié; Blanchart, Philippe

doi:10.2478/cdem-2025-0003

References

Gruselle M. Apatites: A new family of catalysts in organic synthesis. J Organ Chem. 2015;793:93-101. DOI: 10.1016/j.jorganchem.2015.01.018.
Search in Google Scholar Back to article
Su W, Cheng X, Shang S, Pan R, Qi M, Sang Q, et al. Advances in in situ investigations of heterogen catalytic ammonia synthesis. Catalysts. 2025;15:160. DOI: 10.3390/catal15020160.
Search in Google Scholar Back to article
Friend CM, Xu B. Heterogen catalysis: A central science for a sustainable future. Acc Chem Res. 2017;50:517-21. DOI: 10.1021/acs.accounts.6b00510.
Search in Google Scholar Back to article
Wacławek S, Padil VVT, Černík M. Major advances and challenges in heterogen catalysis for environmental applications: A review. Ecol Chem Eng S. 2018;25:9-34. DOI: 10.1515/eces-2018-0001.
Search in Google Scholar Back to article
Zhou Y, Tian Y, Peng X. Applications and challenges of supercritical foaming technology. Polymers. 2023;15:402. DOI: 10.3390/polym15020402.
Search in Google Scholar Back to article
Fallah A, Tajbakhsh M, Vahedi H, Bekhradnia A. Natural phosphate as an efficient and green catalyst for synthesis of tetraketone and xanthene derivatives. Res Chem Interm. 2017;43:29-43. DOI: 10.1007/s11164-016-2603-y.
Search in Google Scholar Back to article
Ganesan M, Nagaraaj P. Recent developments in dehydration of primary amides to nitriles. Org Chem Front. 2020;7:3792-814. DOI: 10.1039/D0QO00843E.
Search in Google Scholar Back to article
Riadi Y, Abrouki Y, Mamouni R, El Haddad M, Routier S, Guillaumet G, et al. New ecofriendly animal bone meal catalysts for preparation of chalcones and aza-Michael adducts. Chem Cent J. 2012;6:60. DOI: 10.1186/1752-153X-6-60.
Search in Google Scholar Back to article
Yadav GD, Wagh DP. Claisen-Schmidt condensation using green catalytic processes: A critical review. Chem Select. 2020;5:9059-85. DOI: 10.1002/slct.202001737.
Search in Google Scholar Back to article
Bentahar S, Taleb MA, Sabour A, Dbik A, Khomri ME, Messaoudi NE, et al. The use of modified clay as an efficient heterogeneous and ecofriendly catalyst for the synthesis of chalcones via Claisen-Schmidt condensation. Russ J Appl Chem. 2020;93:983-90. DOI: 10.1134/S107042722007006X.
Search in Google Scholar Back to article
Devi K, Rajendran V, Ayushee, Rangarajan T, Singh R, Ghosh P, et al. Synthesis and evaluation of anti plasmodial activity of 2,2,2-trifluoroethoxychalcones and 2-fluoroethoxy chalcones against Plasmodium falciparum in culture. Molecules. 2018;23:1174. DOI: 10.3390/molecules23051174.
Search in Google Scholar Back to article
Viana GSB, Bandeira MAM, Matos FJA. Analgesic and antiinflammatory effects of chalcones isolated from Myracrodruon urundeuva Allemão. Phytomedicine. 2003;10:189-95. DOI: 10.1078/094471103321659924.
Search in Google Scholar Back to article
Marcovicz C, Camargo GDA, Scharr B, Sens L, Levandowski MN, Rozada TDC, et al. Schistosomicidal evaluation of synthesized bromo and nitro chalcone derivatives. J Mol Structure. 2022;1258:132647. DOI: 10.1016/j.molstruc.2022.132647.
Search in Google Scholar Back to article
Borane N, Deshmukh AG, Oza NH, Boddula R, Patel PN. Newer chalcone scaffolds with reactive functional groups: Process, spectral and single crystal XRD studies. Eur J Chem. 2023;14:297-302. DOI: 10.5155/eurjchem.14.2.297-302.2405.
Search in Google Scholar Back to article
Elazarifi N, Ezzamarty A, Leglise J, Ménorval LCD, Moreau C. Kinetic study of the condensation of benzaldehyde with ethylcyanoacetate in the presence of Al-enriched fluoroapatites and hydroxyapatites as catalysts. Appl Catal A: General. 2004;267:235-40. DOI: 10.1016/j.apcata.2004.03.012.
Search in Google Scholar Back to article
Zăvoianu R, Tudorache M, Parvulescu VI, Cojocaru B, Pavel OD. New MgFeAl-LDH catalysts for Claisen-Schmidt condensation. Molecules. 2022;27:8391. DOI: 10.3390/molecules27238391.
Search in Google Scholar Back to article
Aichi Y. Natural phosphate doped by potassium as efficient catalyst for the synthesis of chalcones by Claisen-Schmidt condensation reaction. Twist J. 2024;19:113-22. DOI: 10.5281/zenodo.10049652#74.
Search in Google Scholar Back to article
Petigny L, Özel MZ, Périno S, Wajsman J, Chemat F. Water as green solvent for extraction of natural products. Chapter 7 in: Chemat F, Strube J, editors. Green Extraction of Natural Products: Theory and Practice. Willey; 2015:237-64. DOI: 10.1002/9783527676828.ch7.
Search in Google Scholar Back to article
Mohammadi ZG, Badiei A, Abbasi A, Farahani Z. Cross-aldol condensation of cycloalkanones and aromatic aldehydes in the presence of nanoporous silica-based sulfonic acid (SiO₂-Pr-SO₃H) under solvent free conditions. Chin J Chem. 2009;27:1537-42. DOI: 10.1002/cjoc.200990259.
Search in Google Scholar Back to article
Zoungrana JB, Sorgho B, Bakouan C, Sawadogo S, Ouedraogo RD, Guel B, et al. Mineralogical study of phosphate rocks by quantitative rietveld refinement. Open Ceramics. 2024;18:100567. DOI: 10.1016/j.oceram.2024.100567.
Search in Google Scholar Back to article
Laasri L, Hadidi M. Eco-friendly procedure for the synthesis of 4-(Phenylamino)pent-3-en-2-one using an heterogen catalyst - ZnCl₂/natural phosphate. Materials Today Proc. 2021;45:7352-8. DOI: 10.1016/j.matpr.2021.01.018.
Search in Google Scholar Back to article
Widayat W, Hadiyanto H, Wardani PWA, Az Zuhra U, Prameswari J. Preparation of KI/hydroxyapatite catalyst from phosphate rocks and its application for improvement of biodiesel production. Molecules. 2020;25:2565. DOI: 10.3390/molecules25112565.
Search in Google Scholar Back to article
Zahouily M, Mezdar A, Elmakssoudi A, Rayadh A, Sebti S, Lazrek HB. Comparison of different Lewis acids supported on natural phosphate as new catalysts for chemoselective dithioacetalization of carbonyl compounds under solvent-free conditions. Arkivoc. 2005;2006:31-40. DOI: 10.3998/ark.5550190.0007.203.
Search in Google Scholar Back to article
Bazi F, Mounir B, Hamza M, Sebti S. A mild and efficient method for the synthesis of acylals from aromatic aldehydes and their deprotections catalyzed by synthetic phosphates under solvent-free conditions. Green Sust Chem. 2018;08:334-44. DOI: 10.4236/gsc.2018.84023.
Search in Google Scholar Back to article
Mahato BN, Krithiga T. Recent developments in metal-doped SBA-15 catalysts for heterogen catalysis and sustainable chemistry. Can J Chem. 2022;100:9-17. DOI: 10.1139/cjc-2021-0201.
Search in Google Scholar Back to article
Saber A, Smahi A, Solhy A, Nazih R, Elaabar B, Maizi M, et al. Heterogen catalysis of Friedel-Crafts alkylation by the fluorapatite alone and doped with metal halides. J Mol Catal A: Chemical. 2003;202:229-37. DOI: 10.1016/S1381-1169(03)00186-9.
Search in Google Scholar Back to article
Rao GS, Kumar BP, Hussain S, Bhanuchander P. Metal phosphates: Preparation, characterization and catalytic evolution for vapour phase dehydration of glycerol to acrolein. Adv Sci Eng Med. 2020;12:356-63. DOI: 10.1166/asem.2020.2507.
Search in Google Scholar Back to article
Dikova T, Parushev I, Dunchev V, Yotsova R, Ismailov I, Ivanov I, et al. Influence of heat treatment on the phase composition of biphasic calcium phosphates for biomedical application. Cureus. 2025. DOI: 10.7759/cureus.83514.
Search in Google Scholar Back to article
Achchar M, Lamonier C, Ezzamarty A, Lakhdar M, Leglise J, Payen E. New apatite-based supports prepared by industrial phosphoric acid for HDS catalyst synthesis. Chem Reports. 2009;12:677-82. DOI: 10.1016/j.crci.2008.11.011.
Search in Google Scholar Back to article
Sebti S, Saber A, Rhihil A, Nazih R, Tahir R. Claisen-Schmidt condensation catalysis by natural phosphate. Appl Catal A: General. 2001;206:217-20. DOI: 10.1016/S0926-860X(00)00604-9.
Search in Google Scholar Back to article
Rhihil A, Aichi Y, Zahouily M, Sebti S, El Guendouzi M. Apatite phosphate doped by cobalt as hight efficient catalyst of multi-component synthesis of therapeutic spiropyrimidine compound. Nat Prod Bioprospect. 2022;12:35. DOI: 10.1007/s13659-022-00359-8.
Search in Google Scholar Back to article
Andrushkevich TV, Ovchinnikova EV. The role of water in selective heterogeneous catalytic oxidation of hydrocarbons. Molec Catal. 2020;484:110734. DOI: 10.1016/j.mcat.2019.110734.
Search in Google Scholar Back to article
Wu H, Zhang R, Li J, Chang J, Liu Z, Chen J, et al. Experimental and kinetic studies on the conversion of glucose to levulinic acid catalyzed by synergistic Cr/HZSM-5 in GVL/H₂O biphasic system. Catalysts. 2025;15:162. DOI: 10.3390/catal15020162.
Search in Google Scholar Back to article
Anand R, Hegde SG, Rao BS, Gopinath CS. Catalytic synthesis of 2-methyl pyrazine over Zn-modified zeolites. Catal Com. 2002;84:265-72. DOI: 10.1016/S1566-7367(01)00064-4.
Search in Google Scholar Back to article
Jioui I, Dânoun K, Solhy A, Jouiad M, Zahouily M, Essaid B, et al. Modified fluorapatite as highly efficient catalyst for the synthesis of chalcones via Claisen-Schmidt condensation reaction. J Industrial Eng Chem. 2016;39:218-25. DOI: 10.1016/j.jiec.2016.06.003.
Search in Google Scholar Back to article
Straiton AJ, Parish JD, Smith JJ, Lowe JP, Johnson AL. Exploration of solid-state vs solution-state structure in contact ion pair systems: Synthesis, characterization, and solution-state dynamics of zinc diphenyl phosphate, [Zn{O₂P(OPh)₂}₂], donor-base-supported complexes. Inorg Chem. 2023;62:4770-85. DOI: 10.1021/acs.inorgchem.2c03539.
Search in Google Scholar Back to article
Solhy A, Tahir R, Sebti S, Skouta R, Bousmina M, Zahouily M, et al. Efficient synthesis of chalcone derivatives catalyzed by reusable hydroxyapatite. Appl Catal A: General. 2010;374:189-93. DOI: 10.1016/j.apcata.2009.12.008.
Search in Google Scholar Back to article
Blanco S. Determination of absorptivity and formation constant of a chalcone association complex. Talanta. 1998;45:1103-9. DOI: 10.1016/S0039-9140(97)00209-9.
Search in Google Scholar Back to article
Brovelli F, Toledo D, Ahumada G, Moreno Y. Substituted heterocyclic chalcones: electrochemical, spectroscopic and theoretical study. J Chil Chem Soc. 2022;67:5662-6. DOI: 10.4067/S0717-97072022000305662.
Search in Google Scholar Back to article
Jumina J, Styaningrum RW, Siswanta D, Triono S, Priastomo Y, Harizal H, et al. Synthesis and preliminary evaluation of several chalcone derivatives as sunscreen compounds. Chemistry J Moldova. 2019;14:90-6. DOI: 10.19261/cjm.2019.624.
Search in Google Scholar Back to article
Wijayanti LW, Swasono RT, Lee W, Jumina J. Synthesis and evaluation of chalcone derivatives as novel sunscreen agent. Molecules. 2021;26:2698. DOI: 10.3390/molecules26092698.
Search in Google Scholar Back to article

Catalytic Activity of Burkina Phosphates for Chalcone Synthesis in Green Solvent

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