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Best Available Technologies for Waste Co-Firing Applications Cover

Best Available Technologies for Waste Co-Firing Applications

Open Access
|Apr 2020

Figures & Tables

Figure 1.

Location of TPOK plants in Poland [2]
Location of TPOK plants in Poland [2]

Figure 2.

Waste management methods in EU in 2019 [5]
Waste management methods in EU in 2019 [5]

Figure 3.

Graphic diagram of the CFB boiler system in connection with the FGT installation
Graphic diagram of the CFB boiler system in connection with the FGT installation

Figure 4.

Division of the CFB + FGT system emission control range for the co-firing coal with RDF operating mode
Division of the CFB + FGT system emission control range for the co-firing coal with RDF operating mode

Figure 5.

Scheme of the fuel feeding to the combustion chamber of a CFB boiler
Scheme of the fuel feeding to the combustion chamber of a CFB boiler

Figure 6.

Main components of the FGT semi-dry flue gas treatment system
Main components of the FGT semi-dry flue gas treatment system

Figure 7.

Diagram of the emission control systems in CFB+FGT installation
Diagram of the emission control systems in CFB+FGT installation

Characteristics of RDF

ParametersUnitStandardized limits
Lower calorific valueMJ/kg6-25
Carbon%35–40
Hydrogen%5-8
Nitrogen%0-1
Oxygen%25-30
Sulphur%<0.5
Chlorine%<1
Ash content%<15
Volatile matter%50-80
Humidity%<20
Bulk densitykg/m3100-300
Sbppm<20
Asppm<10
Cdppm<5
Cuppm<150
Pbppm<100
Cuppm<150
Pbppm<100
Nippm<50
Hgppm<1

Predicted based emissions

Emission component – subject to reductionMaximum baseline emissionsUnit
Dust<30 * g/Nm3
SO2<2700mg/Nm3
NOx<210mg/Nm3
HCl<1100mg/Nm3
HF<65mg/Nm3
Hg<0.06mg/Nm3
Cd+TI<1.3mg/Nm3
Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V<265mg/Nm3

Emission levels in case for coal and RDF co-firing

PollutantYearly average emission limitUnitBAT no.
Ash5mg/Nm3@6%02BAT 68
S02200 (1) ;150 (2) ;75 (3) mg/Nm3@6%02BAT 66
N0X150 (1) ;100 (2) ;85 (3) mg/Nm3@6%02BAT 64
CO140 (4) ;100 (5) mg/Nm3@6%02BAT 64
NH310 (7) mg/Nm3@6%02BAT 7
HCL6 (1) ;3 (6) mg/Nm3@6%02BAT 66
HF3 (1) , 2 (6) mg/Nm3@6%02BAT 66
Hg3 (4) ;2 (5) Hg/Nm3@6%02BAT 70
Cd+TI12 (4) ;6 (5) Hg/Nm3@6%02BAT 68
TVOC5mg/Nm3@6%02BAT 71
PCDD/PCDF0.03ng I-TEQ/Nm3@6%02BAT 71
Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V0.5 (4) ;0.2 (5) mg/Nm3@6%02BAT 68

Comparison of the CFB, BFB and Grate boiler technologies

Type of boilerCFBBFB * Grate boiler
Boiler’s efficiencyHighAverageLow
Steam parametersHigh 1 LowLow
NOx emissionLowAverageHigh
Fuels rangeWidest 2NarrowWide
Cost of combustion waste managementAverageHighLow
Share of fly ash20-40%80%20%

Emission levels in case of coal firing (BAT-AELs)

PollutantYearly average emission limitUnitBAT no.
Ash5mg/Nm3@6%O2BAT 22
SO2200 (1) ;150 (2) ;75 (3) mg/Nm3@6%O2BAT 21
NOx150 (1) ;100 (2) ;85 (3) mg/Nm3@6%O2BAT 20
CO140 (4) ;100(5)mg/Nm3@6%O2BAT 20
NH310 (7) mg/Nm3@6%O2BAT 7
HCL6 (1) ; 3 (6) mg/Nm3@6%O2BAT 21
HF3 (1) 2 (6) mg/Nm3@6%O2BAT 21
Hg3 (4) ; 2 (5) Hg/Nm3@6%O2BAT 23

Minimum emissions monitoring scope and monitoring frequency (BAT-AELs)

SubstanceMinimum monitoring frequency *
DustContinuous
SO2Continuous
NOx Continuous
N20Once every year
COContinuous
TVOCCombustion plant total rated thermal input** Continuous
HCLCoal + RDF firing: continuous (WI) Coal firing: once every 3 months
HFCoal + RDF firing: continuous (WI) Coal firing: once every 3 months
Metals and metalloids except mercury (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sb, Se, Tl, V, Zn)Coal + RDF firing – once every 6 months;Coal firing: once every year
HgCoal and/or Coal + RDF firing <300MWth (1) – once every 3 months Coal and/or Coal + RDF firing 300MWth (1) – continuous
Dioxins and furans (PCDD/PCDF)Once every 6 months
NH3Continuous (when SNCR used)

Characteristics of coal

ParametersUnitStandardized limits
Lower calorific valueMJ/kg19-26
Carbon%58-78
Hydrogen%3-4.5
Nitrogen%1-2.6
Sulphur%0.4-1.4
Chlorine%0.1-0.4
Oxygen%5.5-8
Volatile matter%28-38
Humidity%<10
Bulk densitykg/m3750-1000
(Na+K)%<0.35
Sbmg/kg<5
Asmg/kg<35
Cdmg/kg<4
Crmg/kg<346
Comg/kg<55
Cumg/kg<225
Pbmg/kg<182
Nimg/kg<227
Snmg/kg<67
Vmg/kg<333
Hgmg/kg<0.2
Znmg/kg<262
DOI: https://doi.org/10.21307/acee-2020-012 | Journal eISSN: 2720-6947 | Journal ISSN: 1899-0142
Language: English
Page range: 139 - 150
Submitted on: Jan 14, 2020
|
Accepted on: Feb 13, 2020
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Published on: Apr 8, 2020
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2020 Krzysztof WYKA, Anna SKOREK-OSIKOWSKA, published by Silesian University of Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.