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Best Available Technologies for Waste Co-Firing Applications Cover

Best Available Technologies for Waste Co-Firing Applications

Open Access
|Apr 2020

Figures & Tables

Figure 1.

Location of TPOK plants in Poland [2]

Figure 2.

Waste management methods in EU in 2019 [5]

Figure 3.

Graphic diagram of the CFB boiler system in connection with the FGT installation

Figure 4.

Division of the CFB + FGT system emission control range for the co-firing coal with RDF operating mode

Figure 5.

Scheme of the fuel feeding to the combustion chamber of a CFB boiler

Figure 6.

Main components of the FGT semi-dry flue gas treatment system

Figure 7.

Diagram of the emission control systems in CFB+FGT installation

Characteristics of RDF

ParametersUnitStandardized limits
Lower calorific valueMJ/kg6-25
Carbon%35–40
Hydrogen%5-8
Nitrogen%0-1
Oxygen%25-30
Sulphur%<0.5
Chlorine%<1
Ash content%<15
Volatile matter%50-80
Humidity%<20
Bulk densitykg/m3100-300
Sbppm<20
Asppm<10
Cdppm<5
Cuppm<150
Pbppm<100
Cuppm<150
Pbppm<100
Nippm<50
Hgppm<1

Predicted based emissions

Emission component – subject to reductionMaximum baseline emissionsUnit
Dust<30 * g/Nm3
SO2<2700mg/Nm3
NOx<210mg/Nm3
HCl<1100mg/Nm3
HF<65mg/Nm3
Hg<0.06mg/Nm3
Cd+TI<1.3mg/Nm3
Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V<265mg/Nm3

Emission levels in case for coal and RDF co-firing

PollutantYearly average emission limitUnitBAT no.
Ash5mg/Nm3@6%02BAT 68
S02200 (1) ;150 (2) ;75 (3) mg/Nm3@6%02BAT 66
N0X150 (1) ;100 (2) ;85 (3) mg/Nm3@6%02BAT 64
CO140 (4) ;100 (5) mg/Nm3@6%02BAT 64
NH310 (7) mg/Nm3@6%02BAT 7
HCL6 (1) ;3 (6) mg/Nm3@6%02BAT 66
HF3 (1) , 2 (6) mg/Nm3@6%02BAT 66
Hg3 (4) ;2 (5) Hg/Nm3@6%02BAT 70
Cd+TI12 (4) ;6 (5) Hg/Nm3@6%02BAT 68
TVOC5mg/Nm3@6%02BAT 71
PCDD/PCDF0.03ng I-TEQ/Nm3@6%02BAT 71
Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V0.5 (4) ;0.2 (5) mg/Nm3@6%02BAT 68

Comparison of the CFB, BFB and Grate boiler technologies

Type of boilerCFBBFB * Grate boiler
Boiler’s efficiencyHighAverageLow
Steam parametersHigh 1 LowLow
NOx emissionLowAverageHigh
Fuels rangeWidest 2NarrowWide
Cost of combustion waste managementAverageHighLow
Share of fly ash20-40%80%20%

Emission levels in case of coal firing (BAT-AELs)

PollutantYearly average emission limitUnitBAT no.
Ash5mg/Nm3@6%O2BAT 22
SO2200 (1) ;150 (2) ;75 (3) mg/Nm3@6%O2BAT 21
NOx150 (1) ;100 (2) ;85 (3) mg/Nm3@6%O2BAT 20
CO140 (4) ;100(5)mg/Nm3@6%O2BAT 20
NH310 (7) mg/Nm3@6%O2BAT 7
HCL6 (1) ; 3 (6) mg/Nm3@6%O2BAT 21
HF3 (1) 2 (6) mg/Nm3@6%O2BAT 21
Hg3 (4) ; 2 (5) Hg/Nm3@6%O2BAT 23

Minimum emissions monitoring scope and monitoring frequency (BAT-AELs)

SubstanceMinimum monitoring frequency *
DustContinuous
SO2Continuous
NOx Continuous
N20Once every year
COContinuous
TVOCCombustion plant total rated thermal input** Continuous
HCLCoal + RDF firing: continuous (WI) Coal firing: once every 3 months
HFCoal + RDF firing: continuous (WI) Coal firing: once every 3 months
Metals and metalloids except mercury (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sb, Se, Tl, V, Zn)Coal + RDF firing – once every 6 months;Coal firing: once every year
HgCoal and/or Coal + RDF firing <300MWth (1) – once every 3 months Coal and/or Coal + RDF firing 300MWth (1) – continuous
Dioxins and furans (PCDD/PCDF)Once every 6 months
NH3Continuous (when SNCR used)

Characteristics of coal

ParametersUnitStandardized limits
Lower calorific valueMJ/kg19-26
Carbon%58-78
Hydrogen%3-4.5
Nitrogen%1-2.6
Sulphur%0.4-1.4
Chlorine%0.1-0.4
Oxygen%5.5-8
Volatile matter%28-38
Humidity%<10
Bulk densitykg/m3750-1000
(Na+K)%<0.35
Sbmg/kg<5
Asmg/kg<35
Cdmg/kg<4
Crmg/kg<346
Comg/kg<55
Cumg/kg<225
Pbmg/kg<182
Nimg/kg<227
Snmg/kg<67
Vmg/kg<333
Hgmg/kg<0.2
Znmg/kg<262
DOI: https://doi.org/10.21307/acee-2020-012 | Journal eISSN: 2720-6947 | Journal ISSN: 1899-0142
Language: English
Page range: 139 - 150
Submitted on: Jan 14, 2020
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Accepted on: Feb 13, 2020
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Published on: Apr 8, 2020
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2020 Krzysztof WYKA, Anna SKOREK-OSIKOWSKA, published by Silesian University of Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.