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Determination of formation constants of uranyl(VI) complexes with a hydrophilic SO3-Ph-BTP ligand, using liquid-liquid extraction Cover

Determination of formation constants of uranyl(VI) complexes with a hydrophilic SO3-Ph-BTP ligand, using liquid-liquid extraction

Nukleonika
Volume 60 (2015): Issue 4 (December 2015)
By: ,  ,   and    
Open Access
|Dec 2015
References

References

  1. 1. Baisden, P. A., & Atkins-Duffi n, C. E. (2011). Radioactive waste management. In A. Vértes, S. Nagy, Z. Klencsár, R. G. Lovas, & F. Rösch (Eds.), Handbook of nuclear chemistry. 2nd ed. (pp. 2797-2835). Springer.
    Open DOISearch in Google Scholar
  2. 2. Salvatores, M., & Palmiotti, G. (2011). Radioactive waste partitioning and transmutation within advanced fuel cycles: Achievements and challenges. Progr. Part. Nucl. Phys., 66, 144-166.
    Open DOISearch in Google Scholar
  3. 3. Miguirditchian, M., Chareyre, L., Sorel, C., Bisel, I., Baron, P., & Masson, M. (2008). Development of the GANEX process for the reprocessing of Gen IV spent nuclear fuels. In ATALANTE 2008, May 19-22 (pp. 1-4). Montpellier, France.
    Search in Google Scholar
  4. 4. Aneheim, E., Ekberg, Ch., Fermvik, A., Foreman, M. R. St. J., Retegan, T., & Skarnemark, G. (2010). A TBP/BTBP-based GANEX separation process. Part 1: Feasibility. Solvent Extr. Ion Exch., 28, 437-458.
    Open DOISearch in Google Scholar
  5. 5. Carrott, M., Bell, K., Brown, J., Geist, A., Gregson, C., Hérès, X., Maher, Ch., Malmbeck, R., Mason, Ch., Modolo, G., Müllich, U., Sarsfi eld, M., Wilden, A., & Taylor, R. (2014). Development of a new fl owsheet for co-separating the transuranic actinides: The “EURO-GANEX” process. Solvent Extr. Ion Exch., 32, 447-467.
    Open DOISearch in Google Scholar
  6. 6. Carrott, M., Geist, A., Hérès, X., Lange, S., Malmbeck, R., Miguirditchian, M., Modolo, G., Wilden, A., & Taylor, R. (2015). Distribution of plutonium, americium and interfering fission products between nitric acid and a mixed organic phase of TODGA and DMDOHEMA in kerosene, and implications for the design of the “EURO-GANEX” process. Hydrometallurgy, 152, 139-148.
    Open DOISearch in Google Scholar
  7. 7. Geist, A., Müllich, U., Magnusson, D., Kaden, P., Modolo, G., Wilden, A., & Zevaco, T. (2012). Actinide( III)/lanthanide(III) separation via selective aqueous complexation of actinide(III) using a hydrophilic 2,6-bis(1,2,4-triazin-3-yl)pyridine in nitric acid. Solvent Extr. Ion Exch., 30, 433-444.
    Open DOISearch in Google Scholar
  8. 8. Modolo, G., Wilden, A., Geist, A., Magnusson, D., & Malmbeck, R. (2012). A review of the demonstration of innovative solvent extraction processes for the recovery of minor actinides from PUREX raffinate. Radiochim. Acta, 100, 715-725.
    Open DOISearch in Google Scholar
  9. 9. Ansari, S. A., Pathak, P., Mohapatra, P. K., & Manhanda, V. K. (2012). Chemistry of diglycolamides: promising extractants for actinide partitioning. Chem. Rev., 112, 1751-1772.
    Open DOISearch in Google Scholar
  10. 10. Kannan, S., Moody, M. A., Barnes, C. L., & Duval, P. B. (2008). Lanthanum(III) and uranyl(VI) diglycolamide complexes: synthetic precursors and structural studies involving nitrate complexation. Inorg. Chem., 47, 4691-4695.
    Open DOISearch in Google Scholar
  11. 11. Sasaki, Y., & Choppin, G. R. (1996). Solvent extraction of Eu, Th, U, Np and Am with N,N ʹ-dimethyl- -N,N ʹ-dihexyl-3-oxapentanediamide and its analogous compounds. Anal. Sci., 12, 225-230.
    Open DOISearch in Google Scholar
  12. 12. Sasaki, Y., Sugo, Y., Suzuki, S., & Tachimori, S. (2001). The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3-ndodecane system. Solvent Extr. Ion Exch., 19, 91-103.
    Open DOISearch in Google Scholar
  13. 13. Zhu, Z. -X., Sasaki, Y., Suzuki, H., Suzuki, S., & Kimura, T. (2004). Cumulative study on solvent extraction of elements by N,N,N ʹ,Nʺ-tetraoctyl-3- -oxapentanediamide (TODGA) from nitric acid into n-dodecane. Anal. Chim. Acta, 527, 163-168.
    Open DOISearch in Google Scholar
  14. 14. Arisaka, M., & Kimura, T. (2011). Thermodynamic and spectroscopic studies on Am(III) and Eu(III) in the extraction system of N,N,N ʹ,Nʺ-tetraoctyl-3- -oxapentane-1,5-diamide in n-dodecane/nitric acid. Solvent Extr. Ion Exch., 29, 72-85.
    Open DOISearch in Google Scholar
  15. 15. Budesinsky, B. W. (1977). Selective spectrophotometric determination of uranium. Microchem. J., 22, 50-54.
    Open DOISearch in Google Scholar
  16. 16. Cagle, F. W., & Smith, G. F. (1947). 2,2-Bipyridine ferrous complex ion as indicator in determination of iron. Anal. Chem., 19, 384-385. DOI: 10.1021/ ac60006a008.
    Open DOISearch in Google Scholar
  17. 17. Rode, J. E., Narbutt, J., Dudek, M. K., Kaźmierski, S., & Dobrowolski, J. Cz. (2016). On the conformation of the actinide-selective hydrophilic SO3-Ph-BTP ligand in aqueous solution. A computational study. J. Mol. Liquids (accepted).
    Open DOISearch in Google Scholar
  18. 18. Stary, J. (1967). The use of solvent extraction of metal chelates for the investigation of complexation in aqueous solutions. In D. Dyrssen, J. -O. Liljenzin, & J. Rydberg (Eds.), Solvent extraction chemistry - Proceedings of the International Conference held at Gothenburg, Sweden, 27 August - 1 September 1966 (pp. 1-10). Amsterdam: North-Holland Publ. Co.
    Search in Google Scholar
  19. 19. Ruff, Ch. (2013). Spektroskopische und thermodynamische Untersuchung der Komplexierung von Cm(III) und Eu(III) mit hydrophilen Bis-Triazinylpyridinen (pp. 49-52). Doctoral dissertation, Ruprecht-Karls-Universität Heidelberg. Available from www.ub.uni-heidelberg.de/archiv/16784.
    Search in Google Scholar
  20. 20. Farrance, I., & Frenkel, R. (2012). Uncertainty of measurement: A review of the rules for calculating uncertainty components through functional relationships. Clin. Biochem. Rev., 33, 49-75.
    Search in Google Scholar
  21. 21. Steczek, L., Rejnis, M., Narbutt, J., Charbonnel, M. -Ch., & Moisy, Ph. (2016). On the stoichiometry and stability of americium(III) complexes with a hydrophilic SO3-Ph-BTP ligand, studied by liquid-liquid extraction. J. Radioanal. Nucl. Chem. (accepted).
    Search in Google Scholar
  22. 22. Kaplan, L., Hildebrandt, R. A., & Ader, M. (1956). The trinitratouranyl ion in organic solvents. J. Inorg. Nucl. Chem., 2, 153-163.
    Open DOISearch in Google Scholar
  23. 23. Condamines, N., & Musikas, C. (1992). The extraction by N,N-dialkylamides. II. Extraction of actinide cations. Solvent Extr. Ion Exch., 10, 69-100.
    Open DOISearch in Google Scholar
  24. 24. Charbonnel, M. C., & Musikas, C. (1989). The extraction by N,Nʹ-tetrabutylglutaramides. II. Extraction of U(VI), Pu(IV) and some fi ssion products. Solvent Extr. Ion Exch., 7, 1007-1025.
    Open DOISearch in Google Scholar
  25. 25. Suleimenov, O. M., Seward, T. M., & Hovey, J. K. (2007). A spectrophotometric study on uranyl nitrate complexation to 150°C . J. Solution Chem., 36, 1093-1102.
    Open DOISearch in Google Scholar
  26. 26. Ruff, C. M., Müllich, U., Geist, A., & Panak, P. J. (2012). Complexation of Cm(III) and Eu(III) with hydropilic 2,6-bis(1,2,4-triazin-3-yl)-pyridine studied by time-resolved laser fl uorescence spectroscopy. Dalton Trans., 41, 14594-14602.
    Open DOISearch in Google Scholar
  27. 27. Berthet, J. -C., Thuéry, P., Dognon, J. -P., Guillaneux, D., & Ephritikhine, M. (2008). Sterically congested uranyl complexes with seven-coordination of the UO2 unit: the peculiar ligation mode of nitrate in [UO2(NO3)2(Rbtp)] complexes. Inorg. Chem., 47, 6850-6862.
    Open DOISearch in Google Scholar
  28. 28. Prestianni, A., Joubert, L., Chagnes, A., Cote, G., & Carlo, A. (2011). A density functional study of uranium(VI) nitrate monoamide complexes. Phys. Chem. Chem. Phys., 13, 19371-19377.
    Open DOISearch in Google Scholar
  29. 29. Hubscher-Bruder, V., Haddaoui, J., Bouhroum, S., & Arnaud-Neu, F. (2010). Recognition of some lanthanides, actinides, and transition- and heavy-metal cations by N-donor ligands: Thermodynamic and kinetic aspects. Inorg. Chem., 49, 1363-1371.
    Open DOISearch in Google Scholar
  30. 30. Marie, C., Miguirditchian, M., Guillaumont, D., Tosseng, A., Berthon, C., Guilbaud, P., Duvail, M., Bisson, J., Guillaneux, D., Pipelier, M., & Dubreuil, D. (2011). Complexation of lanthanides(III), americium(III), and uranium(VI) with bitopic N,O ligands: an experimental and theoretical study. Inorg. Chem., 50, 6557-6566.
    Open DOISearch in Google Scholar
DOI: https://doi.org/10.1515/nuka-2015-0150 | Journal eISSN: 1508-5791 (formerly 0029-5922) | Journal ISSN: 0029-5922
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Language: English
Page range: 821 - 827
Submitted on: Jul 3, 2015
Accepted on: Sep 15, 2015
Published on: Dec 30, 2015
Published by: Institute of Nuclear Chemistry and Technology
In partnership with: Paradigm Publishing Services
Keywords:
uranyl ion,
hydrophilic poly-N-dentate ligands,
complexes,
solvent extraction,
stripping,
formation constant
Related subjects:
Chemistry,
Nuclear chemistry

© 2015 Lukasz Steczek, Jerzy Narbutt, Marie-Christine Charbonnel, Philippe Moisy, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Volume 60 (2015): Issue 4 (December 2015)
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