Interactions between osmium atoms dissolved in iron observed by the 57Fe Mössbauer spectroscopy

Konieczny, Robert; Idczak, Rafał; Chojcan, Jan

doi:10.1515/nuka-2015-0016

Abstract

The room temperature ⁵⁷Fe Mössbauer spectra for binary iron-based solid solutions Fe_1−xOs_x, with x in the range 0.01 ≤ x ≤ 0.05, were analyzed in terms of binding energy E_b between two Os atoms in the Fe-Os system. The extrapolated values of E_b for x = 0 were used for computation of enthalpy of solution of osmium in iron. The result was compared with that resulting from the cellular atomic model of alloys by Miedema. The comparison shows that our findings are in qualitative agreement with the Miedema's model predictions.

References

1. Chojcan, J. (1998). Interactions between impurity atoms of 3d transition metals dissolved in iron. J. Alloy. Compd., 264, 50–53. DOI: 10.1016/S0925-8388(97)00264-8.10.1016/S0925-8388(97)00264-8
Search in Google Scholar
2. Chojcan, J. (2004). A dilute-limit heat of solution of 3d transition metals in iron studied with ⁵⁷Fe Mössbauer spectroscopy. Hyperfine Interact., 156/157, 523–529. DOI: 10.1007/978-1-4020-2852-6_76.10.1007/978-1-4020-2852-6_76
Search in Google Scholar
3. Konieczny, R., Idczak, R., Elsner, J., & Chojcan, J. (2012). An enthalpy of solution of platinum in iron studied by ⁵⁷Fe Mössbauer spectroscopy. Hyperfine Interact., 206, 119–124. DOI: 10.1007/s10751-011-0480-8.10.1007/s10751-011-0480-8
Search in Google Scholar
4. Konieczny, R., Idczak, R., Szarypo, W., & Chojcan, J. (2012). An enthalpy of solution of rhenium in iron studied by ⁵⁷Fe Mössbauer spectroscopy. Hyperfine Interact., 206, 135–139. DOI: 10.1007/s10751-011-0481-7.10.1007/s10751-011-0481-7
Search in Google Scholar
5. Konieczny, R., Idczak, R., & Chojcan, J. (2013). Mössbauer studies of interactions between titanium atoms dissolved in iron. Hyperfine Interact., 219, 121–127. DOI: 10.1007/s10751-012-0653-0.10.1007/s10751-012-0653-0
Search in Google Scholar
6. Królas, K. (1981). Correlation between impurity binding energies and heat of formation of alloys. Phys. Lett. A, 85, 107–110. DOI: 10.1016/0375-9601(81)90235-8.10.1016/0375-9601(81)90235-8
Search in Google Scholar
7. Miedema, A. R. (1992). Energy effects and charge transfer in metal physics, modeling in real space. Physica B, 182, 1–17. DOI: 10.1016/0921-4526(92)90565-A.10.1016/0921-4526(92)90565-A
Search in Google Scholar
8. Bangwei, Z., & Yifang, O. (1993). Theoretical calculation of thermodynamic data for bcc binary alloys with the embedded-atom method. Phys. Rev. B, 48, 3022–3029. DOI: http://dx.doi.org/10.1103/PhysRevB.48.3022.
Search in Google Scholar
9. Bonny, G., Pasianot, R. C., Malerba, L., Caro, A., Olsson, P., & Lavrentiev, M. Yu. (2009). Numerical predictions of thermodynamic properties of iron-chromium alloys using semi-empirical cohesive models: The state of the art. J. Nucl. Mater., 385, 268–277. DOI: 10.1016/j.jnucmat.2008.12.001.10.1016/j.jnucmat.2008.12.001
Search in Google Scholar
10. Boom, R., De Boer, F. R., Niessen, A. K., & Miedema, A. R. (1983). Enthalpies of formation of liquid and solid binary alloys based on 3d metals: III. Alloys of iron. Physica B, 115, 285–309. DOI: 10.1016/0378-4363(83)90020-7.10.1016/0378-4363(83)90020-7
Search in Google Scholar
11. Lejaeghere, K., Cottenier, S., Claessens, S., Waroquier, M., & Van Speybroeck, V. (2011). Assessment of a low-cost protocol for an ab initio based prediction of the mixing enthalpy at elevated temperatures: The Fe-Mo system. Phys. Rev. B, 83, 184201–184207. DOI: http://dx.doi.org/10.1103/PhysRevB.83.184201.
Search in Google Scholar
12. Idczak, R., Konieczny, R., & Chojcan, J. (2012). An enthalpy of solution of chromium in iron studied with ⁵⁷Fe Mössbauer spectroscopy. Physica B, 407, 2078–2081. DOI: 10.1016/j.physb.2012.02.009.10.1016/j.physb.2012.02.009
Search in Google Scholar
13. Cranshaw, T. E. (1989). A Mössbauer study of ¹¹⁹Sn in alloys of iron with Si, Al, and Rh: interaction potentials and phase diagrams. J. Phys.-Condens. Matter, 1, 829–846. DOI: 10.1088/0953-8984/1/5/001.10.1088/0953-8984/1/5/001
Search in Google Scholar
14. Hultgren, R., Desai, P. D., Hawkins, D. T., Gleiser, M., & Kelley, K. K. (1973). Selected values of thermodynamic properties of binary alloys. Metals Park, OH: American Society for Metals.
Search in Google Scholar
15. Swartzendruber, L. J., Itkin, V. P., & Alcock, C. B. (1993). Phase diagrams of binary iron alloys. Materials Park, OH: Materials Information Society.
Search in Google Scholar
16. Vincze, I., & Campbell, I. A. (1973). Mössbauer measurements in iron base alloys with transition metals. J. Phys. F, 3, 647–663.10.1088/0305-4608/3/3/023
Search in Google Scholar
17. Idczak, R., Konieczny, R., & Chojcan, J. (2012). Study of defects in Fe-Re and Fe-Mo alloys by the Mössbauer and positron annihilation spectroscopies. Solid State Commun., 152, 1924–1928. DOI: 10.1016/j.ssc.2012.07.027.10.1016/j.ssc.2012.07.027
Search in Google Scholar
18. Błachowski, A., Ruebenbauer, K., & Żukrowski, J. (2004). Charge and spin density perturbation on iron atom due to osmium impurity in metallic iron. Nukleonika, 49, 67–70.
Search in Google Scholar
19. Błachowski, A., & Wdowik, U. D. (2012). Transition metal impurity effect on charge and spin density in iron: Ab initio calculations and comparison with Mössbauer data. J. Phys. Chem. Solids, 73, 317–323. DOI: 10.1016/j.jpcs.2011.10.017.10.1016/j.jpcs.2011.10.017
Search in Google Scholar
20. Idczak, R., Konieczny, R., & Chojcan, J. (2014). A study of dilute Fe-Os alloys by ⁵⁷Fe Mössbauer spectroscopy. Physica B, 437, 4–9. DOI: 10.1016/j.physb.2013.12.021.10.1016/j.physb.2013.12.021
Search in Google Scholar
21. Gorbatov, O. I., Okatov, S. V., Gornostyrev, Yu. N., Korzhavyi, P. A., & Ruban, A. V. (2013). Effect of magnetism on the solubility of 3d elements in BCC iron: Results of first-principle investigations. Phys. Metals Metallogr., 114, 642–653. DOI: 10.1134/S0031918X13080036.10.1134/S0031918X13080036
Search in Google Scholar

Interactions between osmium atoms dissolved in iron observed by the 57Fe Mössbauer spectroscopy

Abstract

Paradigm

My account