Gas-sensing properties and in-situ diffuse-reflectance Fourier-transform infrared spectroscopy study of diethyl ether adsorption and reactions on SnO2 film

Wang, Ning; Huang, Kaijin; Song, Jian

doi:10.1515/msp-2017-0037

Abstract

Diethyl ether is a common industrial reagent and medical anesthetic. It is necessary to carry out real-time monitoring of this molecule due to its harmful effects on human health. In this paper, a highly sensitive diethyl ether SnO₂ gas-sensing material has been prepared by a sol-gel method. The gas sensitivity was tested by a home-made gas-sensing equipment. The surface adsorption and reaction processes between the SnO₂ gas-sensing film and the diethyl ether have been studied by in situ diffuse-reflectance Fourier-transform infrared spectroscopy (DRFT-IR) at different temperatures. The results show that the SnO₂ gas-sensing material has high sensitivity to diethyl ether, and the lowest detection limit can reach 1 ppm. Furthermore, ethyl (CH₃CH₂●), oxoethyl (CH₃CH₂O●), ethanol (CH₃CH₂OH), formaldehyde (HCHO), acetaldehyde (CH₃CHO), ethylene (C₂H₄), H₂O and CO₂ surface species are formed during diethyl ether adsorption at different temperatures. A possible mechanism of the reaction process is discussed.

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Gas-sensing properties and in-situ diffuse-reflectance Fourier-transform infrared spectroscopy study of diethyl ether adsorption and reactions on SnO2 film

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