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Dielectric and Raman studies of Ba0.06(Na1/2Bi1/2)0.94TiO3–NaNbO3 ceramics

Open Access
|Jun 2016

Figures & Tables

Fig. 1

(a) XRD patterns of (1 – x)Ba0.06(Na1/2Bi1/2)0.94 TiO3–xNaNbO3 ceramics at room temperature and (b) XRD patterns of (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3–xNaNbO3 ceramics in the selected regions of 2θ(45.5° to 48°).
(a) XRD patterns of (1 – x)Ba0.06(Na1/2Bi1/2)0.94 TiO3–xNaNbO3 ceramics at room temperature and (b) XRD patterns of (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3–xNaNbO3 ceramics in the selected regions of 2θ(45.5° to 48°).

Fig. 2

SEM images of (1 – x)Ba0.06(Na1/2Bi1/2)0.94 TiO3–xNaNbO3 ceramics.
SEM images of (1 – x)Ba0.06(Na1/2Bi1/2)0.94 TiO3–xNaNbO3 ceramics.

Fig. 3

Raman spectra of (a) Ba0.06(Na1/2Bi1/2)0.94 TiO3 and peaks fitted with Gaussian components, (b) Raman spectra of NaNbO3 can be deconvoluted with Lorentzian components contrary to Ba0.06(Na1/2Bi1/2)0.94TiO3, NaNbO3 requires multiple peaks and (c) shows a change in the Raman spectra with increasing NaNbO3 doping % in Ba0.06(Na1/2Bi1/2)0.94TiO3 matrix.
Raman spectra of (a) Ba0.06(Na1/2Bi1/2)0.94 TiO3 and peaks fitted with Gaussian components, (b) Raman spectra of NaNbO3 can be deconvoluted with Lorentzian components contrary to Ba0.06(Na1/2Bi1/2)0.94TiO3, NaNbO3 requires multiple peaks and (c) shows a change in the Raman spectra with increasing NaNbO3 doping % in Ba0.06(Na1/2Bi1/2)0.94TiO3 matrix.

Fig. 4

Frequency dependence of dielectric constant of (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3–xNaNbO3 ceramics at room temperature.
Frequency dependence of dielectric constant of (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3–xNaNbO3 ceramics at room temperature.

Fig. 5

Temperature dependence of dielectric constant and loss tangent of (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3– xNaNbO3 ceramics at different frequencies (a) 1 kHz (b) 10 kHz (c) 100 kHz (d) 1MHz.
Temperature dependence of dielectric constant and loss tangent of (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3– xNaNbO3 ceramics at different frequencies (a) 1 kHz (b) 10 kHz (c) 100 kHz (d) 1MHz.

Fig. 6

The modified Curie-Weiss plots ln(1/∊–1/∊m) vs. ln(T–Tm) for (1 – x)Ba0.06(Na1/2Bi1/2)0.94 TiO3–xNaNbO3 ceramics for x = 0, x = 0.50, x = 1.0 at 1 kHz.
The modified Curie-Weiss plots ln(1/∊–1/∊m) vs. ln(T–Tm) for (1 – x)Ba0.06(Na1/2Bi1/2)0.94 TiO3–xNaNbO3 ceramics for x = 0, x = 0.50, x = 1.0 at 1 kHz.

Lattice parameters of the (1 – x)Ba0_06(Na1/2Bi1/2)0_94TiO3–xNaNbO3 (0 ⩽ x ⩽ 1) ceramics_

Parameters / x0.000.050.100.250.500.750.900.951.00
a [Å]3.90373.89793.90333.93.8983.9353.9093.9333.95
b [Å]3.90373.89793.90333.93.8983.9123.873.9123.84
c [Å]3.8983.9033.9093.90383.9073.883.8853.883.909
c/a0.9981.00131.00141.00091.00230.98600.99380.98650.9896
Cell volume [Å 3]58.8659.2959.5659.3859.3659.758.7459.759.34
Crystal systemR / TR / TR / TR / TR / T / OOOOO

Tolerance factor, average A-and B-site ionic radius of (1 – x)Ba0_06(Na1/2Bi1/2)0_94TiO3–xNaNbO3 ceramics_

xTolerance factor (t)Average ionic radius of A site [Å]Average ionic radius of B site [Å]
0.000.9501.3000.605
0.050.9511.3040.607
0.100.9521.3090.609
0.250.9551.3220.614
0.500.9601.3450.623
0.750.9651.3670.631
0.900.9681.3810.637
0.950.9691.3850.638
1.000.9701.3900.640
DOI: https://doi.org/10.1515/msp-2016-0041 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331
Language: English
Page range: 437 - 445
Submitted on: Nov 27, 2015
Accepted on: Jan 28, 2016
Published on: Jun 18, 2016
Published by: Wroclaw University of Science and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2016 Sumit K. Roy, S. Chaudhuri, R.K. Kotnala, D.K. Singh, B.P. Singh, S.N. Singh, K.P. Chandra, K. Prasad, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.