Abstract
Differences between vertical mobilities of nutrient and trace elements within a long-term sludge-treated and an adjacent untreated Alpine grassland cambisol were investigated by column experiments. The site had been intensely fertilized with urban sewage sludge for 10 years of 7.5 Mg/ha annually, whereas an adjacent site had been left untreated. A model column experiment was set up to investigate changes of permeabilities and trace element retentions at 0-20 cm and 20-60 cm layers thereof. Elution was performed with de-ionized water at amounts of expected rainfall at the sampling site (1000 mm), as well as with equal volume of manure after biogas production. Long-term sludge treatment increased organic carbon, formation of ammonium and nitrate, and increased vertical mobility of K, P, S, Cu, and Fe, but also slightly higher (below 10-fold) for Na, Sr, Ba, Ni and V. Additional application of manure was of minor effect, mainly upon nitrate formation, and upon leaching of Fe, Mn as well as Fe/Mn proportion. Prior addition of FeCl2 to the manure in order to increase sulfide precipitation, mainly affected the output of ammonia, but hardly the cations or anions (e.g. P) investigated.