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Kinetics of the decomposition and the estimation of the stability of 10% aqueous and non-aqueous hydrogen peroxide solutions Cover

Kinetics of the decomposition and the estimation of the stability of 10% aqueous and non-aqueous hydrogen peroxide solutions

Open Access
|Mar 2015

Abstract

In this study, the stability of 10% hydrogen peroxide aqueous and non-aqueous solutions with the addition of 6% (w/w) of urea was evaluated. The solutions were stored at 20°C, 30°C and 40°C, and the decomposition of hydrogen peroxide proceeded according to first-order kinetics. With the addition of the urea in the solutions, the decomposition rate constant increased and the activation energy decreased. The temperature of storage also affected the decomposition of substance, however, 10% hydrogen peroxide solutions prepared in PEG-300, and stabilized with the addition of 6% (w/w) of urea had the best constancy.

DOI: https://doi.org/10.1515/cipms-2015-0017 | Journal eISSN: 2300-6676 | Journal ISSN: 2084-980X
Language: English
Page range: 213 - 216
Submitted on: Oct 25, 2014
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Accepted on: Dec 8, 2014
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Published on: Mar 3, 2015
Published by: Sciendo
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2015 Maria Zun, Dorota Dwornicka, Katarzyna Wojciechowska, Katarzyna Swiader, Regina Kasperek, Marzena Rzadkowska, Ewa Poleszak, published by Sciendo
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.