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Investigating dye adsorption: The role of surface-modified montmorillonite nanoclay in kinetics, isotherms, and thermodynamics Cover

Investigating dye adsorption: The role of surface-modified montmorillonite nanoclay in kinetics, isotherms, and thermodynamics

Open Access
|Dec 2024

Figures & Tables

Figure 1

Absorption spectra analysis: Panel I (a): Baseline absorption spectrum of AR dye (concentration: 20 mg/L) without MM-MDH nanoclay. Panel I (b): Spectrum post interaction with 10 mg of MM-MDH nanoclay. Panel II (a): Initial absorption spectrum of MB dye (concentration: 8 mg/L) without MM-MDH nanoclay. Panel II (b): Spectrum after exposure to 7.5 mg of MM-MDH nanoclay.
Absorption spectra analysis: Panel I (a): Baseline absorption spectrum of AR dye (concentration: 20 mg/L) without MM-MDH nanoclay. Panel I (b): Spectrum post interaction with 10 mg of MM-MDH nanoclay. Panel II (a): Initial absorption spectrum of MB dye (concentration: 8 mg/L) without MM-MDH nanoclay. Panel II (b): Spectrum after exposure to 7.5 mg of MM-MDH nanoclay.

Figure 2

SEM images of MM-MDH nanoclay.
SEM images of MM-MDH nanoclay.

Figure 3

TEM analysis of MM-MDH nanoclay across multiple magnifications.
TEM analysis of MM-MDH nanoclay across multiple magnifications.

Figure 4

FT-IR of MM-MDH nanoclay.
FT-IR of MM-MDH nanoclay.

Figure 5

XRD spectra of MM-MDH nanoclay.
XRD spectra of MM-MDH nanoclay.

Figure 6

BET surface area of MM-MDH nanoclay at 77 K.
BET surface area of MM-MDH nanoclay at 77 K.

Figure 7

Impact of pH on dye adsorption percentages for AR (a) and MB (b) using MM-MDH nanoclay; 0.01 ± 0.002 g for AR and 0.0075 ± 0.002 g for MB.
Impact of pH on dye adsorption percentages for AR (a) and MB (b) using MM-MDH nanoclay; 0.01 ± 0.002 g for AR and 0.0075 ± 0.002 g for MB.

Figure 8

Effect of MM-MDH nanoclay quantity on the adsorption rates of dyes AR (a) and MB (b) over a 120-min duration at 22°C.
Effect of MM-MDH nanoclay quantity on the adsorption rates of dyes AR (a) and MB (b) over a 120-min duration at 22°C.

Figure 9

Effect of varying shaking durations on dye removal efficiency for AR (a) and MB (b) using MM-MDH nanoclay at 22°C.
Effect of varying shaking durations on dye removal efficiency for AR (a) and MB (b) using MM-MDH nanoclay at 22°C.

Figure 10

Temperature influence on the removal efficiency of dyes AR and MB using MM-MDH nanoclay over 120 min.
Temperature influence on the removal efficiency of dyes AR and MB using MM-MDH nanoclay over 120 min.

Figure 11

Impact of KNO3 concentration on dye removal efficiency of AR (a) and MB (b) using MM-MDH nanoclay at 22°C.
Impact of KNO3 concentration on dye removal efficiency of AR (a) and MB (b) using MM-MDH nanoclay at 22°C.

Figure 12

Fractional power model curves for dye species using MM-MDH nanoclay under conditions specified in batch extraction.
Fractional power model curves for dye species using MM-MDH nanoclay under conditions specified in batch extraction.

Figure 13

Lagergren kinetics curve for AR and MB dye absorption by MM-MDH nanoclay over time, with experimental conditions detailed in the batch extraction phase.
Lagergren kinetics curve for AR and MB dye absorption by MM-MDH nanoclay over time, with experimental conditions detailed in the batch extraction phase.

Figure 14

Kinetic adsorption curves for AR and MB dyes on MM-MDH nanoclay over time with previously described batch conditions.
Kinetic adsorption curves for AR and MB dyes on MM-MDH nanoclay over time with previously described batch conditions.

Figure 15

Elovich model dynamics for AR and MB dye adsorption on MM-MDH nanoclay over time, with experimental conditions specified in previous batch adsorption descriptions.
Elovich model dynamics for AR and MB dye adsorption on MM-MDH nanoclay over time, with experimental conditions specified in previous batch adsorption descriptions.

Figure 16

Graphical representation of intra-particle diffusion for AR and MB dye removal via solid-phase extraction.
Graphical representation of intra-particle diffusion for AR and MB dye removal via solid-phase extraction.

Figure 17

Graphical representation of AR and MB dye adsorption on MM-MDH nanoclay (mg/g) versus equilibrium concentration (C
                     e) at 22°C.
Graphical representation of AR and MB dye adsorption on MM-MDH nanoclay (mg/g) versus equilibrium concentration (C e) at 22°C.

Figure 18

Langmuir adsorption isotherms for AR and MB dyes on MM-MDH nanoclay at 22°C.
Langmuir adsorption isotherms for AR and MB dyes on MM-MDH nanoclay at 22°C.

Figure 19

Graph of logarithmic adsorption capacity versus equilibrium concentration for AR and MB dyes on MM-MDH nanoclay at 22°C (Freundlich isotherms).
Graph of logarithmic adsorption capacity versus equilibrium concentration for AR and MB dyes on MM-MDH nanoclay at 22°C (Freundlich isotherms).

Figure 20

Logarithmic plots of equilibrium constants (ln K
                     c) versus inverse temperature (1,000/T) for AR and MB dye adsorption from aqueous solutions by MM-MDH nanoclay.
Logarithmic plots of equilibrium constants (ln K c) versus inverse temperature (1,000/T) for AR and MB dye adsorption from aqueous solutions by MM-MDH nanoclay.

Figure 21

Removal efficiency of AR and MB dyes using MM-MDH nanoclay across three real-world samples (experimental conditions: 25 mL solution, contact time = 120 min, pH solution = 2, temperature = 295 K, 30 mg of MM-MDH nanoclay and 20 mg L−1 concentration for AR dye, and for MB dye 25 mL solution, contact time = 120 min, pH solution = 8, temperature = 295 K, 30 mg of MM-MDH nanoclay, and 8 mg L−1 concentration).
Removal efficiency of AR and MB dyes using MM-MDH nanoclay across three real-world samples (experimental conditions: 25 mL solution, contact time = 120 min, pH solution = 2, temperature = 295 K, 30 mg of MM-MDH nanoclay and 20 mg L−1 concentration for AR dye, and for MB dye 25 mL solution, contact time = 120 min, pH solution = 8, temperature = 295 K, 30 mg of MM-MDH nanoclay, and 8 mg L−1 concentration).

Figure 22

The reusability effect of MM-MDH nanoclay for removal of AR and MB dyes four times, (experimental conditions: 25 mL solution, contact time = 120 min, pH solution = 8, temperature = 295 K, 30 mg of MM-MDH nanoclay and 8 mg L−1 concentration for MB dye, and for the AR dye 25 mL solution, contact time = 120 min, pH solution = 2, temperature = 295 K, 30 mg of MM-MDH nanoclay and 20 mg L−1 concentration).
The reusability effect of MM-MDH nanoclay for removal of AR and MB dyes four times, (experimental conditions: 25 mL solution, contact time = 120 min, pH solution = 8, temperature = 295 K, 30 mg of MM-MDH nanoclay and 8 mg L−1 concentration for MB dye, and for the AR dye 25 mL solution, contact time = 120 min, pH solution = 2, temperature = 295 K, 30 mg of MM-MDH nanoclay and 20 mg L−1 concentration).

The parameter of Langmuir and Freundlich isotherm models for the retention of AR and MB dyes on MM-MDH nanoclay at 22°C

Models of sorption isothermsAR dyeMB dye
Langmuir q m (mg/g)34.9620.92
K L (L/g)0.6150.282
R L 0.0750.307
R 2 0.99870.9989
Freundlich K F (mg/g)21.9713.18
1/n 0.1510.329
R 2 0.97650.9626

Comparison between the MM-MDH nanoclay and other reported adsorbents for removal of AR and MB dyes

DyesSolid phaseUptake capacityReference
ARBlack tea leaves30.3[5]
ARCarboxylated alginic acid9.17[70]
ARFerrous sulfate flocs6.623[71]
ARActivated carbon18.76[51]
ARHalloysite nanoclay13.89[42]
ARZinc ferrite Mn0.8Zn0.2Fe2O4 magnetic49.90[72]
AR MM-MDH nanoclay 34.33 This work
MBGreen tea dredge71.4[73]
MBSugarcane bagasse12.42[74]
MBTreated sugarcane bagasse58.9[75]
MBSodium alginate hydrogel51.34[76]
MBMagnetic chitosan–PEGDE–EDTA composite5.04[77]
MBActivated corn husk waste [78]
MB MM-MDH nanoclay 12.5 This work

The parameters for various kinetic models for removal of AR and MB dye onto MM-MDH nanoclay at 22°C

Fractional power function kinetic model
a b ab R 2
AR9.1160.2672.4330.991
MB5.8470.2571.5010.985
Language: English
Submitted on: Aug 26, 2024
Accepted on: Nov 4, 2024
Published on: Dec 18, 2024
Published by: Sciendo
In partnership with: Paradigm Publishing Services

© 2024 Raja Saad Alruwais, published by Sciendo
This work is licensed under the Creative Commons Attribution 4.0 License.