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Calculation Of The Crystal Field Parameters For Eu3+ Doped In SrAl2O4 And SrIn2O4 Spinels Cover

Calculation Of The Crystal Field Parameters For Eu3+ Doped In SrAl2O4 And SrIn2O4 Spinels

By: M. L. Stanciu  
Open Access
|Oct 2015

Abstract

Strontium aluminate (SrAl2O4) and the indium aluminate (SrIn2O4) spinels have been proven to be efficient host materials, which offer the possibility of generating broadband emission after doping with rare earth trivalent ions. The present work is devoted to the calculation of the crystal field parameters and the energy levels of the trivalent europium doped in SrAl2O4 and SrIn2O4 spinels, using the superposition model of the crystal field. Using the intrinsic parameters for Eu3+-O2− bonds, and the geometry structure of the each crystal, we modeled the CFPs and simulated the low-lying energy levels schemes. The obtained results are compared with the experimental data and discussed.

DOI: https://doi.org/10.1515/awutp-2015-0021 | Journal eISSN: 2784-1057 | Journal ISSN: 1224-9718
Language: English
Page range: 132 - 138
Submitted on: Dec 12, 2011
Accepted on: Mar 19, 2012
Published on: Oct 5, 2015
Published by: West University of Timisoara
In partnership with: Paradigm Publishing Services
Publication frequency: 1 issue per year

© 2015 M. L. Stanciu, published by West University of Timisoara
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.