OH and halogen atom influence on the variability of non-methane hydrocarbons in the Antarctic Boundary Layer
References
-
Andreae
, M. 0. and Merlet, P. 2001.Emission of trace gases and aerosols from biomass burning. Global Biogeochem. Cycles 15, 955– 966.Ariya, P. A., Niki, H., Harris, G. W., Anlauf, K. G. and Worthy, D. E. J. 1999.Polar sunrise experiment 1995: hydrocarbon measurements and tropospheric Gland Br-atoms chemistry. Atmos. Environ. 33, 931– 938. -
Blake
, N. J., Blake, D. R., Sive, B. C., Chen, T. Y., Rowland, E S.Biomass burning emissions and vertical distribution of atmospheric methyl halides and other reduced carbon gases in the South Atlantic region. J. Geophys. Res. 101, 24151– 24164. -
Bloss
, W. J., Evans, M. J., Lee, J. D., Sommariva, R., Heard, D. E.The oxidative capacity of the troposphere: Coupling of field measurements of OH and a global chemistry transport model. Faraday Discuss. 130, 425– 436. -
Bonsang
, B., Kanakidou, M.and Lambert, G. 1990. NMHC in the marine atmosphere: Preliminary results of monitoring at Amsterdam Island. J. Atmos. Chem. 11, 169– 178. -
Bottenheim
, J. W., Boudries, H., Brickell, P. C.and Atlas, E. 2002a. Alkenes in the Arctic boundary layer at Alert, Nunavut, Canada. At-mos. Environ. 36, 2585– 2594. -
Bottenheim
, J. W., Dibb, J. E., Honrath, R. E.and Shepson, P. B. 2002b. An introduction to the ALERT 2000 and SUMMIT 2000 Arctic re-search studies. Atmos. Environ. 36, 2467– 2469. -
Carpenter
, L. J., Sturges, W. T., Penkett, S. A., Liss, P. S., Alicke, B.and co-authors 1999. Short-lived alkyl iodides and bromides at Mace Head, Ireland: Links to biogenic sources and halogen oxide produc-tion. J. Geophys. Res. 104, 1679– 1689. -
Clarkson
, T. S., Martin, R. J.and Rudolph, J. 1997. Ethane and propane in the southern marine troposphere. Atmos. Environ. 31, 3763– 3771. -
Davis
, D., Nowak, J. B., Chen, G., Buhr, M., Arimoto, R.Unexpected high levels of NO observed at South Pole. Geophys. Res. Letts. 28, 3625– 3628. -
DeMore
, W. B., Sander, S. P., Golden, D. M., Hampson, R. E, Kurylo, M. J.Chemical kinetics and photochemical data for use in stratospheric modelling, evaluation number 12 JPL Publications, Pasadena, California. -
Domine, E and Shepson, P. B
. 2002. Air-snow interactions and atmo-spheric chemistry. Science, 1506– 1510. -
Donahue
, N. M.and Prinn, R. G. 1990.Nonmethane hydrocarbon chem-istry in the remote marine boundary layer. J. Geophys. Res. 95, 18387– 18411. -
Durana
, N., Navazo, M., Gomez, M. C., Alonso, L., Garcia, J. A.and co-authors. 2006.Long term hourly measurement of 62 non-methane hydrocarbons in an urban area: Main results and contribution of non-traffic sources. Atmos. Environ. 40(D16), 2860– 2872. -
ECMWF
. The description of the ECMWF/WRCP Level DI-A global atmospheric data archive. ECMWF. 1995.Reading, RG2 9AX, UK, Shinfield Park. -
Evans
, M. J., Jacob, D. J., Atlas, E., Cantrell, C. A., Eisele, E and co-authors. 2003.Coupled evolution of BrOx-C10x-H0x-NOx chem-istry during bromine-catalyzed ozone depletion events in the arctic boundary layer./. Geophys. Res. 108, art. no.-8368. -
Fischer
, R., Weller, R., Jacobi, H. W.and Ballschmiter, K. 2002. Levels and pattern of volatile organic nitrates and halocarbons in the air at Neumayer Station (70 degrees S), Antarctic. Chemosphere, 981– 992. -
Goldstein
, A. H., Wofsy, S. C.and Spivakovsky, C. M.Seasonal variations of nonmethane hydrocarbons in rural New England: Con-straints on OH concentrations in northern midlatitudes. J. Geophys. Res., 100, D10, 21 023-21 033. -
Gros
, V., Martin, D., Poisson, N., Kanakidou, M., Bonsang, B.Ozone and C2_C5 hydrocarbon observations in the marine boundary layer between 45°S and 77°S. Tellus 50B, 430 /M. -
Hopkins
, J. R., Jones, I. D., Lewis, A. C., McQuaid, J. B.and Seakins, P. W.Non-methane hydrocarbons in the Arctic boundary layer. Atmos. Environ. 36, 3217– 3229. -
Hopkins
, J. R., Lewis, A. C.and Seakins, P. W.Analysis and applications of measurements of source dominated hydrocarbon con-centrations from the PUMA campaigns in June/July 1999 and Jan-uary/February 2000 at an urban background site in Birmingham, UK. Atmos. Environ. 39, 535– 548. -
Jacobi
, H.-W., Weller, R., Jones, A. E., Anderson, P. S.and Schrems, 0. 2000. Peroxyacetyl nitrate (PAN) concentrations in the Antarctic troposphere measured during the Photochemical Experiment at Neu-mayer (PEAN'99). Atmos. Environ. 34, 5235– 5247. -
Jacobi
, H.-W., Frey, M. M., Hutterli, M. A., Bales, R. C., Schrems, 0. and co-authors. 2002.Measurements of hydrogen peroxide and formaldehyde exchange between the atmosphere and surface snow at Summit, Greenland. Atmos. Environ. 36, 2619– 2628. -
Jenkin
, M. E., Saunders, S. M., Wagner, V.and Pilling, M. J.Pro-tocol for the development of the Master Chemical Mechanism, MCM v3 (Part B): tropospheric degradation of aromatic volatile organic compounds. Atmos. Chem. Phys. 3, 181– 193. -
Jobson
, B. T., Niki, H., Yokouchi, Y., Bottenheim, J., Hopper, E and co-authors. 1994a. Measurements of C2-C6 hydrocarbons during the Polar Sunrise 1992 Experiment: Evidence for Cl atom and Br atom chemistry. J. Geophys. Res. 99, 25355– 25368. -
Jobson
, B. T., Wu, Z., Niki, H.and Barrie, L. A. 1994b. Seasonal trends of isoprene, C2-05 alkanes, and acetylene at a remote boreal site in Canada. J. Geophys. Res. 99( D1), 1589– 1599. -
Jones
, A. E., Weller, R., Wolff, E. W.and Jacobi, H. W. 2000. Speciation and rate of photochemical NO and NO2 production in Antarctic snow. Geophys. Res. Letts. 27, 345– 348. -
Jones
, A. E., Anderson, P. S., Wolff, E. W., Turner, J., Rankin, A. M.A role for newly forming sea ice in springtime polar tropospheric ozone loss? Observational evidence from Halley station, Antarctica. J. Geophys. Res. 111, D08306, 10.1029/2005JD006566. -
Kanakidou
, M., Bonsang, B., Roulley, J. C. L., Lambert, G., Martin, D.Marine source of atmospheric acetylene. Nature 333, 51– 52. -
Kanakidou
, M., Singh, H. B., Valentin, K. M.and Crutzen, P. J. 1991.A two-dimensional study of ethane and propane oxidation in the tropo-sphere. J. Geophys. Res. 96( D8), 15 395-15 413. -
Kaspers
, K. A., van de Wal, R. S. W., de Gouw, J. A., Hofstede, C. M., van den Broeke, M. R.. Analyses of fim gas samples from Dronning Maud Land , Antarctica: Study of nonmethane -
hydrocarbons and methyl chloride
. Geophys. Res. 109, art. no.-D02307. -
Khalil
, M. A. K., Moore, R. M., Harper, D. B., Lobert, J. M., Erickson, D. J.Natural emissions of chlorine-containing gases: Reactive Chlorine Emissions Inventory. J. Geophys. Res. 104, 8333– 8346. -
Khalil
, M. A. K.and Rasmussen, R. A. 1986. Temporal variability of C2-hydrocarbons at the South Pole: Seasonal cycles and the possible effects of El-Nino. Antarct. .1. U. S., 244– 245. -
Khalil
, M. A. K.and Rasmussen, R. A. 1999a. Atmospheric chloroform. Atmos. Environ. 33, 1151– 1158. -
Khalil
, M. A. K.and Rasmussen, R. A. 1999b. Atmospheric methyl chloride. Atmos. Environ. 33, 1305– 1321. -
Kottmeier
, C.and Fay, B. 1998.Trajectories in the Antarctic lower tro-posphere./. Geophys. Res. 103, 10947– 10959. -
Lewis
, A. C., Carpenter, L. J.and Pilling, M. J.Nonmethane hydrocarbons in Southern Ocean boundary layer air.../. Geophys. Res. 106, 4987– 4994. -
Mauldin
, R. L., Eisele, E L., Tanner, D. J., Kosciuch, E., Shetter, -
R. and co-authors
. 2001. Measurements of OH, H2504, and MSA at the South Pole during ISCAT. Geophys. Res. Letts. 28, 3629– 3632. -
Murayama
, S., Nakasawa, T., Tanaka, M., Aoki, S. -
S
. 1992. Variations of tropospheric ozone mixing ratio over Syowa Station, Antarctica. Tellus, 262– 272. -
Platt
, U.and Hönninger, G. 2003. The role of halogen species in the troposphere. Chemosphere, 325– 338. -
PORG
. Ozone in the United Kingdom 1993.Third report of the U.K. photochemical oxidants review group: 1993.Department of the Envi-ronment, London. -
Pszenny
, A. A. P., Keene, W. C., Jacob, D. J., Fan, S., Maben, J. R. and co-authors. 1993.Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air. .1. Geophys. Res. 20, 699. -
Quack
, B.and Wallace, D. W. R. 2003.Air-sea flux of bromoform: Controls, rates and implications. Global Biogeochem. Cycles 17(1), Art. No. 1023. -
Rankin
, A. M.and Wolff, E. W. 2003.A year-long record of size-segregated aerosol composition at Halley, Antarctica. J. Geophys. Res. 108, art. no.-4775. -
Ratte
, M., Bujok, 0., Spitzy, A. and Rudolph, J. 1998.Photochemical alkene formation in seawater from dissolved organic carbon: Results from laboratory experiments. J. Geophys. Res. 103, 5707– 5717.Riedel, K., Weller, R., Schrems, 0. and Konig-Langlo, G. 2000.Variabil-ity of tropospheric hydroperoxides at a coastal surface site in Antarc-tica. Atmos. Environ. 34, 5225– 5234. -
Royal Society
. 1962.. Brunt.D. Volume III, seismology, meteorology. The Royal Society, London. -
Rudolph
, J.The tropospheric distribution and budget of ethane. J. Geophys. Res. 100, 11369– 11381. -
Rudolph
, J., Khedim, A., Clarkson, T.and Wagenbach, D.Long-term measurements of light alkanes and acetylene in the Antarctic troposphere. Tellus 44B, 252– 261. -
Rudolph
, J., Khedim, A.and Wagenbach, D.The seasonal variation of light non-methane hydrocarbons in the Antarctic troposphere. ./. Geophys. Res. 94, 13039– 13044. -
Rudolph
, J., Koppmann, R. and PlassDulmer, C. 1996. The budgets of ethane and tetrachloroethene: Is there evidence for an impact of reactions with chlorine atoms in the troposphere?. Atmos. Environ. 30, 1887– 1894. -
Schnell
, R. C., Liu, S. C.and Oltmans, S. J.Decrease of summer tropospheric ozone concentrations in Antarctica. Nature, 351, 726– 729. -
Sharma
, U. K., Kajii, Y.and Akimoto, H. 2000. Seasonal variation of C2-C6 NMHCs at HAPPO, a remote site in Japan. Atmos. Environ. 34, 4447– 4458. -
Sumner
, A. L.and Shepson, P. B. 1999. Snowpack production of formaldehyde and its effect on the Arctic troposphere. Nature, 230– 233. -
Swanson
, A. L., Blake, N., Atlas, E., Flocke, E, Blake, D. R.Seasonal variations of C1-C4 nonmethane hydro-carbons and C1-C4 alkyl nitrates at the Summit research station in Greenland./. Geophys. Res. 108,4065, 10.1029/2001JD001445. -
Swanson
, A. L., Blake, N. J., Dibb, J. E., Albert, M. R., Blake, D. R.Photochemically induced production of CH3Br, CH3I, C2H5I, ethene, and propene within surface snow at Summit, Greenland. Atmos. Environ. 36, 2671– 2682. -
Touaty
, M., Bonsang, B., Kanakidou, M.and Poisson, N. 1996.Moni-toring and model comparison of the seasonal variation of tropospheric light hydrocarbons at Amsterdam Island. Proceedings of EUROTRAC Symposium '96. (Eds.Borrell, P. M., Bondi, P., Cvitas, T., Kelly, K. and Seiler, W.) 613– 619. -
Vogt
, R., Crutzen, P. J.and Sander, R.A mechanism for halogen release from sea-salt aerosol in the remote marineboundary layer. Nature 383, p. 327– 330. -
Wagenbach
, D., Gorlach, U., Moser, K.and Munnich, K. 0. 1988. Coastal Antarctic aerosol:the seasonal pattern of its chemical com-position and radionuclide content. Tellus, 426– 436. -
Wang
, J.-L., Chen, W.-L. and Tsai, C.-H. 2000.Cryogen free automated gas chromatography for the measurement of ambient volatile organic compounds. J. Chromatogr. A 896, 31– 39. -
Wessel
, S., Aoki, S., Winkler, P., Weller, R., Herber, A., Gernandt, H.Tropospheric ozone depletion in polar regions - A comparison of observations in the Arctic and Antarctic. Tellus B 50, 34– 50. -
Wevill
, D. J.and Carpenter, L. J.Automated mea-surement and calibration of reactive volatile halogenated or-ganic compounds in the atmosphere. Analyst v. 129, 634– 638. -
Yamamoto
, N., Okayasu, H., Hiraiwa, T., Murayama, S., Tuneaki, M.Continuous determination of volatile organic compounds in the atmosphere by an automated gas chromatographic system. J. Chromatogr. A 819, 177– 186. -
Zhou
, X., Beine, H. J., Honrath, R. E., Fuentes, J. D., Simpson, W. and co-authors. 2001.Snowpack photochemical production of HONO: A major source of OH in the Arctic boundary layer in springtime. Geophys. Res. Lett. 28, 4087– 4090.
DOI: https://doi.org/10.1111/j.1600-0889.2006.00226.x | Journal eISSN: 1600-0889
Language: English
Page range: 22 - 38
Submitted on: Dec 21, 2005
Accepted on: Sep 4, 2006
Published on: Jan 1, 2007
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services
© 2007 Katie A. Read, Alastair C. Lewis, Rhian A. Salmon, Anna E. Jones, Stéphane Bauguitte, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.