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On the early studies recognizing the role of sulphuric acid in atmospheric haze and new particle formation Cover

On the early studies recognizing the role of sulphuric acid in atmospheric haze and new particle formation

By:   
Open Access
|Jan 2018

Figures & Tables

Fig. 1.

The experimental setup used by Tyndall: Light source L is used to illuminate glass tube SS, into which air is bubbled through the studied liquid in flask F next to two U-tubes located at the right end of the table, T and T, containing fragments of glass coated with aqueous sulphuric acid and fragments of marble wetted with caustic potash, respectively, through which the air was admitted. Reproduced from Tyndall (1870).

Fig. 2.

The fog chamber used by Barus and his assistants for field measurements. C and q indicate the stopcock and end of inlet for the sampled air, while two stopcocks B (mainly) and F are used for the exhaustion. Water level is marked with w, chamber frame A is made out of waxed wood and e indicates the position of trunnions mounting the chamber, allowing rotation to wet the cotton cloth n lining the chamber. Reproduced from Barus (1905, p. 129).

Fig. 3.

An excerpt of simultaneous daily measurements in Providence (upper curves) and Block Island (lower curves) in spring 1905: the vertical axis gives the concentration as thousands of particles in cubic centimeter. Temperatures (in °F), wind directions, and prevailing weather are also indicated. Reproduced from Barus (1906b, p. 125).

Table 1.

A concise timeline of discovering the role of sulphuric acid in atmospheric haze and new particle formation.

YearDiscovery350 BCEMeteorologica by Aristotle1700Volcan de Lémery1756Kant connects 1755 Lisbon earthquake with visible dust formation, speculating with the mechanism proposed by Lémery1783–1784Eruption of Laki: dry haze over most of the Europe, source speculated, connection to sulphuric smell noted1803, 1809First scientific speculations of particle formation due to chemical reactions in the atmosphere1819–1821Rafinesque points out that a continuous source of particle formation in the atmosphere is needed to explain appearance of scattered sun rays and that sulphuric acid and ammonia are likely to provide the required chemical mechanism1868Tyndall makes the first quantitative laboratory experiments on aerosol formation1875Coulier finds condensation nuclei (CN)1881Aitken points out the importance of CN to cloud formation1884–1893Kiessling, von Helmholtz, and Barus perform laboratory studies on the on-set of condensation, possibility of homogeneous nucleation first brought into discussion1897Wilson’s cloud chamber1900–1906First atmospheric observation of NPF by Aitken intensive field measurements by Barus
Language: English
Page range: 1471913 - 1471913
Submitted on: Sep 12, 2017
Accepted on: Apr 16, 2018
Published on: Jan 1, 2018
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services

© 2018 Jussi Malila, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.